Surface-water quality for the Salí River watershed in NW Argentina

Spatial and temporal variations of Na, Mg, Si, K, Ca, SO₄^2-, Cl^-, HCO₃^-, Ag, Al, As, Au, B, Ba, Be, Bi, Br, Ce, Cd, Co, Cr, Cs, Cu, Dy, Er, Eu, F, Fe, Ga, Ge, Gd, Hf, Hg, Ho, I, La, Li, Mn, Mo, Nb, Nd, Ni, P, Pb, Pr, Rb, Sb, Sm, Sn, Sr, Ta, Tb, Te, Th, Ti, Tl, U, V, W, Y, Yb, Zn, and Zr were monitored through 37 sampling stations to determine the main aspects influencing the surface-water quality in the Salí River watershed (Tucumán Province, NW Argentina). The influence of the regional geological setting on water chemistry allows to distinguish three sub-basins. The interaction with sedimentary rocks was found to be dominant in the northern and central-eastern sub-basin as well as in the southern sub-basin, whereas the metamorphic-granitic basement of the Pampean Ranges was noted in the central sub-basin. In addition, anthropogenic activities affect the spatial variation of K, P, Mn, Rb, and Pb as well as dissolved oxygen concentrations and Eh. Temporal water-quality variation is related to the spatial distribution of precipitation and to the seasonal character of the main local industries (sugar cane, alcohol, citrus), increasing P and K concentrations and decreasing dissolved oxygen concentration and Eh in winter. Cl^-, Na, SO₄^2-, Al, As, B, Fe, Mn, Se and U concentrations exceed the regulated drinking-water thresholds at several sampling stations.