对“提升基础地质调查服务能力”新要求的理解与思考

《浙江省自然资源发展“十四五”规划纲要(征求意见稿)》,对基础地质工作提出了“提升服务能力”的新要求,具体是:全面推进区域地质调查、城市地质调查、水工环地质调查、地球物理和地球化学调查,建立基础地质核心数据库;开展精细化土地质量地质调查和天然富硒土地资源详查,建立土地质量地质调查数据库;推进生态功能区和海岸带等综合地质调查.     

青州市表层土壤元素地球化学组合特征研究

聚类分析和因子分析可以获得土壤元素地球化学组合特征及其差异性。对青州市表层土壤样品数据进行分析研究,通过聚类分析,绘制表层土壤元素聚类谱系图,将23种元素或指标分为5个元素组合簇群及2个单元素簇,研究各元素间的组合特征,探讨其相关性、聚集性及其指示意义;通过因子分析,找出有代表性的因子,用其代表变量,绘制典型因子得分等值线图,并从中分析不同元素组合的区域分布基于何种因素,用11个代表性因子的分布特征就基本可以代表青州市表层土壤23项原始变量的分布特征,并对F1,F2,F3主因子进行了地质解释。聚类分析与因子分析相结合,利于表层土壤中元素的共生组合特征及其差异性研究,利于对研究区表层土壤异常进行归纳总结。     

南海神狐海域沉积物自生黄铁矿和石膏S同位素特征及对甲烷渗漏强度的示踪

The northern slope of the South China Sea is a gas-hydrate-bearing region related to a high deposition rate of organic-rich sediments co-occurring with intense methanogenesis in subseafloor environments.Anaerobic oxidation of methane(AOM) coupled with bacterial sulfate reduction results in the precipitation of solid phase minerals in seepage sediment,including pyrite and gypsum.Abundant aggregates of pyrites and gypsums are observed between the depth of 667 and 850 cm below the seafloor(cmbsf) in the entire core sediment of HS328 from the northern South China Sea.Most pyrites are tubes consisting of framboidal cores and outer crusts.Gypsum aggregates occur as rosettes and spheroids consisting of plates.Some of them grow over pyrite,indicating that gypsum precipitation postdates pyrite formation.The sulfur isotopic values(δ~(34) S) of pyrite vary greatly(from –46.6‰ to –12.3‰ V-CDT) and increase with depth.Thus,the pyrite in the shallow sediments resulted from organoclastic sulfate reduction(OSR) and is influenced by AOM with depth.The relative high abundance and δ~(34) S values of pyrite in sediments at depths from 580 to 810 cmbsf indicate that this interval is the location of a paleo-sulfate methane transition zone(SMTZ).The sulfur isotopic composition of gypsum(from–25‰ to –20.7‰) is much lower than that of the seawater sulfate,indicating the existence of a 34 S-depletion source of sulfur species that most likely are products of the oxidation of pyrites formed in OSR.Pyrite oxidation is controlled by ambient electron acceptors such as MnO_2,iron(Ⅲ) and oxygen driven by the SMTZ location shift to great depths.The δ~(34) S values of gypsum at greater depth are lower than those of the associated pyrite,revealing downward diffusion of 34 S-depleted sulfate from the mixture of oxidation of pyrite derived by OSR and the seawater sulfate.These sulfates also lead to an increase of calcium ions from the dissolution of calcium carbonate mineral,which will be favor to the formation of gypsum.Overall,the mineralogy and sulfur isotopic composition of the pyrite and gypsum suggest variable redox conditions caused by reduced seepage intensities,and the pyrite and gypsum can be a recorder of the intensity evolution of methane seepage.     

Smectite formation in metalliferous sediments near the East Pacific Rise at 13°N

A 43 cm long E271 sediment core collected near the East Pacific Rise(EPR) at 13°N were studied to investigate the origin of smectite for understanding better the geochemical behavior of hydrothermal material after deposition.E271 sediments are typical metalliferous sediments. After removal of organic matter, carbonate, biogenic opal,and Fe-Mn oxide by a series of chemical procedures, clay minerals(2 μm) were investigated by X-ray diffraction,chemical analysis and Si isotope analysis. Due to the influence of seafloor hydrothermal activity and close to continent, the sources of clay minerals are complex. Illite, chlorite and kaolinite are suggested to be transported from either North or Central America by rivers or winds, but smectite is authigenic. It is enriched in iron, and its contents are highest in clay minerals. Data show that smectite is most likely formed by the reaction of hydrothermal Fe-oxyhydroxide with silica and seawater in metalliferous sediments. The Si that participates in this reaction may be derived from siliceous microfossils(diatoms or radiolarians), hydrothermal fluids, or detrital mineral phases. And their δ30 Si values are higher than those of authigenic smectites, which implies that a Si isotope fractionation occurs during the formation because of the selective absorption of light Si isotopes onto Feoxyhydroxides. Sm/Fe mass ratios(a proxy for overall REE/Fe ratio) in E271 clay minerals are lower than those in metalliferous sediments, as well as distal hydrothermal plume particles and terrigenous clay minerals. This result suggests that some REE are lost during the smectite formation, perhaps because their large ionic radii of REE scavenged by Fe-oxyhydroxides preclude substitution in either tetrahedral or octahedral lattice sites of this mineral structure, which decreases the value of metalliferous sediments as a potential resource for REE.     

基于“杂合以治”理论探讨陈大舜和法论治经验

陈大舜教授基于“杂合以治”理论，在杂合各种治疗手段的基础上实行和法论治，有较好的临床优势，疗效肯定。本文从杂合为和法均治、和法复治、和法轻治、和法预治、和法综治5个方面来系统阐述陈大舜教授和法论治的特色。并附验案1则，以资佐证。     

贵州夜郎湖表层水体地球化学昼夜变化及其影响因素

为探究岩溶水库水文地球化学行为过程,对贵州普定夜郎湖表层水体进行了为期3 d的高分辨率昼夜监测。结果表明：1）多变的天气和水文条件叠加导致水体离子指标昼夜变化不显著,规律性较差。而水温、DO、pH值、SpC、SIc、pCO₂等常规理化指标受水温变化和生物作用表现出明显的昼夜波动。2）利用亨利常数和主成分分析,得到温度变化、生物作用、人类活动、水库的蓄水与放水对夜郎湖水库水文地球化学特征变化的贡献率分别为21.66%、17.28%、14.08%和10.22%,说明作用于水库水文地球化学行为的因子具有多元性。3）δ ¹⁸O表现出与DO一致的波动趋势,即白天上升,晚上下降,反映在短时间尺度上,氢氧稳定同位素变化受控于生物过程（主要是呼吸作用过程）;而对比水库水体和大气降水的d-excess（d值）发现,水库水体的d值（8.21‰）显著偏低于当地大气降水的d值（9.64‰）,说明在长时间尺度上,主要受蒸发效应引起的不平衡分馏影响。     

黑河中游夏季昼夜水汽同位素特征及水汽来源分析

基于2012年6~8月的实测水汽同位素数据及相关气象数据，对黑河中游夏季昼夜的同位素基本特征、水汽来源方向及潜在蒸发源地进行了研究。结果表明：空气水汽线斜率白天大于夜晚和水汽过量氘值白天大于夜晚，综合说明白天局地蒸发较夜晚强烈；夏季受西风水汽影响显著。其中，6月主要受西风水汽和北冰洋水汽影响，7、8月主要受西风水汽和东南方向水汽影响，且8月受东南方向水汽影响最为明显；水汽运移路径上下垫面地形和气压带移动会影响水汽后向轨迹高度，西北方向上水汽输送通道较顺畅，风速较大，有利于水汽的输送；水汽蒸发源地主要集中在研究区周围及以东、以北部，其次是西北部。绿洲是主要的水汽蒸发源地，其次是城市和河流，白天较夜晚局地蒸发强烈且面积大。     

空间分析与生物地球化学循环:西藏林周县大骨节病患病村与非患病村的比较研究

西藏林周县是我国大骨节病(KBD)患病较为严重的地区之一,本文将林周县作为研究区,通过使用地理探测器(GeoDetector)量化分析KBD患病率风险因子的影响,并使用环境化学方法验证空间分析结果。通过对10个潜在影响因子的分析以及对当地KBD患病村和非患病村的土壤-水-粮食-人这一生物地球化学循环的环境化学分析,结果表明:(1)林周县KBD由一组多重且交互作用的环境影响因子共同作用影响,其中最重要的控制因子是地层因子;(2)所有环境介质(土壤、水、谷物)及人体组织中的硒元素浓度在KBD患病区均低于非患病区;(3)当地居民对硒和铬的摄入严重不足,尤其是KBD患病村中居民硒元素平均日摄入量(ADD)大约仅为世界卫生组织(WHO)建议的成人基本摄入量下限的4%;(4)我们推测,当地居民患病主要是由于地层这一影响因子,这是由于通过生态系统的迁移转化导致当地人口严重硒缺乏,最终导致地方性生物地球化学硒缺乏。     

氟、氯、溴、碘等卤族元素与人体健康的关系

卤族元素是人体的必需元素,正常情况下成人摄入量不超过F4 mg/d、C11.7～5.1g/d、I 100～200μg/d;少年不超过F 3 mg/d,儿童I1μg/kg-d,婴儿Cl0.3～1.2 g/d.过量摄入或缺乏卤族元素,都可能导致疾病的发生.而F含量0.5～1.0mg/L、C1＜50mg/L、Br＞100μg/L、I 10～100μg/L的饮用地下水,有利于人体健康.     

平衡剖面的制作流程及其地质意义

平衡剖面技术是地质思维和计算机技术的结晶,使对断层构造的研究提高到定量阶段,其依据是在垂直构造走向的剖面上,地层长度和面积(2D)或体积(3D)是均衡的。在此原理基础上利用数学手段对盆地的构造发育史进行正演和反演模拟,直观地再现地下构造的原始几何形态,迅速提供地震剖面的构造解释方案,并对解释结果进行检验(不平衡的剖面其解释一般有问题),为深刻认识构造发育史、分析油气运移及聚集规律提供依据,提高了工作效率。其结果也为盆地模拟、油藏模拟、定量计算构造伸缩量等地质研究打下了坚实的基础[1]。