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坡缕石对直接耐酸大红4BS的吸附动力学特征
引用本文:彭书传,崔康平,王诗生,陈天虎,姜绍通. 坡缕石对直接耐酸大红4BS的吸附动力学特征[J]. 矿物学报, 2006, 26(3): 267-271
作者姓名:彭书传  崔康平  王诗生  陈天虎  姜绍通
作者单位:合肥工业大学,资源与环境工程学院,安徽,合肥,230009;合肥工业大学,资源与环境工程学院,安徽,合肥,230009;合肥工业大学,资源与环境工程学院,安徽,合肥,230009;合肥工业大学,资源与环境工程学院,安徽,合肥,230009;合肥工业大学,资源与环境工程学院,安徽,合肥,230009
摘    要:研究了坡缕石对水中直接耐酸大红4BS的吸附动力学,在初始质量浓度为30~50 mg/L,转速为100~200 r/min,以及温度为303~348 K的范围内,坡缕石对直接耐酸大红4BS的吸附动力学数据均符合准二级速率方程。结果表明,坡缕石对直接耐酸大红4BS的吸附是外表面吸附,吸附表观活化能为11.92 kJ/mol,说明此吸附是由液膜扩散控制的物理吸附过程。

关 键 词:坡缕石  吸附  直接耐酸大红  动力学
文章编号:1000-4734(2006)03-0267-05
收稿时间:2005-11-30
修稿时间:2005-11-30

STUDY ON ADSORPTION KINETICS OF DIRECT ACID PROOF SCARLET 4BS ONTO PURIFIED PALYGORSKITE FROM AQUEOUS SOLUTIONS
PENG Shu-chuan,CUI Kang-ping,WANG Shi-sheng,CHEN Tian-hu,JIANG Shao-tong. STUDY ON ADSORPTION KINETICS OF DIRECT ACID PROOF SCARLET 4BS ONTO PURIFIED PALYGORSKITE FROM AQUEOUS SOLUTIONS[J]. Acta Mineralogica Sinica, 2006, 26(3): 267-271
Authors:PENG Shu-chuan  CUI Kang-ping  WANG Shi-sheng  CHEN Tian-hu  JIANG Shao-tong
Affiliation:School of Resources and Environmental Engineering, Hefei University of Technology, Heifei 230009, China
Abstract:The adsorption kinetics of purified palygorskite for direct acid proof scarlet 4BS from aqueous solutions was investigated. Kinetics data for the adsorption of direct acid proof scarlet 4BS from aqueous solutions were in good agreement with pseudo-second rate equation within the initial concentration 30-50mg/L, agitation speed 100-200 r/min and experimental temperature 298-348 K. The results showed that direct acid proof scarlet 4BS was only adsorbed on the extemal surface of purified palygorskite, The apparent adsorption activation energy is 11. 921 kJ/mol. Relatively low apparent adsorption activation energy suggests that the adsorption direct acid proof scarlet 4BS is a type of physical adsorption, which is controlled by film diffusion.
Keywords:purified palygorskite  adsorption  direct acid proof scarlet 4BS  kinetics
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