Determination of the HCl dissociation constant at a temperature of 350°C and 200 bars of pressure by the potentiometric method using a ceramic electrode |
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Authors: | V V Reukov A V Zotov |
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Institution: | (1) Institute of Geology of Ore Deposits, Petrography, Mineralogy, and Geochemistry, Russian Academy of Sciences, Staromonetnyi per. 35, Moscow, 119017, Russia |
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Abstract: | A technique has been developed for pH measurement in flow-through cells at temperatures from 175 to 350°C and pressures up to 350 bars in a nonisothermal cell consisting of a ZrO2(Y2O3) ceramic electrode and a Ag/AgCl (2 M KCl, 25°C) flow-through reference electrode. This technique has been applied to determination of the HCl dissociation constant at 350°C and 200 bars; previously, the HCl dissociation has not been studied sufficiently reliably under these conditions. The obtained value pK dis = 2.16 ± 0.03 was used to estimate the acidity of fluids from their chemical composition at the vent of high-temperature submarine hydrothermal solutions. |
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