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深部煤层CO2注入过程中煤体积参数变化的模拟实验
引用本文:张琨,桑树勋,刘长江.深部煤层CO2注入过程中煤体积参数变化的模拟实验[J].煤田地质与勘探,2018,46(5):26-31.
作者姓名:张琨  桑树勋  刘长江
作者单位:中国矿业大学煤层气资源与成藏过程教育部重点实验室;中国矿业大学资源与地球科学学院;中国石油大学地球科学与技术学院
基金项目:国家自然科学基金项目(41330638);国家重点研发计划项目(2018YFB0605600)
摘    要:CO2注入煤层会改造储层孔裂隙结构,对提高CO2埋藏和强化甲烷抽采能力产生重要影响。为探究CO2注入后的煤体结构演化规律,选择山西沁水盆地寺河矿无烟煤和新源矿焦煤样品进行模拟实验,通过测试并分析CO2注入前后煤体积参数的变化,得到以下结论:CO2的注入可以溶蚀煤中矿物,增加连通孔隙体积并引起有机质的膨胀;矿物溶蚀对孔隙体积变化的贡献不显著,却导致大量封闭孔转换为连通孔,其中大于40μm的大孔孔隙体积增幅最大;有机质的膨胀量较大,其对孔隙的挤压作用可能会降低煤体的连通性;CO2注入对煤体结构的改造作用受煤级和模拟埋深条件的共同影响。 

关 键 词:CO2地质存储    煤体积    矿物溶蚀    煤基质膨胀
收稿时间:2018-05-12

Simulation experiment on the changes of CO2 burial process in deep coal seam
Abstract:The injection of carbon dioxide(CO2)will change the pore fissure structure of coal seam, which has important influence on improving the capacity of CO2 burial and enhancing methane extraction. In order to explore the evolution law of coal structure after CO2 injection, the Sihe anthracite and Xinyuan coking-lean coal in Qinshui basin were chosen to do the simulation experiment, through the test and analysis of the coal volume parameter before and after CO2 treatment, the following conclusions were obtained:CO2 injection can dissolve minerals in coal, which increases the volume of connected pores and causes the expansion of organic matter; the contribution of mineral dissolution to pore volume changes is not significant, while it leads to the conversion of a large number of closed pores into interconnected pores; the maximum volume increase of pore diameter is larger than 40 μm; the expansion of organic matter is comparatively large and its squeezing effect on pores may reduce the connectivity of coal; the effect of CO2 injection on coal structure is influenced by coal ranks and simulated burial depth. 
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