沉积盆地有机质自由基热演化特征及其作为古温标的探索

恢复沉积盆地热历史的方法主要有古地温指标法和动力学模拟法两类.古温标法中最常用的为有机质成熟度和矿物裂变径迹,动力学模拟法中最常用的是盆地的拉张模型和挤压模型.本文针对Ⅰ型有机质自由基浓度作为沉积盆地古温标进行了探索研究.分析了自然演化系列Ⅰ型有机质的自由基的热演化特征;根据自然演化系列的Ⅰ型有机质自由基浓度及时间-温度指数(TTI)数据,对热模拟实验下的Ⅰ型有机质自由基浓度及时间-温度指数(TTI)值进行校正,由校正后的数据初步建立了Ⅰ型有机质的自由基浓度(Ng)与时间-温度指数(TTI)的定量模型.     

Low temperature volatile production at the Lost City Hydrothermal Field, evidence from a hydrogen stable isotope geothermometer

Although commonly utilized in continental geothermal work, the water-hydrogen and methane-hydrogen isotope geothermometers have been neglected in hydrothermal studies. Here we report δD-CH₄ and δD-H₂ values from high-temperature, black smoker-type hydrothermal vents and low-temperature carbonate-hosted samples from the recently discovered Lost City Hydrothermal Field. Methane deuterium content is uniform across the dataset at − 120 ± 12‰. Hydrogen δD values vary from − 420‰ to − 330‰ at high-temperature vents to − 700‰ to − 600‰ at Lost City. The application of several geothermometer equations to a suite of hydrothermal vent volatile samples reveals that predicted temperatures are similar to measured vent temperatures at high-temperature vents, and 20-60 °C higher than those measured at the Lost City vents. We conclude that the overestimation of temperature at Lost City reflects 1) that methane and hydrogen are produced by serpentinization at > 110 °C, and 2) that isotopic equilibrium at temperatures < 70 °C is mediated by microbial sulfate reduction. The successful application of hydrogen isotope geothermometers to low-temperature Lost City hydrothermal samples encourages its employment with low-temperature diffuse hydrothermal fluids.     

Hydrogeochemistry of the Simav geothermal field, western Anatolia, Turkey

Thermal waters hosted by Menderes metamorphic rocks emerge along fault lineaments in the Simav geothermal area. Thermal springs and drilled wells are located in the Eynal, Çitgöl and Na a locations, which are part of the Simav geothermal field. Studies were carried out to obtain the main chemical and physical characteristics of thermal waters. These waters are used for heating of residences and greenhouses and for balneological purposes. Bottom temperatures of the drilled wells reach 163°C with total dissolved solids around 2225 mg/kg. Surface temperatures of thermal springs vary between 51°C and 90°C. All the thermal waters belong to Na–HCO₃–SO₄ facies. The cold groundwaters are Ca–Mg–HCO₃ type. Dissolution of host rock and ion-exchange reactions in the reservoir of the geothermal system shift the Ca–Mg–HCO₃ type cold groundwaters to the Na–HCO₃–SO₄ type thermal waters. Thermal waters are oversaturated at discharge temperatures for aragonite, calcite, quartz, chalcedony, magnesite and dolomite minerals giving rise to a carbonate-rich scale. Gypsum and anhydrite minerals are undersaturated with all of the thermal waters. Boiling during ascent of the thermal fluids produces steam and liquid waters resulting in an increase of the concentrations of the constituents in discharge waters. Steam fraction, y, of the thermal waters of which temperatures are above 100°C is between 0.075 and 0.119. Reservoir pH is much lower than pH measured in the liquid phase separated at atmospheric conditions, since the latter experienced heavy loss of acid gases, mainly CO₂. Assessment of the various empirical chemical geothermometers and geochemical modelling suggest that reservoir temperatures vary between 175°C and 200°C.     

Chemical equilibria of thermal waters for the application of geothermometers from the Guanzhong basin, China

In this study, representative samples from thermal wells and springs were chemically analyzed and geothermometers were used to calculate the deep temperatures of geothermal reservoirs on the basis of water–mineral equilibrium. In some cases, however, the chemical components are not in equilibrium with the minerals in the reservoir. Therefore, log(Q/K) diagrams are used to study the chemical equilibrium for the minerals that are likely to participate. The Na–K–Mg triangular diagram is also applied to evaluate the equilibrium of water with reservoir rocks. Standard curves at the reference temperatures are prepared to reveal which type of silica geothermometer is appropriate for the specified condition. This study shows that water samples from geothermal wells W9 and W12 are in equilibrium with the selective minerals, and chalcedony may control the fluid–silica equilibrium. It is estimated that there is an exploitable low-temperature reservoir with possible temperatures of 80–90°C in the Guanzhong basin.     

An Experimental Calibration on the Sphalerite-Galena Sulfur Isotope Geothermometer

A new experimental calibration was undertaken in this study to get a more reliable sphalerite-galena sulfur isotope geothermometer. The experimental conditions selected in study were very similar to those of natural hydrothermal solution. The high-precision SF6 method was used in sulfur isotope analyses. The obtained calibration curve for sulfur isotope fractionation between sphalerite and galena can be expressed with the equation 10001nαSp-Gn= 0.74×106T-2+0.08.     

高压超高压变泥质岩适用的地质温压计评述

高压超高压变泥质岩形成温压条件及p-T演化轨迹是高压超高压变质作用研究的重要内容。本文介绍了高压超高压变泥质岩适用的几种地质温压计,包括石榴子石-多硅白云母Fe~(2+)-Mg交换温度计、石榴子石-绿泥石Fe~(2+)-Mg交换温度计、硬绿泥石-绿泥石Fe~(2+)-Mg交换温度计、多硅白云母Si含量压力计、金红石Zr含量温度计、榍石Zr含量温压计、锆石Ti含量温度计、石英Ti含量温度计以及氧同位素温度计,并对上述温压计的适用条件及使用时的注意事项做了简要评述。     

包头—忽鸡沟一带麻粒岩相岩石的矿物学和结晶P-T条件

本文提供了77个石榴石、辉石、角闪石、黑云母和斜长石等单矿物能谱和湿化学分析资料,研究了各种矿物对的分配系数。用二辉石地质温度计估算的变质作用温度为770—860℃,用其他矿物对估算的温度多数在二辉石温度计获得的温度范围内。用Wood的石榴石—斜方辉石地质压力计和Newton—Perkins以及Wells石榴石—斜方辉石—斜长石地质压力计公式估算的变质作用压力为(8—10)×10~8Pa,地热梯度为24.6—27.5℃/km,属低—中压型麻粒岩相。     

A Report on a Biotite-Calcic Hornblende Geothermometer

This paper presents a biotite-calcic hornblende geothermometer which was empirically calibrated based on the gamet-biotite geothermometer and the gamet-plagioclase-hornblende-quartz geobarometer, in the ranges of 560-800℃ (T) and 0.26-1.4 GPa (P) using the data of metadolerite, amphibolite, metagabbro, and metapelite collected from the literature. Biotite was treated as symmetric Fe-Mg-AlVI-Ti quaternary solid solution, and calcic hornblende was simplified as symmetric Fe-Mg binary solid solution. The resulting thermometer may rebuild the input garnet-biotite temperatures well within an uncertainty of ±50℃. Errors of ±0.2 GPa for input pressure, along with analytical errors of ?% for the relevant mineral compositions, may lead to a random error of ±16℃ for this thermometer, so that the thermometer is almost independent of pressure estimates. The thermometer may clearly discriminate different rocks of lower amphibolite, upper amphibolite and granulite facies on a high confidence level. It is assume     

Quartz-Ferberite Oxygen Isotope Geothermometer and Its Geological Applications

Experiments for oxygen isotope exchange between ferberite and water were carried out and the followingequation on oxygen isotope fractionation between ferberite and water against temperature was obtained:Combining this equation with the equation of Clayton et al. (1972) on oxygen isotope fractionation be-tween quartz and water, an equation on oxygen isotope fractionation between quartz and ferberite was ob-tained:The Bigeleison-Mayer function method was used to calculate the oxygen isotope fractionation betweenquartz and ferberite. The theoretical curve obtained agrees with the experimental calibration results quite wellin the temperature range of study.The above calibrated equation has been used in 5 world famous tungsten deposits to determine their tem-peratures of formation. The results show that the temperature range for an idividual deposit determined by thisgeothermometer agrees with those obtained from fluid inclusion determination and other isotopegeothermometers.     

金川铜镍硫化矿床成矿温度压力计算及成矿机制探讨

本文利用橄榄石温度计、压力计的方法,计算金川超基性岩体主要含矿岩相成岩的温度压力条件。根据计算所得的温压数据、矿石结构特征、含矿岩相的相互接触关系及储量分布,判断矿床成因主要属于深部熔集型,并根据不可逆过程热力学平衡扩散方程,探讨硫化物(Ni~(2+),S~(2-))和硅酸盐熔浆(Si_4~(4-))产生熔集的机制。