| SHORT COMMUNICATION COMMENTS ON THE RESIDUAL BILINEARIZATION METHOD |
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| 引用本文： | YONGDONG WANG,ODD S.BORGEN,BRUCE R.KOWALSKI Laboratory for Chemometrics,Center for Process Analytical Chemistry and Department of Chemistry,BG-,University of Washington,Seattle,WA,U.S.A. Present address:Perkin-Elmer Corporation,Main Avenue,Norwalk,CT -,U.S.A.. SHORT COMMUNICATION COMMENTS ON THE RESIDUAL BILINEARIZATION METHOD[J]. 地理学报(英文版), 1993, 0(5) |
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| 作者姓名： | YONGDONG WANG ODD S.BORGEN BRUCE R.KOWALSKI Laboratory for Chemometrics Center for Process Analytical Chemistry and Department of Chemistry BG- University of Washington Seattle WA U.S.A. Present address:Perkin-Elmer Corporation Main Avenue Norwalk CT - U.S.A. |
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| 作者单位： | YONGDONG WANG;ODD S.BORGEN;BRUCE R.KOWALSKI Laboratory for Chemometrics，Center for Process Analytical Chemistry and Department of Chemistry，BG-10，University of Washington，Seattle，WA 98195，U.S.A. Present address:Perkin-Elmer Corporation，761 Main Avenue，Norwalk，CT 06859-0284，U.S.A. |
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| 摘 要： | Through theoretical analysis and computer simulation,this short communication comments on theresidual bilinearization(RBL)method and compares it with non-bilinear rank annihilation(NBRA)forthe treatment of second-order calibration with non-bilinear data.It is found that these two methods aremathematically equivalent but have different noise propagation properties.The second-order advantage,namely quantitation in the presence of unknown interferences,can be carried over to non-bilinear dataonly if there exists a net analyte rank(NAR)for the analyte of interest.
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SHORT COMMUNICATION COMMENTS ON THE RESIDUAL BILINEARIZATION METHOD |
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| YONGDONG WANG,ODD S.BORGEN,BRUCE R.KOWALSKI Laboratory for Chemometrics,Center for Process Analytical Chemistry and. SHORT COMMUNICATION COMMENTS ON THE RESIDUAL BILINEARIZATION METHOD[J]. Journal of Geographical Sciences, 1993, 0(5) |
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| Authors: | YONGDONG WANG ODD S.BORGEN BRUCE R.KOWALSKI Laboratory for Chemometrics Center for Process Analytical Chemistry and |
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| Affiliation: | YONGDONG WANG,ODD S.BORGEN,BRUCE R.KOWALSKI Laboratory for Chemometrics,Center for Process Analytical Chemistry and Department of Chemistry,BG-,University of Washington,Seattle,WA,U.S.A. Present address:Perkin-Elmer Corporation,Main Avenue,Norwalk,CT -,U.S.A. |
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| Abstract: | Through theoretical analysis and computer simulation,this short communication comments on the residual bilinearization(RBL)method and compares it with non-bilinear rank annihilation(NBRA)for the treatment of second-order calibration with non-bilinear data.It is found that these two methods are mathematically equivalent but have different noise propagation properties.The second-order advantage, namely quantitation in the presence of unknown interferences,can be carried over to non-bilinear data only if there exists a net analyte rank(NAR)for the analyte of interest. |
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| Keywords: | Calibration Rank annihilation Residual bilinearization Three-way Trilinear Net analyte rank Second-order Generalized rank annihilation method(GRAM) |
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