Major ion chemistry of groundwater in a river basin: a study from India

Groundwater is the prime source in the area of Varaha River Basin, Andhra Pradesh, India. Groundwater samples collected during pre- and post-monsoon were analyzed for major ion chemistry to understand the operating mechanism of geochemical processes for variation of groundwater quality. Low ionic concentration is observed in the groundwater occurring at topographic-highs and towards the river compared to the rest of the area. This is caused by the influence of recharge water. Geochemistry of groundwater is observed to be mainly controlled by the rock-weathering, mineral dissolution, leaching, ion exchange and evaporation, and is subsequently modified by the anthropogenic and marine activities. Contribution of residual soluble salts below the depth of 5 m from the ground surface is high, while it is low beyond the depth of 5 m. Anthropogenic activities cause an accumulation of excess residual soluble salts in the former depth and the content of this soluble matter is reduced by the clay products beyond the latter depth. Seasonal ionic concentration of groundwater is greatly influenced by the recharge process with reference to topographical features, lithological characteristics and anthropogenic activities. Groundwater quality is classified as mixed and non-carbonate alkali groups due to a combined action of geogenic/anthropogenic and marine sources, respectively. The groundwater quality is above the adequacy level for both drinking and irrigation, and appropriate management measures are recommended for sustainable development.