相律的应用:蒸发结晶过程自由度

在连续原理和浓度限制条件的基础上,分析了卤水蒸发过程的自由度,提出了“蒸发结晶过程自由度”这一概念。发现蒸发结晶过程自由度在整个过程中不是1便是0,在1和0之间交替变化,与选择的组分数和析出固相数目无关。蒸发结晶过程自由度为1,物理意义是在不引起新相产生旧相不消失的前提下过程连续地变化(水分的连续蒸失),几何意义是指在适当的坐标系中的一条线,一条直线或曲线;0的物理意义是指新相的产生和旧相的即将消失或者前一段的连续变化过渡到后一段的连续变化,几何意义是指一点,两蒸发阶段的交点或者过程的终点。简单地讨论了过程的单向性和连续件。     

可可西里——东昆仑活动构造带强震活动研究

青海昆仑山口西 8.1级地震发生在具有新生性特征的可可西里—东昆仑活动断裂带上。该断裂带在 190 0年以来的 10 0多年中经历了一个强震活动过程。在该强震活动过程中 ,地震沿整个可可西里—东昆仑活动构造带分段破裂 ,强震的破裂长度和震级之间大致满足对数线性的统计关系 ,强震活动呈现指数型时间分布的加速特征。这种强震加速活动特征可以用含多个震源体的孕震系统的强震成组活动模型给予解释。     

辽宁义县—北票地区义县组地层层序——义县阶标准地层剖面建立和研究之一

义县地区广义的义县组可解体为王家屯组 (暂命名 )和义县组 ;分属王家屯和义县火山旋回 ,前者为偏酸、偏碱性 ,后者主体为中基性、末期为中酸性火山岩系 ,并广泛发育潜火山岩相的玄武玢岩、安山玢岩和火山集块角砾熔岩筒。该区有七个主要沉积层 ,自下而上分别为王家屯组马神庙层、义县组老公沟层、业南沟层、砖城子层、大康堡层、朱家沟层和金刚山层 ;产有较丰富的无脊椎动物、脊椎动物和植物化石。以砖城子层、大康堡层和金刚山层为界 ,义县火山旋回可划分为 4个亚旋回 ,分别代表火山活动的初始期、主期、晚期和末期。北票四合屯地区的义县组相当义县地区义县组的第一和第二亚旋回 ,含鸟类化石的主沉积层 (尖山沟层和上园层 )可与砖城子层对比     

Characterisation of hydroclimatological trends and variability in the Lake Naivasha basin,Kenya

Recent hydro‐climatological trends and variability characteristics were investigated for the Lake Naivasha basin with the aim of understanding the changes in water balance components and their evolution over the past 50 years. Using a Bayesian change point analysis and modified Mann–Kendall tests, time series of annual mean, maximum, minimum, and seasonal precipitation and flow, as well as annual mean lake volumes, were analysed for the period 1960–2010 to uncover possible abrupt shifts and gradual trends. Double cumulative curve analysis was used to investigate the changes in hydrological response attributable to either human influence or climatic variability. The results indicate a significant decline in lake volumes at a mean rate of 9.35 × 10⁶ m³ year^?1. Most of the river gauging stations showed no evidence of trends in the annual mean and maximum flows as well as seasonal flows. Annual minimum flows, however, showed abrupt shifts and significant (upward/downward) trends at the main outlet stations. Precipitation in the basin showed no evidence of abrupt shifts, but a few stations showed gradual decline. The observed changes in precipitation could not explain the decline in both minimum flows and lake volumes. The findings show no evidence of any impact of climate change for the Lake Naivasha basin over the past 50 years. This implies that other factors, such as changes in land cover and infrastructure development, have been responsible for the observed changes in streamflow and lake volumes. Copyright © 2015 John Wiley & Sons, Ltd.     

Trend and extreme occurrence of precipitation in a mid‐latitude Eurasian steppe watershed at various time scales

The confounding effects of step change invalidate the stationarity assumption of commonly used trend analysis methods such as the Mann–Kendall test technique, so previous studies have failed to explain inconsistencies between detected trends and observed large precipitation anomalies. The objectives of this study were to (1) formulate a trend analysis approach that considers nonstationarity due to step changes, (2) use this approach to detect trends and extreme occurrences of precipitation in a mid‐latitude Eurasian steppe watershed in North China, and (3) examine how runoff responds to precipitation trends in the study watershed. Our results indicate that annual precipitation underwent a marginal step jump around 1995. The significant annual downward trend after 1994 was primarily due to a decrease in summer rainfall; other seasons exhibited no significant precipitation trends. At a monthly scale, July rainfall after 1994 exhibited a significant downward trend, whereas precipitation in other months had no trend. The percentage of wet days also underwent a step jump around 1994 following a significant decreasing trend, although the precipitation intensity exhibited neither a step change nor any significant trend. However, both low‐frequency and high‐frequency precipitation events in the study watershed occurred more often after than before 1994; probably as either a result or an indicator of climate change. In response to these precipitation changes, the study watershed had distinctly different precipitation‐runoff relationships for observed annual precipitations of less than 300 mm, between 300 and 400 mm, and greater than 400 mm. Copyright © 2013 John Wiley & Sons, Ltd.     

Long‐term streamflow trends in Hawai'i and implications for native stream fauna

Climate change has fundamentally altered the water cycle in tropical islands, which is a critical driver of freshwater ecosystems. To examine how changes in streamflow regime have impacted habitat quality for native migratory aquatic species, we present a 50‐year (1967–2016) analysis of hydrologic records in 23 unregulated streams across the five largest Hawaiian Islands. For each stream, flow was separated into direct run‐off and baseflow and high‐ and low‐flow statistics (i.e., Q10 and Q90) with ecologically important hydrologic indices (e.g., frequency of flooding and low flow duration) derived. Using Mann–Kendall tests with a running trend analysis, we determined the persistence of streamflow trends through time. We analysed native stream fauna from ~400 sites, sampled from 1992 to 2007, to assess species richness among islands and streams. Declines in streamflow metrics indicated a general drying across the islands. In particular, significant declines in low flow conditions (baseflows), were experienced in 57% of streams, compared with a significant decline in storm flow conditions for 22% of streams. The running trend analysis indicated that many of the significant downward trends were not persistent through time but were only significant if recent decades (1987–2016) were included, with an average decline in baseflow and run‐off of 10.90% and 8.28% per decade, respectively. Streams that supported higher native species diversity were associated with moderate discharge and baseflow index, short duration of low flows, and negligible downward trends in flow. A significant decline in dry season flows (May–October) has led to an increase in the number of no‐flow days in drier areas, indicating that more streams may become intermittent, which has important implications for mauka to makai (mountain to ocean) hydrological connectivity and management of Hawai'i's native migratory freshwater fauna.     

海南岛蒸发量的变化特征及其影响因子分析

利用海南岛18个气象观测站1966—2001年逐日20cm口径小型蒸发皿蒸发量及气象要素资料,通过数理统计方法分析了海南岛年和四季的蒸发量变化特征及气象因子对蒸发量的影响。结果表明:从时间上看,海南岛年蒸发量变化呈波动式下降,蒸发量的减少主要出现在春季,冬季和夏季次之。从空间上看,年蒸发量呈东北少、西南多的分布,其大值区主要集中在西南部,小值区主要集中在东北部和中部地区。M-K检验说明年与春冬两季蒸发量的变化呈下降趋势且在1994年前后发生突变。影响蒸发量变化的因子中,日照时数和风速是造成蒸发量减小的主要因子,降水量的影响仅次于风速和日照时数,而气温不是造成海南岛蒸发量减小的主要因子,相对湿度可能是海南岛的蒸发量减小的影响因子。     

Flood seasonality across Scandinavia—Evidence of a shifting hydrograph?

Fluvial flood events have substantial impacts on humans, both socially and economically, as well as on ecosystems (e.g., hydroecology and pollutant transport). Concurrent with climate change, the seasonality of flooding in cold environments is expected to shift from a snowmelt‐dominated to a rainfall‐dominated flow regime. This would have profound impacts on water management strategies, that is, flood risk mitigation, drinking water supply, and hydro power. In addition, cold climate hydrological systems exhibit complex interactions with catchment properties and large‐scale climate fluctuations making the manifestation of changes difficult to detect and predict. Understanding a possible change in flood seasonality and defining related key drivers therefore is essential to mitigate risk and to keep management strategies viable under a changing climate. This study explores changes in flood seasonality across near‐natural catchments in Scandinavia using circular statistics and trend tests. Results indicate strong seasonality in flooding for snowmelt‐dominated catchments with a single peak occurring in spring and early summer (March through June), whereas flood peaks are more equally distributed throughout the year for catchments located close to the Atlantic coast and in the south of the study area. Flood seasonality has changed over the past century seen as decreasing trends in summer maximum daily flows and increasing winter and spring maximum daily flows with 5–35% of the catchments showing significant changes at the 5% significance level. Seasonal mean daily flows corroborate those findings with higher percentages (5–60%) of the catchments showing statistically significant changes. Alterations in annual flood occurrence also point towards a shift in flow regime from snowmelt‐dominated to rainfall‐dominated with consistent changes towards earlier timing of the flood peak (significant for 25% of the catchments). Regionally consistent patterns suggest a first‐order climate control as well as a local second‐order catchment control, which causes inter‐seasonal variability in the streamflow response.     

Discrete wavelet‐based trend identification in hydrologic time series

Trend identification is a substantial issue in hydrologic series analysis, but it is also a difficult task in practice due to the confusing concept of trend and disadvantages of methods. In this article, an improved definition of trend was given as follows: ‘a trend is the deterministic component in the analysed data and corresponds to the biggest temporal scale on the condition of giving the concerned temporal scale’. It emphasizes the intrinsic and deterministic properties of trend, can clearly distinguish trend from periodicities and points out the prerequisite of the concerned temporal scale only by giving which the trend has its specific meaning. Correspondingly, the discrete wavelet‐based method for trend identification was improved. Differing from those methods used presently, the improved method is to identify trend by comparing the energy difference between hydrologic data and noise, and it can simultaneously separate periodicities and noise. Furthermore, the improved method can quantitatively estimate the statistical significance of the identified trend by using proper confidence interval. Analyses of both synthetic and observed series indicated the identical power of the improved method as the Mann–Kendall test in assessing the statistical significance of the trend in hydrologic data, and by using the former, the identified trend can adaptively reflect the nonlinear and nonstationary variability of hydrologic data. Besides, the results also showed the influences of three key factors (wavelet choice, decomposition level choice and noise content) on discrete wavelet‐based trend identification; hence, they should be carefully considered in practice. Copyright © 2012 John Wiley & Sons, Ltd.     

安徽铜陵地区含金硫化物矿床成矿作用

铜陵地区位于华中地洼区,苏鄂地洼系。具工业价值的金矿床多赋存于地洼期次一级构造以及它们的交汇处,这是本区构造控矿的特点。近矿围岩以地台型碳酸盐岩为主,矿体明显受地层层位控制。与矿化有关的侵入岩,主要形成于地洼期(燕山早、中期)。岩体形成后叠加了成矿热液的多次活动。金的成矿作用及金矿床的形成,通常与含金丰度相对较高的地台构造层有密切的成因联系,它们提供了重要的物质来源,可认为是矿源层(Source beds)。本区各主要矿床是以地洼型岩浆期后热液作用为主的多因复成层控含金硫化物矿床。