胶州湾海水微表层粘度及其在海-气通量计算中的作用

物质海 -气通量计算新建议中将物质海 -气通量计算公式 F=K(CL- b Cg)中的 CL 用CL ( SML ) 代替。本文着重于对公式中质量迁移系数 K的讨论。在测定了海水微表层、次表层水粘度并同时测定了其它一些化学参量基础上 ,得出如下结论 :海水粘度与盐度、碱度有一定相关性 ;微表层与次表层海水的粘度变化小于 3%。因此 ,海水微表层效应影响 K值 ,与海水微表层效应影响物质浓度相比 ,可以不考虑。     

大亚湾微表层和次表层海水营养盐的研究

根据1998年秋季（10、11月）、1999年春、秋季（4、5、10月）5个航次对大亚湾海区微、次表层的调查结果，分析了微表层海水对氮、磷、硅营养盐的富集概况，讨论了营养盐与环境因子的关系。结果表明：大亚湾海区微表层海水对氮、磷、硅营养盐均有富集作用，因海况及季节不同，富集因数（EF）与其他海区的有所差别；无论夏季或秋季，大亚湾海区微表层海水中无机氮都以NH4－N为主要存在形态；其余水层则以NO3－N为主要存在形态。结果还表明，微表层、次表层海水中NH4－N与BOD5、COD测值都呈高度显著正相关，与PO4－P和SiO3-Si含量均无相关，说明大亚湾海区水中含氮有机物较含磷有机物丰富。     

Influence of the surface microlayer on the flux of nonconservative trace gases (CO,H2, CH4, N2O) across the ocean-atmosphere interface

Gas exchange experiments were conducted in the tropical Atlantic Ocean during a ship expedition with FS Meteor using a small rubber raft. The temporal change of the mixing ratios of CO, H₂, CH₄ and N₂O in the headspace of a floating glass box and the concentrations of these gases in the water phase were measured to determine their transfer velocities across the ocean-atmosphere interface. The ocean acted as a sink for these gases when the water was undersaturated with respect to the mixing ratio in the headspace. The transfer velocities were different for the individual gases and showed still large differences even when normalized for diffusivity. Applying the laminar film model, film thicknesses of 20 to 70 m were calculated for the observed flux rates of the different gas species. When the water was supersaturated with respect to atmospheric CO, H₂, CH₄ and N₂O, the transfer velocities of the emission process were smaller than those determined for the deposition process. In case of H₂ and CH₄, emission was even not calculable although, based on the observed gradient, the laminar film model predicted significant fluxes at the air-sea interface. The results are interpreted by destruction processes active within the surface microlayer.     

夏季赤道东太平洋海温异常对全球及东亚短期气候变化影响的数值试验

本文应用中国科学院大气物理研究所设计的两层大气环流模式（IAP-AGCM）研究了夏季赤道东太平洋地区负的海温异常对全球大气及赤道太平洋地区和东亚局地短期气候变化的影响，着重分析了海温异常（SSTA）所造成的降水、高度场、风场以及赤道太平洋地区海表感热和潜热输送等一些物理场的异常，并对赤道东太平洋海温异常影响全球及赤道太平洋和东亚局地短期气候变化的物理机制进行了探讨，得到了一些有意义的结果。     

Occurrence and fate of polycyclic aromatic hydrocarbons in the coastal surface microlayer

Polycyclic aromatic hydrocarbons (PAHs) were measured in the coastal sea surface microlayer (SML), the sub-surface waters (SSW) and the overlying atmosphere in order to investigate the influence of the SML on contaminant enrichment and air-sea exchange. Samples were collected at two contrasting locations of the NW Mediterranean, one urban influenced (off Barcelona, Spain) and another comparatively clean (off Banyuls-sur-Mer, France). Statistical data analysis confirmed the accumulation of PAHs in the SML with respect to the SSW (20.3+/-9.1 vs. 13.1+/-10.0 ng L(-1) in the dissolved phase; 709+/-207 vs. 158+/-111 ng g(-1) in the particulate phase). This accumulation was higher at the contaminated location (Barcelona station) compared with the more pristine one, with PAH enrichments 1.5 and 4.5 times higher for the dissolved and particulate phases, respectively, indicating that the enrichment of PAHs in the SML is dominated by particle transport processes.     

南印度洋热带气旋快速增强事件气候特征及其年际变率

利用美国联合台风预警中心的热带气旋最佳路径数据集、美国国家海洋和大气管理局的扩展重构海表温度数据、全球海洋数据同化系统的温度、盐度数据及美国国家环境预报中心/国家大气研究中心的再分析资料, 分析了1981—2019年南印度洋热带气旋快速增强事件的气候特征和年际变率。结果表明, 南印度洋热带气旋快速增强事件产生频率呈现单峰分布, 主要产生在每年的12月至次年4月。南印度洋热带气旋增强事件的产生位置呈带状分布, 其中3个高值中心分别位于马达加斯加岛东北海域、南印度洋中部海域和澳大利亚西北海域, 这主要是由于热带气旋热潜和垂直风切变两个大尺度环境变量决定的。年际变率方面, 厄尔尼诺-南方涛动对南印度洋热带气旋增强事件产生频率的调制作用是不对称的, 厄尔尼诺年与拉尼娜年南印度洋热带气旋快速增强事件均减少, 但使其减少的物理机制不同。厄尔尼诺年, 热带气旋快速增强事件减少主要是较高的垂直风切变造成的; 拉尼娜年, 热带气旋快速增强事件减少主要是由于热带气旋热潜的降低, 而海表温度、垂直风切变和相对湿度也存在一定贡献。     

Determination of copper complexation in surface microlayer of Daya Bay and Jiaozhou Bay

1 INTRODUCTION Bioavailability to the biota and the biogeo-chemistry of trace metals in marine environment areaffected by their chemical speciation in the naturalsystem (Bruland et al., 1991; Van den Berg andDonat, 1992; Wells et al., 1998). Therefore, thesetwo parameters, the ligands concentrations andconditional stability constants, are important todetermine the complexing capacity. Sea surface microlayer (SML), the thin interfa-cial boundary between ocean and atmosphere, playsan imp…     

A review of pollutants in the sea-surface microlayer (SML): a unique habitat for marine organisms

Boundary layers between different environmental compartments represent critical interfaces for biological, chemical and physical processes. The sea-surface microlayer (uppermost 1-1000 microm layer) forms the boundary layer interface between the atmosphere and ocean. Environmental processes are controlled by the SML, and it is known to play a key role in the global distribution of anthropogenic pollutants. Due to its unique chemical composition, the upper organic film of the SML represents both a sink and a source for a range of pollutants including chlorinated hydrocarbons, organotin compounds, petroleum hydrocarbons, polycyclic aromatic hydrocarbons (PAH) and heavy metals. These pollutants can be enriched in the SML by up to 500 times relative to concentrations occurring in the underlying bulk water column. The SML is also a unique ecosystem, serving as an important habitat for fish eggs and larvae. Concentration ranges and enrichment factors of pollutants in the SML in different areas of the world's oceans have been critically reviewed, together with available toxicity data for marine biota found within the SML. Overall, the SML is highly contaminated in many urban and industrialized areas of the world, resulting in severe ecotoxicological impacts. Such impacts may lead to drastic effects on the marine food web and to fishery recruitment in coastal waters. Studies of the toxicity of fish eggs and larvae exposed to the SML contaminants have shown that the SML in polluted areas leads to significantly higher rates of mortality and abnormality of fish embryos and larvae.     

一次春季冷空气过程中东海海域海气通量与界面热交换分析

利用船测资料分析一次冷空气过程中东海海域海气通量特征及海洋表面热收支变化特征。2017年5月5日20时—6日14时冷空气过境期间,动量通量平均值为0.22 N·m-2。感热和潜热通量的平均值分别为27.17 W·m-2和90.25 W·m-2,是春季整个观测期间（2017年4月20日—5月26日）平均值的2.8倍和1.1倍。冷空气爆发当天,净热通量为-12.73 W·m-2,海洋失热。白天海表面热收入58.36 W·m-2,影响海面热收支变化的主要是净辐射通量和潜热通量。夜间海表面热支出156.89 W·m-2,海洋作为热源向大气释放潜热99.79 W·m-2,占海洋释放能量过程的63.61%,向大气释放感热27.11 W·m-2,占海表释放热量的17.28%,海表面损失的热量主要以潜热的形式向大气传输。