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Equilibration and disequilibration between monazite and garnet: indication from phase‐composition and quantitative texture analysis
Authors:A BERGER  N C SCHERRER  F BUSSY
Abstract:The integration of information which can be gained from accessory i.e. age (t)] and rock‐forming minerals i.e. temperature (T) and pressure (P)] requires a more profound understanding of the equilibration kinetics during metamorphic processes. This paper presents an approach comparing conventional P–T estimate from equilibrated assemblages of rock‐forming minerals with temperature data derived from yttrium‐garnet‐monazite (YGM) and yttrium‐garnet‐xenotime (YGX) geothermometry. Such a comparison provides an initial indication on differences between equilibration of major and trace elements. Regarding this purpose, two migmatites, two polycyclic and one monocyclic gneiss from the Central Alps (Switzerland, northern Italy) were investigated. While the polycyclic samples exhibit trace‐element equilibration between monazite and garnet grains assigned to the same metamorphic event, there are relics of monazite and garnet obviously surviving independent of their textural position. These observations suggest that surface processes dominate transport processes during equilibration of those samples. The monocyclic gneiss, on the contrary, displays rare isolated monazite with equilibration of all elements, despite comparably large transport distances. With a nearly linear crystal‐size distribution of the garnet grain population, growth kinetics, related to the major elements, were likely surface‐controlled in this sample. In contrast to these completely equilibrated examples, the migmatites indicate disequilibrium between garnet and monazite with a change in REE patterns on garnet transects. The cause for this disequilibrium may be related to a potential disequilibrium initiated by a changing bulk chemistry during melt segregation. While migmatite environments are expected to support high transport rates (i.e. high temperatures and melt presence), the evolution of equilibration in migmatites is additionaly related to change in chemistry. As a key finding, surface‐controlled equilibration kinetics seem to dominate transport‐controlled processes in the investigated samples. This may be decisive information towards the understanding of age data derived from monazite.
Keywords:Alps  equilibration kinetics  monazite thermometry  quantitative textures
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