南海神狐海域沉积物自生黄铁矿和石膏S同位素特征及对甲烷渗漏强度的示踪

The northern slope of the South China Sea is a gas-hydrate-bearing region related to a high deposition rate of organic-rich sediments co-occurring with intense methanogenesis in subseafloor environments.Anaerobic oxidation of methane(AOM) coupled with bacterial sulfate reduction results in the precipitation of solid phase minerals in seepage sediment,including pyrite and gypsum.Abundant aggregates of pyrites and gypsums are observed between the depth of 667 and 850 cm below the seafloor(cmbsf) in the entire core sediment of HS328 from the northern South China Sea.Most pyrites are tubes consisting of framboidal cores and outer crusts.Gypsum aggregates occur as rosettes and spheroids consisting of plates.Some of them grow over pyrite,indicating that gypsum precipitation postdates pyrite formation.The sulfur isotopic values(δ~(34) S) of pyrite vary greatly(from –46.6‰ to –12.3‰ V-CDT) and increase with depth.Thus,the pyrite in the shallow sediments resulted from organoclastic sulfate reduction(OSR) and is influenced by AOM with depth.The relative high abundance and δ~(34) S values of pyrite in sediments at depths from 580 to 810 cmbsf indicate that this interval is the location of a paleo-sulfate methane transition zone(SMTZ).The sulfur isotopic composition of gypsum(from–25‰ to –20.7‰) is much lower than that of the seawater sulfate,indicating the existence of a 34 S-depletion source of sulfur species that most likely are products of the oxidation of pyrites formed in OSR.Pyrite oxidation is controlled by ambient electron acceptors such as MnO_2,iron(Ⅲ) and oxygen driven by the SMTZ location shift to great depths.The δ~(34) S values of gypsum at greater depth are lower than those of the associated pyrite,revealing downward diffusion of 34 S-depleted sulfate from the mixture of oxidation of pyrite derived by OSR and the seawater sulfate.These sulfates also lead to an increase of calcium ions from the dissolution of calcium carbonate mineral,which will be favor to the formation of gypsum.Overall,the mineralogy and sulfur isotopic composition of the pyrite and gypsum suggest variable redox conditions caused by reduced seepage intensities,and the pyrite and gypsum can be a recorder of the intensity evolution of methane seepage.     

CARBON DYNAMICS OF WETLAND IN THE SANJIANG PLAIN

1INTRODUCTIONWetlandsplayanimportant roleintheprocessofcar-bonstorage.Thetotalcarbonstoredindifferentkindsofwetlandsisabout15%-35%ofthetotalcarboninthegloballandsoils(POSTetal.,1982;GORHAM,1991).Inaddition,wetlandsaresignificantnaturalsources fortheatmospheric CH4 (MOORE,1994).It isestimatedthatabout110×1012gCH4 originates fromanaerobicdecompositioninthenaturalwetlands,CH4 emission fromthenaturalwetlandsis15%-30%oftheglobalCH4 emission andtheCH4 emission from thepeat land at hi…     

一种甲烷连续测量系统的开发并用于某些源区甲烷分布的研究

为了调查大气甲烷的区域分布，我们用火焰离子检测器（ＦＩＤ）制成了一台连续测量系统。由于ＦＩＤ几乎对所有的烃类都敏感，故而让样气通过一个装有Ｐｔ催化剂的加热柱体以除去非甲烷烃，得到低达０．００４×１０＾－６Ｖ的检出限和短达１０ｓ的响应时间。我们把该系统装配在汽车上，测量了两个典型源区－稻田和天然气田上大气甲烷的区域分布。在气田的实例中，我们依据所观测的甲烷柱剖面估算了甲烷的逸散率。     

墨西哥湾GC238区冷泉碳酸盐岩的微结构与石化微生物特征

采于墨西哥湾GC238海底天然气渗漏区浅表层的冷泉碳酸盐岩呈结核状产出,由方解石微晶和胶结物及少量的黄铁矿构成。胶结物由直径为0.1～0.5 m的方解石化的球体、卵形体、棒状体组成,充填于方解石晶体之间。冷泉碳酸盐岩结核下表面发育有由方解石化的球体、卵形体、棒状体组成的薄层,其中的一些球状集合体（约5 m）断面显示发育有核和外壳的层圈结构。黄铁矿呈草莓状,也具有相似的层圈结构。这种层状结构与活体古细菌被硫酸盐还原细菌包裹的层圈结构相似。样品中所保存的球体、卵形体、棒状体及其所组成的层圈结构可能是石化的甲烷氧化古细菌和硫酸盐还原细菌。     

海底甲烷逸出处碳酸盐结核的形成

在库页岛东北岛坡出现甲烷水合物的地方，发现碳酸盐结核。提出了碳酸盐结核化学形成硫酸盐还原与甲烷生成作用使孔隙水呈现高碱性，是查出产生结核的必要预备阶段。借助甲烷将溶解于孔隙水中的二氧化碳气体排出，是形成结核的必须条件。     

墨西哥湾西北部陆坡气体水合物资源评价

气体水合物是一种似冰状的结晶物质 ,烃类和非烃类气体赋存于水分子笼形格架内。全球海底气体水合物储集层可能含有２×１０１４（Ｓｏｌｏｖｉｅｗ，２０００）～７．６×１０１７ ｍ３（Ｄｂｒｙｎｉｎ等，１９８１）的甲烷。目前 ,在墨西哥湾西北部陆坡水深４４０～＞２４００ｍ处采集了５０个热成因和细菌成因的气体水合物样品。通过活塞柱状取样和科学考察深潜器 ,研究者已经从海底取到细菌成因Ⅰ型构造的甲烷水合物和热成因Ⅱ型和Ｈ型的气体水合物。近年来 ,ＧＯＭ (墨西哥湾 )深水区已经成为对石油勘探具有重要意义的地区。１９９９…     

蒙特卡罗法在天然气水合物资源量计算中的应用

天然气水合物甲烷资源量的估算是天然气水合物研究中的热点问题。运用体积法计算含水合物沉积物中的甲烷资源量时,存在参数赋值不确定的问题,从而影响了计算结果的可信度。采用蒙特卡罗法,通过计算样本的频率可以较好地评价和描述计算结果的信度,弥补体积法的不足。对采用蒙特卡罗法估算甲烷资源量的原理进行了分析和探讨,并以麦肯齐三角洲和南海海域水合物为例,计算了水合物赋存区的甲烷资源量。