In situ laboratory X-ray powder diffraction study of wollastonite carbonation using a high-pressure stage |
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Authors: | Pamela S Whitfield Lyndon D Mitchell |
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Institution: | aInstitute for Chemical Process and Environmental Technology, National Research Council Canada, 1200 Montreal Road, Ottawa ON, Canada K1A 0R6;bInstitute for Research in Construction, National Research Council Canada, 1200 Montreal Road, Ottawa ON, Canada K1A 0R6 |
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Abstract: | A high-pressure gas stage, recently developed for in-situ X-ray powder diffraction studies of polymer crystallization under CO2, has been used to observe the carbonation of wollastonite under various temperature/pressure conditions despite the fact that the stage was not designed for use with moisture-containing samples. The rate of carbonation of wollastonite at 60 °C was found to be pressure-independent. Additional experiments at 34.5 bar between 43 and 73 °C enabled an activation energy of 53 kJ mol−1 to be determined for the rate-limiting step. This value agrees very well with a published value for the leaching of Ca from wollastonite in acidic conditions and suggests that Ca leaching is the rate-limiting step in wollastonite carbonation at these temperatures. |
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