Chemical Features of White Micas from the Piemonte Calc-schists, Western Alps and Implications for K–Ar Ages of Metamorphism

Anomalously large chemical ranges in muscovite-paragonite and muscovite-celadonite systems are observed in white micas from the Piemonte calcschists in the Chisone valley area, internal western Alps. The petrographical and chemical observations on white mica strongly suggest that most mica crystals with high Na/K ratios in the chlorite zone are of detrital origin, and were derived from the pre-Alpine high-temperature metamorphic sequence such the Caledonian and/or Variscan. Submicroscopic muscovite (Ms) - paragonite (Pg) composite aggregates occur in the chlorite zone and their EPMA analyses give an apparent chemical composition range from Ms_0.6Pg_0.4 to Ms_0.2Pg_0.8. In the rutile zone, the paragonite content of the white micas is less than 20%, suggesting that the white micas have been homogenized during the Alpine metamorphism even if detrital white micas existed.Metamorphic mica is also very heterogeneous. The total range in Si content becomes wider with increasing of metamorphic grade: 3.22–3.39 pfu for the chlorite zone, 3.07–3.45 pfu for the chloritoid zone and 3.06–3.59 pfu for the rutile zone. This clearly indicates that the micas have experienced significant retrogressive chemical reactions during cooling and exhumations of the host schists.The detrital white mica in the chlorite zone has not reset well in its K-Ar system during the Alpine subduction-related metamorphism. The wide range of the white mica K-Ar ages from 115 to 41 Ma must be due to a mixture of various amounts of detrital white mica in the separates. This feature is also observed in the chloritoid zone though the age variation is not so large as that in the chlorite zone. In contrast, the mica in the rutile zone, which was higher than 450°C, has been reset completely during Alpine HP metamorphism.