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土壤中有机碳含量对三氯乙烯的吸附影响实验
引用本文:张坤峰,何江涛,刘明亮,曲雪妍,张 晶.土壤中有机碳含量对三氯乙烯的吸附影响实验[J].岩石矿物学杂志,2009,28(6):649-652.
作者姓名:张坤峰  何江涛  刘明亮  曲雪妍  张 晶
作者单位:中国地质大学,水资源与环境工程北京市重点实验室,北京,100083
基金项目:国家自然科学基金项目,863国家高技术研究发展计划 
摘    要:采用某地区土壤样品,利用批实验的方法,研究不同有机碳含量的土壤样品对三氯乙烯(TCE) 的吸附行为.研究表明,土壤样品中,由于有机碳含量不同,有机污染物三氯乙烯(TEC)的吸附量不同,存在有机碳含量的阈值区间(foc*).最小foc*=0.702%,最大foc*=1.831%,当foc<0.702%时,TCE吸附量随土壤样品的有机碳含量变化较小,基本不随foc变化而发生较大变化;在0.702%1.831%时,TCE吸附量随土壤样品的有机碳含量变化又变得平缓,基本上又不随foc升高而发生较大的变化.

关 键 词:三氯乙烯  吸附  有机碳  阈值区间

The effects of different contents of organic carbon on the adsorption of trichlorinated hydrocarbon in soil
ZHANG Kun_feng,HE Jiang_tao,LIU Ming_liang,QU Xue_yan and ZHANG Jing.The effects of different contents of organic carbon on the adsorption of trichlorinated hydrocarbon in soil[J].Acta Petrologica Et Mineralogica,2009,28(6):649-652.
Authors:ZHANG Kun_feng  HE Jiang_tao  LIU Ming_liang  QU Xue_yan and ZHANG Jing
Abstract:The adsorption of organic contaminants in soil is one of the most important factors affecting the migration and transformation process of these organic contaminants. Using batch experiments, this paper studied the adsorption behaviors of Trichloroethylene (TCE) in soil samples with different contents of organic carbon. The results indicate that the adsorption capacity is significantly correlated with different contents of organic carbon. There exist critical threshold values (f_∝~*) of organic carbon contents. The minimum f_∝~* and the maximum f_∝~* are equal to 0.702% and 1.831%, respectively. The TCE adsorption capacity does not vary greatly with the increasing of organic carbon contents when f_∝ is lower than 0.702% . Nevertheless, the TCE adsorption capacity varies considerably with the increasing of organic carbon contents when 0.702%
Keywords:trichloroethylene (TCE)  adsorption  organic carbon  critical threshold value
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