Pressure-induced incipient amorphization of α-quartz and transition to coesite in an eclogite from Antarctica: a first record and some consequences

Monocrystalline quartz inclusions in garnet and omphacite from various eclogite samples from the Lanterman Range (Northern Victoria Land, Antarctica) have been investigated by cathodoluminescence (CL), Raman spectroscopy and imaging, and in situ X‐ray (XR) microdiffraction using the synchrotron. A few inclusions, with a clear‐to‐opalescent lustre, show ‘anomalous’ Raman spectra characterized by weak α‐quartz modes, the broadening of the main α‐quartz peak at 465 cm^?1, and additional vibrations at 480–485, 520–523 and 608 cm^?1. CL and Raman imaging indicate that this ‘anomalous’α‐quartz occurs as relicts within ordinary α‐quartz, and that it was preserved in the internal parts of small quartz inclusions. XR diffraction circular patterns display irregular and broad α‐quartz spots, some of which show an anomalous d‐spacing tightening of ～2%. They also show some very weak, hazy clouds that have d‐spacing compatible with coesite but not with α‐quartz. Raman spectrometry and XR microdiffraction characterize the anomalies with respect to α‐quartz as (i) a pressure‐induced disordering and incipient amorphization, mainly revealed by the 480–485 and 608‐cm^?1 Raman bands, together with (ii) a lattice densification, evidenced by d‐spacing tightening; (iii) the cryptic development of coesite, 520–523 cm^?1 being the main Raman peak of coesite and (iv) Brazil micro‐twinning. This ‘anomalous’α‐quartz represents the first example of pressure‐induced incipient amorphization of a metastable phase in a crustal rock. This issue is really surprising because pressure‐induced amorphization of metastable α‐quartz, observed in impactites and known to occur between 15 and 32 GPa during ultrahigh‐pressure (UHP) experiments at room temperature, is in principle irrelevant under normal geological P–T conditions. A shock (due to a seism?) or a local overpressure at the inclusion scale (due to expansion mismatch between quartz and its host mineral) seem the only geological mechanisms that can produce such incipient amorphization in crustal rocks. This discovery throws new light on the modality of the quartz‐coesite transition and on the pressure regimes (non‐lithostatic v. lithostatic) during high‐pressure/UHP metamorphism. In particular, incipient amorphization of quartz could favour the quartz‐coesite transition, or allow the growth of metastable coesite, as already experimentally observed.     

Gamma暴余辉的相对论流体动力学演化和光变曲线

本文首先对Gamma暴的观测特性和物理过程作了简要的介绍 ,而后 ,对火球模型的相对论流体动力学机制和同步加速辐射机制作了论述。主要工作是 :具体研究火球所抛出壳层的相对论流体动力学演化 ,应用同步加速辐射机制 ,通过由共动坐标系到实验室坐标系的相对论变换 ,得到Gamma暴余辉的光变曲线。对于火球壳层的不同的动力学演化规律 ,各向同性或各向异性的壳层抛出形式 ,以及不同的外部介质环境 ,所得到的光变曲线都各不相同。通过对这些不同的光变曲线的比较 ,明确了Gamma暴余辉的整体的物理演化图象以及各种物理过程在Gamma暴余辉演化过程中所起的作用 ,并从余辉演化的方面进一步理解了Gamma暴的物理本质     

In situ time resolved synchrotron powder diffraction study of thaumasite

Structural changes during dehydration and subsequent decomposition in thaumasite Ca₃Si(SO₄)(CO₃)(OH)₆·12 H₂O were studied by in situ synchrotron powder diffraction between 303 and 1,098 K. Evolution of the crystal structure was observed through 28 structure refinements, by full profile Rietveld analysis performed in the P6₃ space group, between 300 and 417 K, whereupon the thaumasite structure was observed to breakdown. Within this temperature range, the cell parameters of thaumasite increased as a function of temperature in a nearly linear fashion up to about 393 K, at which temperature, a slight slope change was observed. Above 400 K, the thermogravimetric analysis revealed that the dehydration process proceeded very rapidly while the refined occupancy of water molecules dropped below a critical level, leading to instability in the thaumasite structure. At a same time, a remarkable change in the unit cell parameters occurring at about 417 K indicated that the crystal structure of thaumasite collapsed on losing the crystallization water and it turned amorphous. This result indicated that the dehydration/decomposition of thaumasite was induced by the departure of the crystallization water. At about 950 K, anhydrite and cristobalite crystallized from the thaumasite glass.     

同步辐射软X射线吸收谱与发射谱测定天然针铁矿能带结构

天然半导体矿物由于成分、缺陷复杂,传统测试方法如紫外可见漫反射等难以准确测定其禁带宽度.本文以针铁矿为例,通过第一性原理计算得到纯针铁矿及掺Al针铁矿的电子结构.计算结果显示,纯针铁矿导带底与价带顶均由Fe3d与O2p轨道组成,而当含杂质Al时,Al2p与O2p发生杂化参与了价带组成.在此基础上,利用同步辐射X射线氧的K边吸收谱与发射谱对纯针铁矿及天然针铁矿的能带结构进行了测定.结果表明,天然含Al的针铁矿禁带宽度为2.30eV,小于纯针铁矿(2.57eV).本研究提供了一种测定天然氧化物矿物禁带宽度的新方法,为深入研究天然半导体可见光催化活性产生机制提供了理论依据.     

微束分析测试技术十年(2011~2020)进展与展望

现代地球科学研究的重大突破在很大程度上取决于观测和分析技术的创新。新世纪以来,我国地球科学领域引进了一批高性能新型微束分析仪器设备,建立了一批高规格的实验室。本文回顾了近十年来微束分析技术与方法的主要进展及其在地球科学研究中的应用实例,包括电子探针、扫描电镜、透射电镜、大型离子探针、纳米离子探针、飞行时间二次离子质谱、激光剥蚀等离子体质谱、激光诱导原子探针、原子探针技术、显微红外光谱、同步辐射等,这些分析技术的进步和广泛应用极大地提高了我们对地球和行星演化历史及许多地质过程的理解。今后,应加快微束分析的新技术、新方法和新标准的开发,特别是高水平人才队伍建设,提高创新能力并在国际学术舞台上发挥重要作用。     

The strain‐dependent spatial evolution of garnet in a high‐P ductile shear zone from the Western Gneiss Region (Norway): a synchrotron X‐ray microtomography study

Reaction and deformation microfabrics provide key information to understand the thermodynamic and kinetic controls of tectono‐metamorphic processes, however, they are usually analysed in two dimensions, omitting important information regarding the third spatial dimension. We applied synchrotron‐based X‐ray microtomography to document the evolution of a pristine olivine gabbro into a deformed omphacite–garnet eclogite in four dimensions, where the 4^th dimension is represented by the degree of strain. In the investigated samples, which cover a strain gradient into a shear zone from the Western Gneiss Region (Norway), we focused on the spatial transformation of garnet coronas into elongated garnet clusters with increasing strain. The microtomographic data allowed quantification of garnet volume, shape and spatial arrangement evolution with increasing strain. The microtomographic observations were combined with light microscope and backscatter electron images as well as electron microprobe (EMPA) and electron backscatter diffraction (EBSD) analysis to correlate mineral composition and orientation data with the X‐ray absorption signal of the same mineral grains. With increasing deformation, the garnet volume almost triples. In the low‐strain domain, garnet grains form a well interconnected large garnet aggregate that develops throughout the entire sample. We also observed that garnet coronas in the gabbros never completely encapsulate olivine grains. In the most highly deformed eclogites, the oblate shapes of garnet clusters reflect a deformational origin of the microfabrics. We interpret the aligned garnet aggregates to direct synkinematic fluid flow, and consequently influence the transport of dissolved chemical components. EBSD analyses reveal that garnet shows a near‐random crystal preferred orientation that testifies no evidence for crystal plasticity. There is, however evidence for minor fracturing, neo‐nucleation and overgrowth. Microprobe chemical analysis revealed that garnet compositions progressively equilibrate to eclogite facies, becoming more almandine‐rich. We interpret these observations as pointing to a mechanical disintegration of the garnet coronas during strain localization, and their rearrangement into individual garnet clusters through a combination of garnet coalescence and overgrowth while the rock was deforming.     

同步辐射标定平面镜反射率不确定度分析方法研究

为了提高多通道软X射线能谱仪的测量精度,2009年在北京同步辐射(BSRF)软X束线源上对多种材料的掠入射平面镜的反射率进行了标定.在标定实验的基础上,对光源的单色性、高次谐波以及源强稳定性、探测器响应一致性和数据采集统计误差等多项不确定因素进行了评估,给出了反射率的修正方法和相应的不确定度分析结果.     

Preliminary Study on the Chemical Mapping of Individual Fluid Inclusion by Synchrotron X-ray Fluorescence Microprobe

Abstract: Synchrotron X-ray fluorescence analyses on individual hypersaline fluid inclusions were tested to using synchrotron source at Tsukuba (KEK), Japan. The XRF instrumentation at KEK meets the purpose of fluid inclusion analysis, nondestructive, multi–element, ppm detection limits, with micro spatial resolution. In practice, however, the quantitative chemical analysis of fluid inclusion requires further considerable data accumulation. Semi-quantitative distribution of elements (mass number > 25) in single fluid inclusion was obtained.     

The use of sintered diamond anvils in the MA8 type high-pressure apparatus

A new multi-anvil type high-presure apparatus has been developed using sintered diamond anvils to generate pressures over 30 GPa and temperatures up to about 2000°C. A maximum sample volume of about 1 mm³ is available in this system. The pressure was confirmed by dissociation of forsterite into Mg-perovskite and periclase. The basic techniques and problems in utilizing sintered diamond in the MA8 type high-pressure apparatus are discussed with an emphasis on the future prospect of incorporating simultancous X-ray diffraction observation.