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Sea-floor exhalative sedimentary and magmatic hydrothermal superimposition on the Bainiuchang polymetallic deposit in Yunnan Province: REE geochemical evidence
作者姓名:ZHU  Chaohui  ZHANG  Qian  SHAO  Shuxun  ZHU  Xiaoqing  HE  Yuliang  WANG  Dapeng
作者单位:ZHU Chaohui 1,2,ZHANG Qian1,SHAO Shuxun1,ZHU Xiaoqing1,HE Yuliang1,2,and WANG Dapeng1,2 1 State Key Laboratory of Ore Deposit Geochemistry,Institute of Geochemistry,Chinese Academy of Sciences,Guiyang 550002,China 2 Graduate School of the Chinese Academy of Sciences,Beijing 100039,China
基金项目:The authors wish to thank Dr. Zhang Hongpei, Mr. Xia Hongchun and Mr. Zhou Yaokun for their help with sample collection. This research project was financially supported jointly by the Key Research Project (No. KZCX3-SW-125) of CAS and the National Natural Science Foundation of China (No. 40172037).
摘    要:In order to study the characteristics of sea-floor exhalative sedimentary and magmatic hydrothermal superimposition on the Bainiuchang polymetallic deposit, the REE compositions of the granites, host-rocks and ores have been systematically analyzed by ICP-MS. As viewed from their REE compositions, the granites show obvious negative Eu anomalies and weak negative Ce anomalies. According to their REE characteristics, the host-rocks were derived partly from sea-floor exhalative sediments. In terms of their REE compositions, the ores can be divided into two groups: one group, of which the samples were collected from the Baiyang segment relatively far away from the Bozhushan granite batholith, possesses positive Eu anomalies or no Eu anomaly and negative Ce anomalies, indicating that ore-forming hydrothermal fluid was relatively reductive and its temperature was higher than 250 ℃. Furthermore, the coinstantaneous presence of positive Eu anomalies and negative Ce anomalies indicate that the convective mixing of a little amount of seawater with hydrothermal fluid had happened while ores were precipitated on ancient sea floor. The other group, of which the samples were mainly collected from the Chuanxindong and Duimenshan segments near the Bozhushan granite batholith, has similar chondrite-monalized REE distribution patterns to those of the magmatic rocks. But as a whole, the REE characteristics of both groups change gradually starting from the Bozhushan granite batholith. Based on the REE characteristics of the granites, host-rocks and ores, it is suggested that the ore-forming metals seem to have come from several different sources.

关 键 词:海床  沉积物  稀土  矿石
收稿时间:27 July 2006
修稿时间:2006-07-272006-08-25

Sea-floor exhalative sedimentary and magmatic hydrothermal superimposition on the Bainiuchang polymetallic deposit in Yunnan Province: REE geochemical evidence
ZHU Chaohui ZHANG Qian SHAO Shuxun ZHU Xiaoqing HE Yuliang WANG Dapeng.Sea-floor exhalative sedimentary and magmatic hydrothermal superimposition on the Bainiuchang polymetallic deposit in Yunnan Province: REE geochemical evidence[J].Chinese Journal of Geochemistry,2007,26(3):267-275.
Authors:Zhu Chaohui  Zhang Qian  Shao Shuxun  Zhu Xiaoqing  He Yuliang  Wang Dapeng
Institution:(1) State Key Laboratory of Ore Deposit Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang, 550002, China;(2) Graduate School of the Chinese Academy of Sciences, Beijing, 100039, China
Abstract:In order to study the characteristics of sea-floor exhalative sedimentary and magmatic hydrothermal superimposition on the Bainiuchang polymetallic deposit, the REE compositions of the granites, host-rocks and ores have been systematically analyzed by ICP-MS. As viewed from their REE compositions, the granites show obvious negative Eu anomalies and weak negative Ce anomalies. According to their REE characteristics, the host-rocks were derived partly from sea-floor exhalative sediments. In terms of their REE compositions, the ores can be divided into two groups: one group, of which the samples were collected from the Baiyang segment relatively far away from the Bozhushan granite batholith, possesses positive Eu anomalies or no Eu anomaly and negative Ce anomalies, indicating that ore-forming hydrothermal fluid was relatively reductive and its temperature was higher than 250°C. Furthermore, the coinstantaneous presence of positive Eu anomalies and negative Ce anomalies indicate that the convective mixing of a little amount of seawater with hydrothermal fluid had happened while ores were precipitated on ancient sea floor. The other group, of which the samples were mainly collected from the Chuanxindong and Duimenshan segments near the Bozhushan granite batholith, has similar chondrite-monalized REE distribution patterns to those of the magmatic rocks. But as a whole, the REE characteristics of both groups change gradually starting from the Bozhushan granite batholith. Based on the REE characteristics of the granites, host-rocks and ores, it is suggested that the ore-forming metals seem to have come from several different sources.
Keywords:Bainiuchang polymetallic deposit  exhalative sedimentary  magmatic hydrothermal superimposition  rare-earth element  ore deposit origin
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