Solar-wind interactions with the moon: Nature and composition of nitrogen compounds

The lunar atmosphere and magnetic field are very tenuous. The solar wind, therefore, interacts directly with the lunar surface material and the dominant nature of interaction is essentially complete absorption of solar-wind particles by the surface material resulting in no upstream bowshock, but a cavity downstream. The solar-wind nitrogen ion species induce and undergo a complex set of reactions with the elements of lunar material and the solar-wind-derived trapped elements. The nitrogen concentration indigeneous to the lunar surface material is practically nil. Therefore any nitrogen and nitrogen compounds found in the lunar surface material are due to the solar-wind implantation of nitrogen ions. The flux of the solar-wind nitrogen ion species is about 6×10³ cm^–2 s^–1. Since there is no evidence for accumulation of nitrogen species in the lunar surface material, the outflux of nitrogen species from the lunar material to the atmosphere is the same as the solar-wind nitrogen ion flux. The species of the outflux are primarily NO and NH₃, and their respective concentrations in the near surface lunar atmosphere are found by calculation to be 327 and 295 cm^–3. The calculated concentration of NH₃ seems to be consistent with the sunrise concentration results of the mass spectrometer implanted on the lunar surface. This is not the case for the concentration of NO. According to the presently calculated concentration value of NO, the mass spectrometer should have detected NO at sunrise, but no report was made for its detection. There is also discrepancy about the concentration of N₂ which is explained in this paper. The concentrations of nitrogen species in the lunar material at the time of sample collection on the Moon remained about the same when the samples were analyzed on the Earth. However, no specific experiment was planned to detect the nitrogen species in the lunar material samples.