The use of tourmaline in geochemical prospecting for gold and copper mineralization

Chemical composition, unit cell parameters, and trace elements of tourmalines from Mesozoic gold-quartz-sulphide and gold-bearing copper-porphyry ore-magmatic systems of the Trans-Baikal area and Mongolia show that they belong to the specific schorl-dravite highly ferruginous oxytourmaline series. They are low in alumina (Al₂O₃ = 16–33%) and have MgO contents (up to 10%) and Fe₂O₃ (1%). There is a direct correlation of unit cell parameters (a,c,V) with total iron, which permits composition estimates from X-ray diffraction analyses. As a rule, these tourmalines contain high concentrations of Au, Pb and Cu, which are mainly hosted by inclusions of native gold and ore minerals. The highest As abundances are contained in the tourmalines of the copper-porphyry field.Two trends of isomorphic replacement are related to increasing Fe content of oxyferruginous tourmalines:(1) “Acid leaching” trend (less ferruginous part of the series) Mg + Fe²⁺ + 4Al + 40 4Fe³⁺ + 2 + 4(OH,F); and (2) “conjugate deposition” trend Mg + 1.5Fe²⁺ + 1.5Al + 4(OH,F) 4Fe³⁺ + 4O.These features distinguish tourmalines from gold-bearing systems from schorl-dravites of tin and rare-metal deposits. They may be used in metallogenic analyses, interpretation of the origin of primary and secondary anomalies, and assessment of the type and zonation of ore fields.