北京城市绿化的时空动态分析

城市绿化覆盖是城市生态系统的重要组成部分,合理的绿化率和绿化布局可以改善城市环境,提高城市人居适宜性。研究中将2005、2010、2015年北京市土地利用（LUC）数据中的城市居民用地作为城区范围,应用Landsat 5、GF-1影像数据和MODIS产品,利用支持向量机的监督分类方法,提取了2005、2010、2015年的北京市城市绿化覆盖数据,并获取了同期的植被指数（NDVI）数据;继而以城市绿化覆盖率、绿化覆盖均匀度和植被指数为评价指标,在公里栅格和行政区2个尺度上探讨了北京市城市绿化覆盖的空间分布格局和时间变化动态特征。研究表明：① 3个指标在空间和时间2个维度、区县和栅格2个尺度上都表现一致。这反映北京市过去10年中,在绿化面积增加的同时,绿化的空间布局得到优化改善,绿化的质量得到提高。② 2005-2015年,北京市城市绿化覆盖面积由518.93 km² 增加到1405.54 km²,绿化覆盖率由39.9%增加到49.13%,绿化覆盖均匀度由0.598增加到0.653,植被指数由0.42增加至0.5。③ 北京市城市绿化建设存在明显的时空差异。中心城区绿化建设缓慢,成效不明显;重大绿化建设成果主要集中在城市边缘地区和远郊区县。城市绿化改善过程主要发生在2005-2010年。     

新疆和田地区耕地面源污染生态风险评价

随着化肥、农膜等在农业生产中的过量投入，耕地面源污染的程度随之加重。文章选取塔里木河流域上游和田地区为研究区域，依据P-S-R框架理论，构建和田地区耕地面源污染生态风险评价指标体系，加入土壤理化数据，使用生态风险评价模型对和田地区1980 年及2016 年耕地面源污染状况进行生态风险评价，运用耕地生态风险模型、生态风险转移矩阵、Arcgis分析和田地区耕地面源污染时空分异状况。研究结论如下：和田地区1980 年耕地生态风险等级均为II级或III级，呈“中间高，两侧低”分布；2016 年耕地生态风险等级上升至IV级或V级，呈“倒W型”分布，各县耕地面源污染程度较1980 年均有较大幅度的上升，其中墨玉县和于田县在2016 年耕地生态风险等级达到最高的V级，而民丰县因自身生态环境的强脆弱性，同样需要提高关注。根据面源污染“从源头治理”的原则，应切实推进和田地区耕地生态环境保护与治理，提高政府重视程度，增强技术指导，开展试点工作，改善和田地区耕地面源污染现状。     

南海神狐海域沉积物自生黄铁矿和石膏S同位素特征及对甲烷渗漏强度的示踪

The northern slope of the South China Sea is a gas-hydrate-bearing region related to a high deposition rate of organic-rich sediments co-occurring with intense methanogenesis in subseafloor environments.Anaerobic oxidation of methane(AOM) coupled with bacterial sulfate reduction results in the precipitation of solid phase minerals in seepage sediment,including pyrite and gypsum.Abundant aggregates of pyrites and gypsums are observed between the depth of 667 and 850 cm below the seafloor(cmbsf) in the entire core sediment of HS328 from the northern South China Sea.Most pyrites are tubes consisting of framboidal cores and outer crusts.Gypsum aggregates occur as rosettes and spheroids consisting of plates.Some of them grow over pyrite,indicating that gypsum precipitation postdates pyrite formation.The sulfur isotopic values(δ~(34) S) of pyrite vary greatly(from –46.6‰ to –12.3‰ V-CDT) and increase with depth.Thus,the pyrite in the shallow sediments resulted from organoclastic sulfate reduction(OSR) and is influenced by AOM with depth.The relative high abundance and δ~(34) S values of pyrite in sediments at depths from 580 to 810 cmbsf indicate that this interval is the location of a paleo-sulfate methane transition zone(SMTZ).The sulfur isotopic composition of gypsum(from–25‰ to –20.7‰) is much lower than that of the seawater sulfate,indicating the existence of a 34 S-depletion source of sulfur species that most likely are products of the oxidation of pyrites formed in OSR.Pyrite oxidation is controlled by ambient electron acceptors such as MnO_2,iron(Ⅲ) and oxygen driven by the SMTZ location shift to great depths.The δ~(34) S values of gypsum at greater depth are lower than those of the associated pyrite,revealing downward diffusion of 34 S-depleted sulfate from the mixture of oxidation of pyrite derived by OSR and the seawater sulfate.These sulfates also lead to an increase of calcium ions from the dissolution of calcium carbonate mineral,which will be favor to the formation of gypsum.Overall,the mineralogy and sulfur isotopic composition of the pyrite and gypsum suggest variable redox conditions caused by reduced seepage intensities,and the pyrite and gypsum can be a recorder of the intensity evolution of methane seepage.     

Smectite formation in metalliferous sediments near the East Pacific Rise at 13°N

A 43 cm long E271 sediment core collected near the East Pacific Rise(EPR) at 13°N were studied to investigate the origin of smectite for understanding better the geochemical behavior of hydrothermal material after deposition.E271 sediments are typical metalliferous sediments. After removal of organic matter, carbonate, biogenic opal,and Fe-Mn oxide by a series of chemical procedures, clay minerals(2 μm) were investigated by X-ray diffraction,chemical analysis and Si isotope analysis. Due to the influence of seafloor hydrothermal activity and close to continent, the sources of clay minerals are complex. Illite, chlorite and kaolinite are suggested to be transported from either North or Central America by rivers or winds, but smectite is authigenic. It is enriched in iron, and its contents are highest in clay minerals. Data show that smectite is most likely formed by the reaction of hydrothermal Fe-oxyhydroxide with silica and seawater in metalliferous sediments. The Si that participates in this reaction may be derived from siliceous microfossils(diatoms or radiolarians), hydrothermal fluids, or detrital mineral phases. And their δ30 Si values are higher than those of authigenic smectites, which implies that a Si isotope fractionation occurs during the formation because of the selective absorption of light Si isotopes onto Feoxyhydroxides. Sm/Fe mass ratios(a proxy for overall REE/Fe ratio) in E271 clay minerals are lower than those in metalliferous sediments, as well as distal hydrothermal plume particles and terrigenous clay minerals. This result suggests that some REE are lost during the smectite formation, perhaps because their large ionic radii of REE scavenged by Fe-oxyhydroxides preclude substitution in either tetrahedral or octahedral lattice sites of this mineral structure, which decreases the value of metalliferous sediments as a potential resource for REE.     

闭合复位经皮空心钉内固定配合中药3期辨证治疗股骨颈骨折72例

目的：观察闭合复位经皮空心钉内固定配合中药3期辨证治疗股骨颈骨折的临床疗效。方法：将144例股骨颈骨折患者随机分为2组各72例，对照组采用闭合复位经皮空心钉内固定治疗，治疗组在对照组治疗基础上配合使用中药3期辨证治疗。术后随访观察2组患者的骨折愈合时间及骨折不愈合、股骨头缺血性坏死发生情况，并观察末次随访时的髋关节Harris评分。结果：2组术后骨折平均愈合时间、骨折不愈合与股骨头坏死情况及髋关节Harris评分比较，差异均有统计学意义（P＜0.05）。结论：闭合复位经皮空心钉内固定配合中药3期辨证治疗能够促进股骨颈骨折的愈合，有利于髋关节功能的恢复。