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The Preparation and Preliminary Characterisation of Eight Geological MPI-DING Reference Glasses for In-Situ Microanalysis
Authors:Klaus Peter Jochum  Donald B Dingwell  Alexander Rocholl  Brigitte Stoll  Albrecht W Hofmann  S Becker  A Besmehn  D Bessette  H-J Dietze  P Dulski  J Erzinger  E Hellebrand  P Hoppe  I Horn  K Janssens  GA Jenner  M Klein  WF McDonough  M Maetz  K Mezger  C Müker  IK Nikogosian  C Pickhardt  I Raczek  D Rhede  HM Seufert  SG Simakin  AV Sobolev  B Spettel  S Straub  L Vincze  A Wallianos  G Weckwerth  S Weyer  D Wolf  M Zimmer
Institution:Max-Planck-Institut für Chemie, Postfach 3060, D-55020 Mainz, Germany. e-mail:;Bayerisches Geoinstitut, UniversitäUt Bayreuth, Postfach 101251, D-95440 Bayreuth, Germany;Forschungszentrum Jülich, D-52425 Jülich, Germany;UniversitäUt Hamburg, Grindelallee 48, D-20146 Hamburg, Germany;Harvard University, 20 Oxford St, Cambridge, MA 02138, USA;University of Antwerp, Universiteitsplein 1, B-2610 Wilrijk-Antwerp, Belgium;Memorial University of Newfoundland, St. Johns NF A1B 3X5, Canada;UniversitäUt zu KöUln, ZüUlpicher Str. 49, D-50674 KöUln, Germany;Max-Planck-Institut füUr Kernphysik, Postfach 103980, D-69029 Heidelberg, Germany;Vrije Universiteit, De Boelelaan 1085, NL-1081 HV Amsterdam, The Netherlands;UniversitäUt Heidelberg, Im Neuenheimer Feld 236, D-69120 Heidelberg, Germany;Institute of Microelectronics, Universitetskaya St. 21, Yaroslavl 150007, Russia;Vernadsky Institute of Geochemistry, Kosigin 19, Moscow 117979, Russia;GeoForschungsZentrum Potsdam, Telegrafenberg, D-14473 Potsdam, Germany;GEOMAR, Wischhofstraβe 1-3, D-24148 Kiel, Germany;UniversitäUt Münster, Corrensstraβe 24, D-48149 MüUnster, Germany
Abstract:Eight silicate glasses were prepared by directly fusing and stirring 50-100 g each of basalt, andesite, komatiite, peridotite, rhyolite, and quartz-diorite. These are referred to as MPI-DING glasses and were made for the purpose of providing reference materials for geochemical, in-situ microanalytical work. Results from various analytical techniques indicate that individual glass fragments are well homogenised with respect to major and trace elements at the μm to mm scale. Heterogeneities due to quench crystallisation of olivine have been observed in small and limited areas of the two komatiitic glasses. In order to obtain concentration values for as many elements as possible, the glasses were analysed by a variety of bulk and microanalytical methods in a number of laboratories. The analytical uncertainties of most elements are estimated to be between 1% and 10%. From the analytical data, preliminary reference values for more than sixty elements were calculated. The analytical uncertainties of most elements are estimated to be between 1% and 10%.
Keywords:reference materials  geological glasses  microprobe analysis  preparation  characterisation  in-situ techniques
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