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顶空气相色谱法测定地层水中的苯系物 总被引:10,自引:2,他引:10
利用极性聚乙二醇弹性石英毛细管柱分离苯系物,在线顶空气相色谱法测定地层水中的苯系物。讨论了色谱柱、载气压力、液相体积、顶空压力、顶空加热温度等因素对测定的影响。该方法实现了地层水中苯、甲苯、乙苯、对二甲苯、间二甲苯、邻二甲苯、异丙苯、苯乙烯等各组分的完全分离,方法的检出限在0.07—0.23μg/L,8次测定相对标准偏差在2.98%-4.91%,加标回收率为95.2%-104%。方法可用于地层水等液体样品中苯系物的测定。 相似文献
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B. Gallego‐Elvira A. Baille B. Martin‐Gorriz J. F. Maestre‐Valero V. Martínez‐Alvarez 《水文研究》2011,25(11):1694-1703
The main objective of this study was to assess the impact of a suspended cover on the evaporation loss of an agricultural water reservoir (AWR). To this aim, a detailed data collection was carried out in a typical AWR located in south‐eastern Spain during 2 consecutive years. During the first year, the reservoir remained uncovered, while during the second year it was covered with a double black polyethylene (PE) shade cloth. On an annual scale, it was observed that the cover can provide a reduction of evaporation loss of 85%. Two approaches, energy balance and mass transfer, were used to analyse the effect of the cover on the evaporation process. Important modifications were observed on the magnitude, sign, annual trend and relative weight of the components of the energy balance. The changes were ascribed to the strong reduction of net radiation and to the substantial weight of the heat storage and sensible heat flux in the energy balance. A relevant finding was the contrast between the patterns of the annual evaporation curve for open‐water and covered conditions. The mass transfer approach allowed discriminating between the wind‐ and radiation‐shelter effects on the evaporation term. The reduction in water‐to‐air vapour deficit was the main factor explaining the high efficiency of the cover, whereas the reduction of the mass transfer coefficient was a modulating factor that accounted for the wind‐shelter effect. Overall, both approaches provided a sound basis to describe and explain the physical mechanisms underlying the high performance of the tested cover. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
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渔用高强度聚乙烯和普通聚乙烯单丝结构与性能的比较研究 总被引:10,自引:1,他引:9
为给渔具设计与材料的合理选配提供科学依据,通过差示扫描量热法(DSC)、广角X射线衍射(WAXD)及扫描电镜(SEM)等方法的比较,研究了渔用高强度聚乙烯(high-strength polyethylene,简称HSPE)和普通聚乙烯(PE)单丝的结构与性能。结果表明,HSPE单丝的断裂强度和结节强度比普通PE单丝分别提高了14.54%,3.05%,而断裂伸长率降低了44.44%;HSPE单丝的结晶度和声速值比普通PE单丝分别增加了6.20%和76.8%;HSPE单丝微晶尺寸稍大于普通PE单丝,而晶胞参数变化很小;HSPE单丝内部结晶形态为平行的串晶和纤维复合结构。正是由于结晶度、取向度的提高以及单丝内部生成了平行的串晶和纤维复合结构,导致了渔用HSPE单丝强度的提高。 相似文献
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Bioavailable contaminant concentrations are an important component in assessing environmental effects as they directly affect ecosystem health. Shellfish contaminant monitoring programmes have traditionally filled this requirement but are being phased out in some jurisdictions. Passive sampling devices (PSDs) have the potential to replace shellfish monitoring; however, there are still knowledge gaps to address before this can occur. This study assessed the suitability of three different PSDs in providing the required information to replace shellfish monitoring. PSDs were deployed at three historic mussel monitoring sites with different levels of urban influence in the Waitemata Harbour, Auckland, New Zealand. Contaminants of interest were urban heavy metals, plus current and emerging organic contaminants. PSDs provided extremely low detection limits and, for some contaminants, very strong correlations to shellfish. PSDs can currently complement shellfish in monitoring, but it is premature to make conclusions as to the suitability of PSDs in replacing shellfish monitoring until more information is available. 相似文献
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中国页岩气资源开发潜力巨大,近年来页岩气勘探开发力度不断加大,对钻探工艺和技术的要求不断提高。页岩气地层岩性主要为泥岩、砂岩、页岩、碳质板岩、灰岩,该类地层胶结性差、破碎、井壁强度低,钻进中易出现孔壁失稳,发生坍塌、卡钻、埋钻等孔内事故,需要研制具有强抑制性、低成本、绿色环保的冲洗液体系来保证施工安全。本文通过对页岩气井壁稳定机理的探究,优选出一种适用于页岩地层双聚防塌和成膜防塌低固相冲洗液体系,该体系由抑制剂、防塌剂、降失水剂、润滑剂、封堵剂、流型调节剂等处理剂组成,具有良好的抑制性和胶结性。现场应用取得了良好的效果,保证了项目的顺利施工。 相似文献
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C Kosore L Ojwang J Maghanga J Kamau A Kimeli J Omukoto 《African Journal of Marine Science》2018,40(3):225-234
Microplastics can be ingested by marine organisms and may lead to negative impacts at the base of marine food chains. This study investigated the occurrence and composition of microplastics in the sea-surface water and sought evidence of ingestion by zooplankton. Surface seawater was collected using a stainless-steel bucket and sieved directly through a stainless-steel sieve (250-µm mesh), while a 500-μm mesh net was towed horizontally to collect zooplankton, at 11 georeferenced stations off the Kenyan coast in February 2017, on board the national research vessel RV Mtafiti. Microplastic particles were sorted and characterised using an Optika dissecting microscope. Polymer types were identified using an ALPHA Platinum attenuated total reflection—Fourier-transform infrared (ATR-FTIR) spectrometer. A total of 149 microplastic particles, with an average abundance of 110 particles m–3, were found in the surface seawater. A total of 129 particles were found ingested by zooplankton groups, where Chaetognatha, Copepoda, Amphipoda and fish larvae ingested 0.46, 0.33, 0.22 and 0.16 particles ind.–1, respectively. Filaments dominated both the surface-water microplastics and the ingested microplastics, contributing 76% and 97% to those compositions, respectively. White particles were prevalent in the water (51%), whereas black was the colour found most commonly (42%) across the zooplankton groups. The sizes of particles that were in the water were in the range of 0.25–2.4 mm, and those ingested ranged between 0.01 and 1.6 mm. Polypropylene was predominant in the surface water, whereas low-density polyethylene was the most-ingested polymer type. The results provide the first documented evidence of the occurrence, composition and ingestion of microplastics by zooplankton in Kenya's marine environment, indicating that microplastics have the potential to enter pelagic food webs and cause pollution in the study area. 相似文献