山东省远距离热带气旋暴雨研究

应用1971-2003年的山东降水资料、常规天气图资料、台风年签和NCEP资料,对在华南沿海登陆和活动的热带气旋在山东造成远距离暴雨的气候特征进行统计分析,对环流形势场进行合成分析.建立了山东省远距离热带气旋暴雨的天气学模型.分别计算分析了山东有和无远距离热带气旋暴雨合成的水汽和温湿能的收支.结果表明:在华南沿海登陆和活动的热带气旋与西风带环流系统和副热带高压相互作用在山东造成的远距离热带气旋暴雨年均2.5次.暴雨的范围广、强度大.出现暴雨的时间比热带气旋登陆时间滞后.在山东造成远距离暴雨的热带气旋在华南沿海登陆时,中心东部有一股东南风或偏南风低空急流指向内陆.中高纬度中低层西风带环流弱,位置偏北.500 hPa西风带中的偏北气流与副高边缘的偏南气流在山东境内汇合.低层850-700 hPa伴有低值系统影响,山东为气旋性环流控制.热带气旋登陆后其中心附近的中低层偏南风急流向北伸展,绕过副高脊线直达山东.在台风中心附近至山东之间建立起水汽和温湿能的输送通道,把高温高湿的暖湿空气源源不断地向山东输送.在台风登陆后12-48小时内,山东暴雨区上空有大量的水汽和温湿能的净流入.暖湿气流与西风带气流相汇合,产生辐合上升,造成暴雨.     

Heat of formation of petalite, LiAlSi4O10

The enthalpy of formation of petalite, LiAlSi₄O₁₀, has been measured using high-temperature solution calorimetry. The measurements were carried out in a Calvet-type twin micro calorimeter at 728?°C. A 2PbO?·?B₂O₃ melt was used as a solvent. Tabulated heats of formation of the components and tabulated heat capacities of the reactants and the product (Robie and Hemingway 1995) were used to calculate the standard heat of formation of petalite from the measured heats of solution. The calculations yielded a mean value of Δ _f H ^pet _298.15=?4872±5.4 kJ mol^?1. This value may be compared to the heat of formation of Δ _f H ^pet _298.15= ?4886.5±6.3 kJ mol^?1 determined by the HF solution calorimetry by Bennington et?al. (1980). Faßhauer et?al. (1998) combined thermodynamic data with phase-equilibrium results to obtain best-fit thermodynamic results using the Bayes method, in order to derive an internally consistent dataset for phases in the NaAlSiO₄– LiAlSiO₄–Al₂O₃–SiO₂–H₂O system. They determined ?4865.6?±?0.8?kJ?mol^?1 as the enthalpy of formation of petalite, a value that is appreciably closer to the enthalpy found in this work.     

Comparison of different numerical approaches to the 1D sea-ice thermodynamics problem

The vertical one-dimensional sea-ice thermodynamic problem using the principle of conservation of enthalpy is revisited here using (1) the Bitz and Lipscomb (1999) finite-difference approach (FD), (2) a reformulation of the sigma-level transformation of Huwald et al. (2005b) (FV) and (3) a Finite Element approach also in sigma coordinates (FE). These three formulations are compared in terms of physics, numerics, and performance, in order to identify the best choice for large-scale climate models. The BL99 formulation sequentially treats the diffusion of heat and the changes in the vertical position of the ice-snow layers. In contrast, the FV sigma-level transformation elegantly treats both simultaneously. The original FV formulation suffers however from slow convergence. The convergence can nonetheless be improved significantly with a few simple modifications to the original code. The three formulations are compared following the experimental protocol of the Sea Ice Model Intercomparison Project for ice thermodynamics (SIMIP2). It is found that all formulations converge to the same solution. The FD approach, however, suffers from the added cost of the remapping step at large number of ice layers (we include in the appendix an optimized version of the FD code–written by one of the reviewer–that resolves this issue). Finally the FE formulation results in a sub-surface temperature over-estimation at low resolution, a problem which disappears at high resolution. Hence, only FD and FV are found suitable for climate models.     

一次台风远距离作用下的西南低涡大暴雨个例分析

利用2009年8月2—5日发生在川渝地区一次远距离台风暴雨的实况降水资料和NCEP/NCAR再分析资料,研究了远距离台风作用下的水汽和温湿能输送特征;利用25点平滑算子方法研究了台风"天鹅"对此次暴雨影响系统——西南低涡作用下的中尺度特征。结果表明,此次大暴雨过程是在有利的环流背景下发生的,东移的高空槽耦合了西南低涡,远距离的台风"天鹅"使得西南低涡在川渝地区长时间维持,台风"天鹅"倒槽对低涡系统暖湿结构具有重要作用;在台风倒槽偏东气流驱动下,其携带的水汽和能量与西南低空急流输送的暖湿水汽汇合,构建了输送到低值系统附近的水汽和能量通道,增强了强降水区水汽和能量积聚效应,这种积聚效应促使低涡系统物理结构的维持;在台风倒槽顶部偏东气流动力作用下,促使低涡系统中低层正涡度增强,进一步促使垂直涡度增长,对低涡系统动力结构维持起到积极作用,进而促使低涡系统长时间维持,最终导致长时间强降水的发生。     

A model of boiling for fluid inclusion studies: Application to the Bolaños Ag–Au–Pb–Zn epithermal deposit,Western Mexico

Boiling can be inferred from fluid inclusion microthermometry studies when a progressive increase in apparent salinity is observed along with a decrease of homogenization temperature (T_H) and depth, thus reflecting the partitioning of non-volatile solutes into the liquid phase during steam loss. We propose a model for fluid evolution during boiling based on mass and heat balance equations, which establishes paths in the T_H-salinity space that can be compared with fluid inclusion data to confirm or discard boiling. Additionally, the model allows calculating paleo-depths, for which the effect of steam bubbles lowering the hydrostatic pressure is taken into account.     

High-temperature heat capacity and thermodynamic properties for end-member titanite (CaTiSiO5)

 The heat capacity of end-member titanite and (CaTiSiO₅) glass has been measured in the range 328–938 K using differential scanning calorimetry. The data show a weak λ-shaped anomaly at 483 ± 5 K, presumably associated with the well-known low-pressure P2₁/a ⇆ A2/a transition, in good agreement with previous studies. A value of 0.196 ± 0.007 kJ mol⁻¹ for the enthalpy of the P2₁/a ⇆ A2/a transition was determined by integration of the area under the curve for a temperature interval of 438–528 K, bracketing the anomaly. The heat capacity data for end-member titanite and (CaTiSiO₅) glass can be reproduced within <1% using the derived empirical equations (temperature in K, pressure in bars):

Crystal-chemical and energetic systematics of wadeite-type phases A2BSi3O9 (A = K, Cs; B = Si, Ti, Zr)

Wadeite K₂ZrSi₃O₉ and its analogues K₂TiSi₃O₉ and Cs₂ZrSi₃O₉, synthesized by high-temperature solid-state sintering, have been investigated using powder X-ray diffraction coupled with Rietveld analysis and high-temperature oxide melt solution calorimetry. The crystal chemistry and energetics of these phases, together with K₂Si^VISi₃ ^IVO₉, a high-pressure wadeite analogue containing both tetrahedral and octahedral Si, are discussed in term of ionic substitutions. As the size of the octahedral framework cation increases, Si⁴⁺ → Ti⁴⁺ → Zr⁴⁺, the cell parameter c increases at a much higher rate than a. In contrast, increasing the interstitial alkali cation size (K⁺ → Cs⁺) results in a higher rate of increase in a compared with c. This behavior can be attributed to framework distortion around the interstitial cation. The enthalpies of formation from the constituent oxides (ΔH_f,ox⁰) and from the elements (ΔH_f,el⁰) have been determined from drop-solution calorimetry into 2PbO·B₂O₃ solvent at 975 K. The obtained values (in kJ/mol) are as follows: ΔH_f,ox⁰ (K₂TiSi₃O₉) = −355.8 ± 3.0, ΔH_f,el⁰ (K₂TiSi₃O₉) = −4395.1 ± 4.8, ΔH_f,ox⁰ (K₂ZrSi₃O₉) = −374.3 ± 3.3, ΔH_f,el⁰ (K₂ZrSi₃O₉) = −4569.9 ± 5.0, ΔH_f,ox⁰ (Cs₂ZrSi₃O₉) = −396.6 ± 4.4, and ΔH_f,el⁰ (Cs₂ZrSi₃O₉) = −4575.0 ± 5.5. The enthalpies of formation for K₂Si^VISi₃ ^IVO₉ were calculated from its drop-solution enthalpy of an earlier study (Akaogi et al. 2004), and the obtained ΔH_f,ox⁰ (K₂SiSi₃O₉) = −319.7 ± 3.4 and ΔH_f,el⁰ (K₂SiSi₃O₉) = −4288.7 ± 5.1 kJ/mol. With increasing the size of the octahedral framework cation or of the interstitial alkali cation, the formation enthalpies become more exothermic. This trend is consistent with the general behavior of increasing energetic stability with decreasing ionic potential (z/r) seen in many oxide and silicate systems. Further, increasing the size of the octahedral framework cation appears to induce more rapid increase in stability than increasing the interstitial alkali cation size, suggesting that framework cations play a more dominant role in wadeite stability.     

Validation of A One-Dimensional Snow-Land Surface Model at the Sleepers River Watershed

A one-dimensional land surface model, based on conservations of heat and water substance inside the soil and snow, is presented. To validate the model, a stand-alone experiment is carried out with five years of meteorological and hydrological observations collected from the NOAA-ARS Cooperative Snow Research Project (1966–1974) at the Sleepers River watershed in Danville, Vermont, U.S.A. The numerical results show that the model is capable of reproducing the observed soil temperature at different depths during the winter as well as a rapid increase of soil temperature after snow melts in the spring. The model also simulates the density, temperature, thickness, and equivalent water depth of snow reasonably well. The numerical results are sensitive to the fresh snow density and the soil properties used in the model, which affect the heat exchange between the snowpack and the soil.     

Direct calculation of thermodynamic properties of the barite/celestite solid solution from molecular principles

 Thermodynamic properties of the barite–celestite solid solution were calculated using molecular principles. Cation–cation (Ba–Ba, Sr–Sr, and Ba–Sr) interaction energies were derived from a number of random and ordered cation distributions which were energy-optimized using force potentials as incorporated in the program package GULP. With these interaction energies, diagrams for the enthalpy and free energy of mixing could be computed for the entire range of the solid solution between the barite and celestite end members and for a number of annealing temperatures. These thermodynamic data show that the solid solution is nonideal. The system has a tendency for Ba²⁺ and Sr²⁺ cations to order onto alternating layers ||(100). However, this ordering scheme is thermodynamically only relevant for annealing temperatures below approximately 500 K and systems that are kinetically inhibited during crystal growth. For sufficiently long annealing times at room temperature, the solid solution tends to exsolve with barite–celestite interfaces ||(100). The cell parameters a and c were calculated to have almost linear behavior for the whole solid solution, suggesting close to ideal behavior according to Vegard's law. In contrast, b tends to deviate positively from linearity, in agreement with experimental values. Received: 6 April 1999 / Revised, accepted: 29 September 1999