The role of cavities and mantles in the ultraviolet extinction peak of graphite spheres with particular reference to a possibly discovered C60 structure

A computer routine using rigorous Güttler theory was developed to consider effects of concentric cavities and organic mantles within and around graphite spheres, with a view to assessing the stability of the extinction peak near 4.60 m^–1. The newly discovered stable carbon molecule of 60 atoms gives an absorption band at 4.60 m^–1 which closely agrees with the observed; moreover, it leads to the observed extinction rise in the far UV and can possibly explain the fine structure around the 5.5–7 m^–1 dip, while its own structure deals successfully with the main objections to previous carbon-graphite models. The role of the electric vector component perpendicular to the basal plane of the crystal in achieving the fit is stressed.