Chromite in Komatiites, II. Modification during Greenschist to Mid-Amphibolite Facies Metamorphism

Chromite compositions in komatiites are influenced by metamorphicprocesses, particularly above 500°C. Metamorphosed chromiteis substantially more iron rich than igneous precursors, asa result of Mg–Fe exchange with silicates and carbonates.Chromite metamorphosed to amphibolite facies is enriched inZn and Fe, and depleted in Ni, relative to lower metamorphicgrades. Relative proportions of the trivalent ions Cr³⁺, Al³⁺and Fe³⁺ are not greatly modified by metamorphism up to loweramphibolite facies, although minor Fe³⁺ depletion occurs duringtalc–carbonate alteration at low temperature. SignificantAl is lost from chromite cores above 550°C, as a resultof equilibration with fluids in equilibrium with chlorite. ElevatedZn content in chromite is restricted to rocks with low (metamorphic)Mg/Fe ratios, and is the result of introduction of Zn duringlow-temperature alteration, with further concentration and homogenizationduring prograde metamorphism. Cobalt and Mn also behave similarly,except where carbonate minerals are predominant in the metamorphicassemblage. Chromite at amphibolite facies is typically extensivelyreplaced by magnetite. This is the result of incomplete metamorphicreaction between chromite and chlorite-bearing silicate assemblages.Magnetite compositions at the inner chromite–magnetiteboundary are indicators of metamorphic grade. KEY WORDS: chromite; komatiite; spinel; metamorphism; Zn