Terrestrial discharge influences microbioerosion and microbioeroder community structure in coral reefs

Microbioerosion rates and microbioeroder community structure were studied in four Kenyan protected coral-reef lagoons using shell fragments of Tridacna giant clams to determine their response to the influence of terrestrial run-off. Fourteen different microbioeroder traces from seven cyanobacteria, three green algae and four fungi species were identified. The river discharge-impacted reef and ‘pristine’ reef showed similar composition but higher microbioeroder abundance and total cyanobacteria- and chlorophyte-bioeroded areas when compared with the other study reefs. Cyanobacteria dominated during the north-east monsoon (NEM) relative to the south-east monsoon (SEM) season, with algae and cyanobacteria being major microbioeroders in the river-impacted and pristine reefs. The rate of microbioerosion varied between 4.3 g CaCO3 m^?2 y^?1 (SEM) and 134.7 g CaCO₃ m^?2 y^?1 (NEM), and was highest in the river-impacted reef (127.6 g CaCO₃ m^?2 y^?1), which was almost double that in the pristine reef (69.5 g CaCO₃ m^?2 y^?1) and the mangrove-fringed reef (56.2 g CaCO₃ m^?2 y^?1). The microbioerosion rates measured in this study may not be high enough to cause concern with regard to the health and net carbonate production of Kenya’s coral reefs. Nevertheless, predicted increases in the frequency and severity of stresses related to global climate change (e.g. increased sea surface temperature, acidification), as well as interactions with local disturbances and their influence on bioerosion, may be increasingly important in the future.     

海洋表层沉积物中金属镉的来源解析

利用2015年8月份对长江口及其邻近海域表层沉积物的监测数据,基于主成分分析/绝对主成分分数(PCA/APCS)受体模型定量解析了重金属元素镉(Cd)的可能来源,并结合地统计学插值了Cd的源贡献量的空间分布状况,结果表明沉积物中镉污染主要存在3个可能来源,源头及贡献率分别为工业污染(18.8%)、陆地径流输入(66.0%)、生物活动等自然因素(13.6%),并且各个源头贡献量具有不同的空间分布状况,其中工业污染的高值区主要集中在靠近陆地区域,陆地径流输入的分布呈现由近岸向外海逐减降低的特征,生物活动等自然因素的高值区主要集中在远离陆地的外海区域。     

High-frequency monitoring of hydrological and biogeochemical fluxes in forested catchments of southern Chile

The variability of rainfall-dependent streamflow at catchment scale modulates many ecosystem processes in wet temperate forests. Runoff in small mountain catchments is characterized by a quick response to rainfall pulses which affects biogeochemical fluxes to all downstream systems. In wet-temperate climates, water erosion is the most important natural factor driving downstream soil and nutrient losses from upland ecosystems. Most hydrochemical studies have focused on water flux measurements at hourly scales, along with weekly or monthly samples for water chemistry. Here, we assessed how water and element flows from broad-leaved, evergreen forested catchments in southwestern South America, are influenced by different successional stages, quantifying runoff, sediment transport and nutrient fluxes during hourly rainfall events of different intensities. Hydrograph comparisons among different successional stages indicated that forested catchments differed in their responses to high intensity rainfall, with greater runoff in areas covered by secondary forests (SF), compared to old-growth forest cover (OG) and dense scrub vegetation (CH). Further, throughfall water was greatly nutrient enriched for all forest types. Suspended sediment loads varied between successional stages. SF catchments exported 455 kg of sediments per ha, followed by OG with 91 kg/ha and CH with 14 kg/ha, corresponding to 11 rainfall events measured from December 2013 to April 2014. Total nitrogen (TN) and phosphorus (TP) concentrations in stream water also varied with rainfall intensity. In seven rainfall events sampled during the study period, CH catchments exported less nutrients (46 kg/ha TN and 7 kg/ha TP) than SF catchments (718 kg/ha TN and 107 kg/ha TP), while OG catchments exported intermediate sediment loads (201 kg/ha TN and 23 kg/ha TP). Further, we found significant effects of successional stage attributes (vegetation structure and soil physical properties) and catchment morphometry on runoff and sediment concentrations, and greater nutrients retention in OG and CH catchments. We conclude that in these southern hemisphere, broad-leaved evergreen temperate forests, hydrological processes are driven by multiple interacting phenomena, including climate, vegetation, soils, topography, and disturbance history.     

Predicting quantiles of water quality from catchment characteristics

Water quality is often highly variable both in space and time, which poses challenges for modelling the more extreme concentrations. This study developed an alternative approach to predicting water quality quantiles at individual locations. We focused on river water quality data that were collected over 25 years, at 102 catchments across the State of Victoria, Australia. We analysed and modelled spatial patterns of the 10th, 25th, 50th, 75th and 90th percentiles of the concentrations of sediments, nutrients and salt, with six common constituents: total suspended solids (TSS), total phosphorus (TP), filterable reactive phosphorus (FRP), total Kjeldahl nitrogen (TKN), nitrate-nitrite (NO_x), and electrical conductivity (EC). To predict the spatial variation of each quantile for each constituent, we developed statistical regression models and exhaustively searched through 50 catchment characteristics to identify the best set of predictors for that quantile. The models predict the spatial variation in individual quantiles of TSS, TKN and EC well (66%–96% spatial variation explained), while those for TP, FRP and NO_x have lower performance (37%–73% spatial variation explained). The most common factors that influence the spatial variations of the different constituents and quantiles are: annual temperature, percentage of cropping land area in catchment and channel slope. The statistical models developed can be used to predict how low- and high-concentration quantiles change with landscape characteristics, and thus provide a useful tool for catchment managers to inform planning and policy making with changing climate and land use conditions.     

Smectite formation in metalliferous sediments near the East Pacific Rise at 13°N

A 43 cm long E271 sediment core collected near the East Pacific Rise(EPR) at 13°N were studied to investigate the origin of smectite for understanding better the geochemical behavior of hydrothermal material after deposition.E271 sediments are typical metalliferous sediments. After removal of organic matter, carbonate, biogenic opal,and Fe-Mn oxide by a series of chemical procedures, clay minerals(2 μm) were investigated by X-ray diffraction,chemical analysis and Si isotope analysis. Due to the influence of seafloor hydrothermal activity and close to continent, the sources of clay minerals are complex. Illite, chlorite and kaolinite are suggested to be transported from either North or Central America by rivers or winds, but smectite is authigenic. It is enriched in iron, and its contents are highest in clay minerals. Data show that smectite is most likely formed by the reaction of hydrothermal Fe-oxyhydroxide with silica and seawater in metalliferous sediments. The Si that participates in this reaction may be derived from siliceous microfossils(diatoms or radiolarians), hydrothermal fluids, or detrital mineral phases. And their δ30 Si values are higher than those of authigenic smectites, which implies that a Si isotope fractionation occurs during the formation because of the selective absorption of light Si isotopes onto Feoxyhydroxides. Sm/Fe mass ratios(a proxy for overall REE/Fe ratio) in E271 clay minerals are lower than those in metalliferous sediments, as well as distal hydrothermal plume particles and terrigenous clay minerals. This result suggests that some REE are lost during the smectite formation, perhaps because their large ionic radii of REE scavenged by Fe-oxyhydroxides preclude substitution in either tetrahedral or octahedral lattice sites of this mineral structure, which decreases the value of metalliferous sediments as a potential resource for REE.     

Tephrochronology and tephrostratigraphy of two Pleistocene continental fossiliferous successions from central Italy

The stratigraphical context of two Middle Pleistocene fossiliferous palaeosols from Central Italy (Abruzzo and Tuscany) have been studied. Small mammals and molluscs occur in both palaeosols, which are covered by tephra layers that were analysed using an interdisciplinary approach. Application of fission‐track dating to apatites separated from the Case Picconetto tephra (Pescara, Abruzzo), yielded an age of 0.48 ± 0.04 Ma, indistinguishable from those previously determined for the Campani Quarry (Lower Valdarno, Tuscany) (0.46 ± 0.05 Ma and 0.48 ± 0.05 Ma). Geochemical and petrographic investigations indicate that these tephra originated from different volcanoes, the Alban Hills Volcanic Complex and the Vico Volcano (Latium) respectively. Small mammal and mollusc assemblages indicate different palaeoclimatic and palaeoenvironmental conditions for the Case Picconetto and Campani Quarry palaeosols. Warm and humid conditions can be inferred for the Campani Quarry site, whereas open and cold conditions can be inferred for Case Picconetto. On the basis of faunal data, fission‐track dates and attribution of tephra to specific volcanic eruptions, we suggest a correlation of these faunas with marine oxygen isotope stage 14 (Case Picconetto) and with marine oxygen isotope stage 11 (Campani Quarry), respectively. Copyright © 2003 John Wiley & Sons, Ltd.     

The grain-size characteristics of Quaternary deposits at Xingshan near Siping in Jilin province, China

This research paper analyses the grain-size characteristics of the Quaternary deposits at Xingshan near Siping, Jilin province in China by employing graphic measures to study the grain size distribution and its mode of transport and deposition. The Quaternary deposits at Xingshan lie unconformable on Cretaceous rocks made of siltstone, mudstone and sandstone. The average grain size is between 8.06 to 8.55Φ (0.002 6 ～0.003 7 mm). The Quaternary deposits at Xingshan mainly compose of very fine silt to clay. The compositions of the grade are clay 63% and silt 37%. The clay size components are weathered debris transported and deposited by flowing water from the SE highlands or hills to the low lying NW Xingshan plains whereas the silty components accumulated by aoelian process. The Quaternary deposits at Xingshan accumulated in the middle and late Pleistocene interglacial periods from (459.12～39.03) ka to (88.92～7.56) ka. The standard deviation ranged from 0.96 to 1.36Φ, indicating that the sediments are moderately to poorly sorted, Coefficient of skewness ranged from 0.16～0.31 with an average skewness of 0.218, (Positively skewed towards fine). Kurtosis values (0.84～1.05) from the grain size distribution and visual inspection of the frequency curves indicate platykurtic to mesokurtic curves and unimodal to bimodal grain-size distribution. The type of deposit formation is sand dune and the source is at a distal from its provenance.     

Evidence for a mid‐Pleistocene shift of ice‐drift pattern in the Nordic seas

Sediment proxy records from a continuous, 1.5 million year long deep‐sea sediment core from a site in the western Norwegian Sea were used to obtain new insights into the nature of palaeoceanographic change in the northern North Atlantic (Nordic seas) during the climatic shift of the Mid‐Pleistocene Revolution (MPR). Red‐green sediment colour and magnetic susceptibility records both reveal significant differences in their mean values when comparing the intervals older than 700 000 yr (700 ka) with those from the past 500 kyr. The timing and duration of these changes indicates that the MPR in the Nordic seas is characterised by a gradual transition lasting about 200 kyr. Together with further sedimentological evidence this suggests that the mid‐Pleistocene climate shift was accompanied by a general change in ice‐drift pattern. It is further proposed that prior to the onset of the major late Pleistocene glaciations in the Northern Hemisphere a significant proportion of the ice in the eastern Nordic seas originated from a southern provenance, whereas later it dominantly came from the surrounding landmasses. Copyright © 2003 John Wiley & Sons, Ltd.     

西藏结则茶卡湖岸沉积物中铀系年龄及意义

通过对藏北高原西北部结则茶卡湖泊及其沿岸地质地貌调查,发现其为一个富含硼、锂、钾、锶的封闭型盐湖,沿岸海拔4 850 m拔湖325 m有一条明显的高位湖岸线,该湖岸线到湖面之间有六级湖积阶地发育,六级以上阶地保存零星。沿湖岸不同高度上的湖积物U系年龄分别为(14.2±1.2)ka BP(T2)、(38.0±3.5)ka BP(T4)和(41.6±3.2)ka BP(T5)。湖面下降的幅度是藏北高原迄今所知最大。根据湖面平均下降速度推算高位湖岸线和高位湖积层的形成年龄在(120~90)ka BP,与东部的纳木错和西部的甜水海基本一致,说明藏北高原在晚更新世初期有一个明显的泛湖期。大约100 ka BP结则茶卡湖面开始下降,晚更新世以来湖泊演化是在封闭体系干旱环境下进行的,盐湖形成于14 ka BP左右,藏北高原在晚更新世以来气候变化可能为自西向东逐渐变为干寒。