Spatial distribution of organic matter in the Bells CM2 chondrite using near‐field infrared microspectroscopy |
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| Authors: | Yoko KEBUKAWA Satoru NAKASHIMA Michio ISHIKAWA Kento AIZAWA Tsutomu INOUE Keiko NAKAMURA‐MESSENGER Michael E ZOLENSKY |
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| Institution: | 1. Department of Earth and Space Science, Osaka University, 1‐1 Machikaneyama, Toyonaka, Osaka 560‐0043, Japan;2. Present address: Geophysical Laboratory, Carnegie Institution of Washington, 5251 Broad Branch Rd. NW, Washington, D.C. 20015, USA;3. Jasco Co., Ltd., 2967‐5 Ishikawa, Hachioji, Tokyo 192‐8537, Japan;4. Astromaterials Research and Exploration Science, KT, NASA Johnson Space Center, Houston, Texas 77058, USA |
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| Abstract: | Abstract– Distributions of organic functional groups as well as inorganic features were analyzed in the Bells (CM2) carbonaceous chondrite using near‐field infrared (NFIR) spectroscopy. NFIR spectroscopy has recently been developed to enable infrared spectral mapping beyond the optical diffraction limit of conventional Fourier transform infrared microspectroscopy. NFIR spectral mapping of the Bells 300 nm thick sections on Al plates for 7.5 × 7.5 μm2 areas showed some C‐H‐rich areas which were considered to represent the organic‐rich areas. Heterogeneous distributions of organic matter as well as those of inorganic phases such as silicates (Si‐O) were observed with 1 μm spatial resolution. The NFIR mappings of aliphatic C‐H (2960 and 2930 cm?1) and structural OH (3650 cm?1) confirm that organic matter is associated with phyllosilicates as previously suggested. The NFIR mapping method can provide 1 μm spatial distribution of organic functional groups and their association with minerals. High local sensitivity of NFIR enables us to find organic‐rich areas and to characterize them by their aliphatic CH2/CH3 ratios. The aliphatic CH2/CH3 ratio of Bells is slightly higher than Murchison, similar to Orgueil, and lower than literature values of IDPs and cometary dust particles. |
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