He–Ar and Nd–Sr isotopic compositions of late Pleistocene felsic plutonic back arc basin rocks from Ulleungdo volcanic island, South Korea: Implications for the genesis of young plutonic rocks in a back arc basin

We report analyses of noble gases and Nd–Sr isotopes in mineral separates and whole rocks of late Pleistocene (< 0.2 Ma) monzonites from Ulleungdo, South Korea, a volcanic island within the back arc basin of the Japan island arc. A Rb–Sr mineral isochron age for the monzonites is 0.12 ± 0.01 Ma. K–Ar biotite ages from the same samples gave relatively concordant ages of 0.19 ± 0.01and 0.22 ± 0.01 Ma. ⁴⁰Ar/³⁹Ar yields a similar age of 0.29 ± 0.09 Ma. Geochemical characteristics of the felsic plutonic rocks, which are silica oversaturated alkali felsic rocks (av., 12.5 wt% in K₂O + Na₂O), are similar to those of 30 alkali volcanics from Ulleungdo in terms of concentrations of major, trace and REE elements. The initial Nd–Sr isotopic ratios of the monzonites (⁸⁷Sr/⁸⁶Sr = 0.70454–0.71264, ¹⁴³Nd/¹⁴⁴Nd = 0.512528–0.512577) are comparable with those of the alkali volcanics (⁸⁷Sr/⁸⁶Sr = 0.70466–0.70892, ¹⁴³Nd/¹⁴⁴Nd = 0.512521–0.512615) erupted in Stage 3 of Ulleungdo volcanism (0.24–0.47 Ma). The high initial ⁸⁷Sr/⁸⁶Sr values of the monzonites imply that seawater and crustally contaminated pre-existing trachytes may have been melted or assimilated during differentiation of the alkali basaltic magma.A mantle helium component (³He/⁴He ratio of up to 6.5 RA) associated with excess argon was found in the monzonites. Feldspar and biotite have preferentially lost helium during slow cooling at depth and/or during their transportation to the surface in a hot host magma. The source magma noble gas isotopic features are well preserved in fluid inclusions in hornblende, and indicate that the magma may be directly derived from subcontinental lithospheric mantle metasomatized by an ancient subduction process, or may have formed as a mixture of MORB-like mantle and crustal components. The radiometric ages, geochemical and Nd–Sr isotopic signatures of the Ulleungdo monzonites as well as the presence of mantle-derived helium and argon, suggests that these felsic plutonic rocks evolved from alkali basaltic magma that formed by partial melting of subcontinental lithospheric mantle beneath the back arc basin located along the active continental margin of the southeastern part of the Eurasian plate.     

Li2O—B2O3功能材料体系研究概述

本文介绍了碱金属硼酸盐的一些基本知识，主要回顾了其中Ｌｉ２Ｏ—Ｂ２Ｏ３体系的研究历史，讨论了该体系结构与性质的关系并总结了Ｌｉ２Ｏ－Ｂ２Ｏ３晶态及非晶态物质作为新型功能材料的研究进展。     

云南北衙矿区富碱斑岩正长石和白云母的40Ar-39Ar年龄

云南北衙矿区石英正长斑岩岩体在空间上与金、铅锌矿体共生。红泥塘岩体地表岩石正长石的⁴⁰Ar-³⁹Ar坪年龄和等时线年龄为25.89±0.13Ma和25.72±0.7Ma,万洞山岩体地表以下382m钻孔中岩石的正长石坪年龄和等时线年龄为25.53±0.25Ma和25.50±0.07Ma,分别为两个岩体的形成年龄。但是,万洞山岩体地表团块状白云母的坪年龄和等时线年龄为32.50±0.09Ma和32.34±0.04Ma,为白云母的结晶年龄,也可能是主岩的结晶年龄     

Origin of the alkali tonsteins from southwest China: Implications for alkaline magmatism associated with the waning stages of the Emeishan Large Igneous Province

A unique type of Nb–Zr–REE–Ga-enriched alkali tonstein of pyroclastic origin occurs exclusively within the late Permian coal measures of southwest China. The alkali tonsteins are located within the lowest Xuanwei or Longtan formations of Wuchiapingian age, indicating that their age is later than the main episode of Emeishan Large Igneous Province (ELIP) magmatism. The alkali tonsteins have intermediate–felsic Al₂O₃/TiO₂ values (12.6–34.2, mean 22.0), light rare earth element-enriched chondrite-normalised patterns, negative δEu and incompatible element ratios similar to those of ELIP alkaline Nb–Ta-enriched syenites. All available evidence shows that the alkali tonsteins from southwest China originated from coeval ELIP alkaline magmatism. The enrichment of Nb–Zr–REE–Ga in alkali tonsteins is derived from the ELIP alkaline Nb–Ta-enriched volcanic ashes and may represent the last stage of mineralisation associated with the Emeishan mantle plume activity.     

Hydro-geochemistry of groundwater and surface water in Dschang town(West Cameroon): Alkali and alkaline-earth elements ascertain lithological and anthropogenic constraints

This study focuses on the sources of alkali and alkaline-earth elements based on the geochemistry of groundwater and surface water in Dschang concerning environmental and anthropogenic constraints. A comprehensive set of 50 samples from groundwater and surface water were analyzed by ICPMS and processed by spatial interpolation in a GIS environment. The results highlight a geochemical anomaly at the center of the densely inhabited area subject to a profusion of open dumps discharges. This anomaly with the highest spatial contents of Be(Cs, Rb, Mg) suggests an anthropogenic source that demarcates with the lowest alkali and alkaline-earth elements on the peripheral area of Dschang. Other findings include lithological constraints with volcanic rocks being the main source compared to granitoid.The study points out good correlations between Be, Cs, Rb and Mg spatial distributions and physicochemical parameters of waters(K, EC, TDS), and inversely with the lowest p H. p H is established as the most functioning physico-chemical constraint of alkali and alkaline-earth mobility in Dschang. The p H lowest values within the geochemical anomaly also highlight the impact of human activities on water acidity, which later enhance elements mobility and enrichment. Despite low elements contents relative to WHO standards, our findings point out an example of anthropogenic impact on water geochemistry linked to solid waste pollution; it also demonstrates significant anthropogenic changes of environmental physicochemical parameters of prime importance in the mobility and distribution of elements in the study area.Similar assessments should be extended in major towns in Cameroon.     

前寒武纪富铀矿床与热液碱交代作用

本文根据国内外文献资料,提出前寒武纪富铀矿床的形成与碱交代作用在空间上、成因上蕾切相关的认识,并根据碱性热水溶液的性质将前寒武纪富铀矿床分为钠交代型和钾交代型。同时,简述了两种类型矿床的主要特征,成矿地质条件及机理。     

巴尔哲碱性花岗岩稀有稀土矿床地质特征及成因探讨

内蒙古巴尔哲碱性花岗岩稀有稀土特大型矿床是国内首次发现的一种新类型工业矿床,其规模居亚洲第三位.含矿岩体为燕山期碱性花岗岩,岩体普遍矿化,岩体即是矿体,矿石品位富,稀有稀土元素种类多,其共生伴生矿物多达44种,工业矿物以羟硅铍钇铈矿、烧绿石、铌铁矿、锌日光榴石为主.     

Depleted lithosphere from the mantle wedge beneath Tres Lagos, southern Patagonia, Argentina

Anhydrous spinel lherzolite and harzburgite xenoliths from Tres Lagos, situated inboard of the Volcanic Arc Gap (VAG) in southernmost Patagonia, are samples of a depleted lithospheric mantle and can be divided into two major groups: metasomatized and non-metasomatized. Metasomatized samples, which are the minority, are partly mylonitized and their metasomatism is related to this tectonic process. A group of non-metasomatized samples have enriched whole rock LREE-abundances that are not consistent with the depleted LREE-abundances in their clinopyroxenes. Intergranular host basalt infiltration could be responsible for the whole rock LREE enrichments. Their Sr- and Nd-isotopic ratios have also been affected by host basalt infiltration, whereas their high Sr-isotopic ratios point to subsequent contamination by ground-water and/or Ca-rich surface solutions. Similar contamination is thought to cause the decoupling of Sr- and Nd-isotopes (high Sr- and Nd-isotopic ratios) observed in the non-metasomatized samples with depleted whole rock LREE. A two-stage partial melting process could be responsible for the origin of the Tres Lagos xenoliths. Model calculations have shown that in the first stage, 2% of batch melting took place in the garnet peridotite field and subsequently the residue experienced 2–8% batch melting in the spinel peridotite field. The Tres Lagos peridotites have not been affected by subduction-related metasomatic processes and they could represent an old lithospheric mantle.     

海拉尔盆地贝尔凹陷铜体庙组-南屯组储层次生孔隙成因及意义

海拉尔盆地贝尔凹陷白垩系南屯组和铜体庙组凝灰质砂岩、凝灰质泥岩、沉凝灰岩和凝灰岩储层是该区主要产层。油气储集空间以次生孔隙为主。大量碱性矿物组合如柯绿泥石、钠板石、碳钠铝石、方沸石、绿磷石、铈褐帘石、铁绿泥石等的存在,证明发生了大规模碱性溶解和交代作用。晶屑、玻屑、长石和粘土等填隙物均发生不同程度的溶解现象。研究表明,次生孔隙是凝灰质储层大规模碱交代作用的结果,预示盆地深部存在油气储集空间并富集油气。     

湖南道县虎子岩碱性玄武岩及其基性捕虏体成因和地质意义

本文在湖南道县虎子岩地区采集了碱性玄武岩、橄榄辉长岩和基性麻粒岩捕虏体。碱性玄武岩的斑晶为橄榄石(10%~15%),岩石K2O含量为2.88%~3.51%,Mg#值为80,具有洋岛玄武岩的微量元素特征,岩石具有富集的氧同位素组成(7.8‰~11.0‰),可能是其上升到地表后由碳酸盐岩组分的加入及后期风化蚀变作用造成的,其相对均一且为负的εNd(t)值和靠近EMⅡ地幔端员的特点,指示了该玄武岩是拉张构造环境下富集地幔部分熔融的产物。橄榄辉长岩具有弱富集的LREE(La/Yb)N=2.5~3.0)、弱的Eu正异常(δEu=1.03~1.06),其Sr-Nd同位素组成更靠近EMⅡ地幔端员,87Sr/86Sr比值、εNd(t)值及Nd模式年龄均高于碱性玄武岩,说明橄榄辉长岩是先形成的上述玄武岩浆在未到达地表之前局部发生结晶作用后形成的。基性麻粒岩捕虏体具较强的正Eu异常(δEu=1.42~4.41),其重稀土元素含量出现明显的分组特征,强烈亏损U、Th和Nb、Ta、Zr、Hf、Ti等高场强元素,同时Sr-Nd同位素组成显示其具有壳幔混合的特征。本文结合已有研究结果,探讨了岩浆起源和演化,以及与古太平洋板片俯冲有关的构造环境转换。