The Bear Brook Watershed in Maine: Multi-decadal whole-watershed experimental acidification

The Bear Brook Watershed in Maine (BBWM) is a long-term research site established to study the response of forest ecosystem function to environmental disturbances of chronic acidic deposition and ecosystem nitrogen enrichment. Starting in 1989, the West Bear (treated) watershed received bimonthly applications of ammonium sulfate [(NH₄)₂SO₄] fertilizer from above the canopy, whereas East Bear (reference) received ambient deposition. The treatments were stopped in 2016, marking the beginning of the recovery phase. Research at the site has focused on soils, streams, and vegetation. Here, we describe data collected over three decades at the BBWM—input and stream output nutrient fluxes, quantitative soil pits and soil chemistry, and soil temperature and moisture.     

察尔汗盐湖西北部典型采区地下卤水赋存状态的地面核磁探测与数值模拟研究

察尔汗盐湖地下晶间卤水蕴藏了宝贵的盐湖矿产资源,如何确定地下卤水的赋存规律以制定科学合理的卤水开采和补给方案,正成为盐湖资源大规模可持续利用亟需解决的重要问题。本文以察尔汗盐湖西北部的典型采卤区作为研究区域,1)利用新型的地面核磁共振找水仪,通过在研究区布设两条十字交叉的测线,探测并反演解译测区地下60米深度内的卤水静态赋存形式,2)结合OpenGeoSys(OGS)多物理场耦合地下水数值模拟软件,对测区地下卤水的动态运移形式进行数值模拟计算。地面核磁探测结果表明研究区含水量整体偏低,最大含水量约0.8%,平均含水量约0.4%。测点结果给出的含水层位分界面与邻近钻孔的地层层位分界面的一致性较高,浅部的层位误差在10%以下,达到了0.5米的精度。考虑到测区南北两边均有采卤渠正在汲取地下卤水,且在测区中心存在两条废弃的采卤渠,OGS地下水数值模拟研究结果表明采卤渠造成测区浅部卤水较大空缺,与研究区浅部含水量总体偏低的探测特征一致。研究结果表明地面核磁共振技术能准确探测卤水当前的赋存状态,地下水运移模拟技术可以深入认识采补活动引起卤水赋存状态的变化规律。探测和模拟结合的联合研究是确定卤水赋存规律的重要手段,研究成果可为盐湖资源合理开采高效利用提供基础资料和相关科学支撑。     

Patterns of pH change inferred from chrysophyte microfossils in Adirondack and northern New England lakes

The silica-scaled chrysophytes are being used increasingly in paleolimnological studies of lake acidification. This study compares the distribution of scaled chrysophytes in the surface sediment of a calibration set of lakes from the Adirondack Park and from northern New England. With the exception of two taxa, species distributions with respect to pH are similar in the two regions. The stratigraphic distribution of chrysophytes is then compared in five Adirondack and three New England lakes. All the presently acid lakes indicate recent lake acidification, with more acid tolerant chrysophytes increasing in relative frequency in the recent sediments. Because the timing of these species changes is unrelated to any watershed disturbances that may have occurred in the lakes' catchments, atmospheric deposition of acids is believed responsible for these recent pH changes.This is the seventh of a series of papers to be published by this journal which is a contribution of the Paleoecological Investigation of Recent Lake Acidification (PIRLA) project. Drs. D. F. Charles and D. R. Whitehead are guest editors for this series.     

Fossil midge associations and the historical status of fish in acidified lakes

Chaoborid and chironomid (Diptera) fossils were examined in sediment cores form nine Ontario Precambrian Shield lakes that were fishless in 1979. An abundance of Chaoborus americamus (intolerant of predation by fish) throughout cores from four lakes indicated that they were fishless historically. Occurrence of Chaoborus punctipennis and C. flavicans and absence of C. americanus in cores, except near the surface in two cases, indicated that four other lakes were inhabited by fish historically. One of these was probably periodically fishless as suggested by fluctuations among these Chaoborus species. The ninth lake was not suitable for Chaoborus; only one specimen of C. trivittatus was found in this core. Chironomid fossil associations were substantially different in historically fishless and inhabited lakes. Fishless lakes had chironomids typical of eutrophic conditions indicating that seasonal oxygen depletion likely was inimical to fish. Chironomid associations of oligotrophic waters occurred in lakes historically inhabited by fish. Both good water quality and accessibility were required for long-term habitation by fish. Partial recovery of alkalinity and rise in pH were accompanied by substantial re-invasion by fish in two lakes which had been inhabited historically by fish. Diptera associations provide valuable information on the historical suitability of lakes for fish and the presence/absence of fish in regions where acidification of surface waters has occurred.     

A laboratory test of the soil chemical submodels of two models of catchment acidification

Parameters for ion exchange selectivity and aluminium hydroxide dissolution in the soil chemical submodels used in applications of the Birkenes model and of MAGIC are compared and several discrepancies identified for organic soils. A laboratory column simulation of the soil chemical submodels is proposed and applied to soils from the Loch Dee area in Galloway. Experimental results were well predicted by a simplified version of MAGIC, with ion exchange selectivity parameters similar to those used in a previous simulation of one subcatchment of Loch Dee. The aluminium hydroxide dissolution parameter used previously was found to be too low for the organic soil materials, where a value of 106 predicted the experimental results more closely. The model developed also included a simple silicate weathering reaction to release base cations into the system. It is concluded that such simple laboratory simulations are useful for independent calibration of the soil chemical submodel of catchment models.     

The effect of naturally acidified irrigation water on agricultural volcanic soils. The case of Asembagus, Java, Indonesia

Acid water from the Banyuputih river (pH  3.5) is used for the irrigation of agricultural land in the Asembagus coastal area (East Java, Indonesia), with harmful consequences for rice yields. The river water has an unusual composition which is caused by seepage from the acidic Kawah Ijen crater lake into the river. This unique irrigation setting allows the study of soil acidification in situ. This paper assesses the effects of volcanogenically contaminated irrigation water on the chemical properties of the agricultural soils.The changes in soil properties were evaluated by comparing samples taken from the topsoil and sub-soil (1–3 m depth) from areas irrigated with acid water and areas irrigated with neutral water. The field survey thus resulted in four soil categories. Bulk soil composition, organic matter content, moisture content and particle size distribution were determined. Reactive phases were quantified with the selective extractions 1 M KCl, 0.1 M Na-pyrophosphate and 0.2 M acid ammonium oxalate (AAO).By comparing the four soil categories it is shown that the use of the naturally polluted irrigation water has had a large influence on the chemical composition of the topsoil. The composition of the soil solution has changed over the entire investigated soil profile. Furthermore the acid irrigation water has strongly modified the composition of the reactive phases, extracted as KCl, pyrophosphate, and AAO extractable elements, and also the bulk soil composition has been significantly modified. Overall this has resulted in the net dissolution of some elements and the net precipitation of others. The changes in the reactive phases and bulk soil composition are only apparent in the topsoil (0–20 cm) but not in the deeper soil.     

The contribution of atmospheric acid deposition to ocean acidification in the subtropical North Atlantic Ocean

The absorption of anthropogenic CO₂ and atmospheric deposition of acidity can both contribute to the acidification of the global ocean. Rainfall pH measurements and chemical compositions monitored on the island of Bermuda since 1980, and a long-term seawater CO₂ time-series (1983–2005) in the subtropical North Atlantic Ocean near Bermuda were used to evaluate the influence of acidic deposition on the acidification of oligotrophic waters of the North Atlantic Ocean and coastal waters of the coral reef ecosystem of Bermuda. Since the early 1980's, the average annual wet deposition of acidity at Bermuda was 15 ± 14 mmol m^− 2 year^− 1, while surface seawater pH decreased by 0.0017 ± 0.0001 pH units each year. The gradual acidification of subtropical gyre waters was primarily due to uptake of anthropogenic CO₂. We estimate that direct atmospheric acid deposition contributed 2% to the acidification of surface waters in the subtropical North Atlantic Ocean, although this value likely represents an upper limit. Acidifying deposition had negligible influence on seawater CO₂ chemistry of the Bermuda coral reef, with no evident impact on hard coral calcification.     

沿海与内陆地下卤水对比分析

分析对比我国滨海与内陆地下卤水的分布、成因及其水文地球化学特征，指出不同成因的地下卤水具有不同的水质．     

低盐度地下卤水养殖南美白对虾的研究

研究了用低盐度地下卤水养殖南美白对虾（Penaeus vannamei)的可行性和养殖模式。结果表明，向地下卤水中添加适量的K^ ，调节Na^ /K^ 比值，能明显提高仔虾的成活率；通过合理的水质调控，获得低盐度地下餐水南美白对虾养殖的高产高效，其中精养池平均成活率，平均产量和投入产出分别比半精养提高25．23％，148g/m^2和0．49。     

Physiological and behavioral responses of Bathynerita naticoidea (Gastropoda: Neritidae) and Methanoaricia dendrobranchiata (Polychaeta: Orbiniidae) to hypersaline conditions at a brine pool cold seep

Bathynerita naticoidea (Gastropoda: Neritidae) and Methanoaricia dendrobranchiata (Polychaeta: Orbiniidae) are two of the most abundant invertebrates associated with cold‐seep mussel beds in the Gulf of Mexico. At the methane seep known as Brine Pool NR‐1 (27 °43.415 N, 91 °16.756 W; 650 m depth), which is surrounded by a broad band of mussels (Bathymodiolus childressi), these species have distinctly different patterns of abundance, with the gastropod being found mostly at the outer edge of the mussel bed (average density in November 2003: 817 individuals·m⁻² in outer zone, 20·m⁻² in inner zone) and the polychaete being found almost exclusively near the inner edge (average density in November 2003: 3155 individuals·m⁻² in inner zone, 0·m⁻² in outer zone), adjacent to the brine pool itself. The salinity of the brine pool exceeds 120, so we hypothesized that M. dendrobranchiata should be more tolerant of high salinities than B. naticoidea. The opposite proved to be true. The gastropods were capable of withstanding salinities at least as high as 85, whereas the polychaetes died at salinities higher than 75. Both species were osmoconformers over the range of salinities (35–75) tested. Behavioral responses of B. naticoidea to salinities of 50, 60, and 70 were investigated in inverted vertical haloclines. Gastropods generally did not enter water of salinity greater than 60, but tolerated short periods at 60. Behavioral avoidance of brine should limit the vertical distribution of B. naticoidea in the inner zone to the top 2.5–5 cm of the mussel bed. Behavior is also a likely (though unproven) mechanism for controlling horizontal distribution of this species across the mussel bed. Methanoaricia dendrobranchiata can tolerate short excursions into the brine, but probably avoids hypersaline conditions by aggregating on the tops of the mussels.