Geochemistry of subsurface Late Quaternary ironstones in Rajshahi and Bogra Districts,Bangladesh: implications for genetic and depositional conditions

The present study deals with the geochemistry of Late Quaternary ironstones in the subsurface in Rajshahi and Bogra districts, Bangladesh with the lithological study of the boreholes sediments. Major lithofacies of the studied boreholes are clay, silty clay, sandy clay, fine to coarse grained sand, gravels and sands with (fragmentary) ironstones. The ironstones contain major oxides, Fe₂O₃* (* total Fe) (avg. 66.6 wt%), SiO₂ (avg. 15.3 wt%), Al₂O₃ (avg. 4.0 wt%), MnO (avg. 7.7 wt%), and CaO (avg. 3.4 wt%). These geochemical data imply that the higher percentage of Fe₂O₃* along with Al₂O₃ and MnO indicate the ironstone as goethite and siderite, which is also validated by XRD data. A comparatively higher percentage of SiO₂ indicates the presence of relative amounts of clastic quartz and manganese-rich silicate or clay in these rocks. These ironstones also have significant amounts of MnO (avg. 7.7 wt%) suggesting their depositional environments under oxygenated condition. Chemical data of these ironstones suggest that the source rock suffered deep chemical weathering and iron was mostly carried in association with the clay fraction and organic matter. Iron concretion was mostly formed by bacterial build up in swamps and marshes, and was subsequently embedded in clayey mud. Within the coastal environments, the water table fluctuates and goethite and siderite with mud and quartz became dry and compacted to form ironstone.