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几种常见矿物的接触角测定及其讨论
引用本文:陆现彩,侯庆锋,尹琳,赵连泽,刘显东.几种常见矿物的接触角测定及其讨论[J].岩石矿物学杂志,2003,22(4):397-400.
作者姓名:陆现彩  侯庆锋  尹琳  赵连泽  刘显东
作者单位:1. 南京大学,地球科学系,江苏省凹土工程技术研究中心,江苏,南京,210093
2. 江苏省表界面工程技术研究中心,江苏,南京,210093
基金项目:国家自然科学基金资助项目 ( 4 0 0 0 3 0 0 2 ),南京大学分析测试基金资助项目 (DK3 -7)
摘    要:为了评价矿物表面与特征液体的界面能量,分别测定了长石、石英、黑云母、方解石、萤石和黄铁矿等7种常见矿物与水、正庚烷和正丁醇的接触角,并计算了相应的表面自由能。结果表明同一矿物不同结晶面(晶面)的接触角有一定的差异,这一差异与矿物结构面上原子种类和相对含量差异有一定的对应关系。

关 键 词:接触角  矿物  结晶学  表面自由能  界面能量  矿物结构
文章编号:1000-6524(2003)04-0397-04
修稿时间:2003年7月31日

Measurement of contact angles of several common minerals and its discussion
LU Xian_cai,HOU Qing_feng,YIN Lin,ZHAO Lian_ze and LIU Xian_dong.Measurement of contact angles of several common minerals and its discussion[J].Acta Petrologica Et Mineralogica,2003,22(4):397-400.
Authors:LU Xian_cai  HOU Qing_feng  YIN Lin  ZHAO Lian_ze and LIU Xian_dong
Institution:LU Xian_cai 1,HOU Qing_feng 2,YIN Lin 1,ZHAO Lian_ze 1 and LIU Xian_dong 1
Abstract:In this paper, the contact angles between common minerals and water, n_heptane and n_butanol are reported. Seven common minerals, i.e., quartz, biotite, fluorite, pyrite, calcite, microcline and perthite, were polished and measured, and the surface free energies were calculated based on the Young's Equation. The results indicate that most of the crystalline planes are partially wetted by water and fully wetted by n_heptane and n_butanol. Furthermore, the heterogeneity between different crystalline planes is found, which could be attributed to the distinctive density of atoms of different elements as shown from the crystalline lattices. The data obtained and the viewpoint held in this paper will be helpful to understanding the interface process between the mineral and the liquid phase.
Keywords:contact angle  mineral  crystallography  surface free energy
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