顶空气相色谱法测定海水二甲基硫和浮游植物细胞二甲基硫丙酸的研究

建立了顶空ＧＣ／ＦＰＤ测定海水中二甲基硫（ＤＭＳ）和浮游植物细胞中二甲基硫丙酸（ＤＭＳＰ）的方法，并研究盐度、温度、气液相比ＤＭＳ诸因素对ＤＭＳ顶空灵敏度的影响。该法对ＤＭＳ测定的相对标准偏差均小于６％，平均回收率为１０６％，最低检出限为２０ｎｇ／Ｌ。细胞ＤＭＳＰ先经碱作用转化为ＤＭＳ，在５０℃下作用时间不少于６ｈ，峰高与浓度的双对数线性相关系数大于０．９９。对１９９４年冬、１９９５年夏采自胶州湾     

Effects of salinity downshock on dimethylsulfide production

During time-series observations in Sagami Bay, Japan, the concentration of dissolved dimethylsulfoniopropionate (DMSP_d), a precursor of dimethylsulfide (DMS), was negatively correlated with salinity. In the laboratory, low-salinity shock reduced DMS production rates of the natural bacterial community and induced rapid DMSP release from a dinophyte, Heterocapsa triquetra, suggesting that low-salinity shock reduced DMSP_d consumption but enhanced DMSP_d production, which agrees with the negative correlation between DMSP_d and salinity observed in Sagami bay. In addition, low-salinity shock did not affect DMSP lyase activity of H. triquetra. Low-salinity shock would increase the contribution from algae in DMS production, leading to an increase in potential DMS productivity in the environment.     

Simple determination of dimethylsulfide (DMS) and dimethylsulfoniopropionate (DMSP) using solid-phase microextraction and gas chromatography-mass spectrometry

Solid-phase microextraction (SPME) is a simple, sensitive and less destructive method for the determination of dimethylsulfide (DMS) in seawater. Combined with detection by gas chromatography-mass spectrometry (GC-MS), the method had sufficient sensitivity (minimum detectable concentration of DMS was 0.05 nM), and practical levels of reproducibility (relative standard deviation ≤7%) and linearity (r ² > 0.995) over a wide concentration range (0.5 to 910 nM). The protocol developed was applied to a Sagami Bay water sample to determine concentrations of DMS and DMSP, and in situ DMSP-lyase activity.     

海水温度对衰亡期浒苔释放生源硫影响的模拟研究

为研究浒苔释放生源硫的特征，本文对采集于黄海绿潮中期和末期的浒苔进行了实验室模拟培养，探讨了不同温度对衰亡期浒苔释放生源硫化物的影响。实验结果表明，在10~25℃温度范围内，温度升高能够加速浒苔的衰亡。二甲基硫（DMS）的平均释放速率范围为2.79~150.70 nmol/（L·g·d），二甲基硫基丙酸内盐（DMSP）的平均释放速率范围为2.16~113.26 nmol/（L·g·d）。温度升高能够使DMS和DMSP的释放速率加快，释放量增加，DMS最大平均释放速率在25℃条件下比10℃条件下升高了约60%，培养液中DMS浓度升高了2~3倍。采集于绿潮末期的浒苔培养液中的DMS和DMSP和采集于绿潮中期的浒苔相比，浓度有所增加，采集于浒苔绿潮末期浒苔培养液中DMS的最高平均浓度为418.41 nmol/L，约为中期的4倍；DMSP的最高平均浓度为316.14 nmol/L，是中期的3倍。浒苔绿潮的爆发会对水体中的硫体系循环产生影响，进而影响该海域生态环境。     

基于夜间灯光和土地利用数据的云南沿边地区GDP空间差异性分析

云南沿边地区包括8个地州,共56个县,其中有25个县市与老挝、缅甸和越南直接毗邻,具有重要的地缘位置。本研究利用土地利用数据和夜间灯光数据在实现云南沿边地区GDP空间化的基础上,对GDP的空间分布格局进行深入探讨,这对缩小区域经济差异及促进地区共同发展具有一定的指导意义。采用土地利用数据对国内生产总值（Gross Domestic Product, GDP）数据的第一产业进行空间化拟合,采用DMSP/OLS夜间灯光数据对GDP的第二、三产业进行拟合,将第一产业和第二、三产业空间化拟合的结果相加,实现云南沿边地区1992-2013年的GDP的空间化拟合。在此基础上对云南沿边地区GDP空间分布差异进行分析。结果表明：① 土地利用数据对第一产业建模的效果较好,拟合的多期数据的相对误差均低于1.12%,采用夜间灯光数据,基于“分类回归”方法对第二、三产业拟合相对误差最大仅为6.404%,最终二者之和拟合的GDP拟合精度都较好,相对误差最大仅为4.241%;② 22期GDP数据在空间分布上均呈现正的相关性,且均为显著集聚;③ GDP空间分布局部集聚的高值-高值区域集中在开远、蒙自等县域,低值-低值地区集中在绿春、西蒙等地区;④ 云南沿边地区县域之间的经济差异在1992-1996年逐渐增强,1996年之后,经济差异波动缩小,空间关联效应呈现波动式的增强和减弱;⑤ 云南沿边地区的三维插值结果均呈现出西北至东南一线的“洼地-丘陵-平地-高峰”地势变化格局,沿边地区的东南角地区即红河州的建水、个旧和开远等县市的GDP最高,“丘陵”地势主要集中在腾冲、保山市以及最南部的景洪地区,“洼地-平地”地势主要分布在沿边地区西北角的贡山和福贡等县域、西南角的西蒙和孟连等县及中部区域的绿春和江城县等地区。     

DMSP/OLS夜间灯光数据研究成果知识图谱分析

利用CitesSpace软件对1997-2017年DMSP/OLS夜间灯光数据进行知识图谱分析,梳理国内外研究热点与演化历史,发掘研究难点,为后来研究者提供方向。本文选取Web of Science 核心数据集数据库收录的文献,进行合著特征分析、关键词共现分析和文献共被引分析。结果表明：① 夜间灯光数据相关研究最活跃的国家、机构和作者分别是美国、中国科学院和Elvidge;② 社会经济条件估计（人口、人口密度和电力）和城市扩展变化监测一直是国内外研究的热点和前沿;③ 目前的研究难点是如何减少灯光溢出效应以及灯光过饱和现象对研究精度的影响;④ 研究学科交叉性强,涉及地理学、测绘科学与技术、应用经济学、社会学等领域。因此,未来的研究趋势主要表现在数据处理方法的优化、研究领域的拓展以及深化已有研究成果3个方面。     

Use of an inside buffer method to extract the extent of urban areas from DMSP/OLS nighttime light data in North China

Defense Meteorological Satellite Program (DMSP)/Operational Linescan System (OLS) nighttime imagery provides a valuable data source for mapping urban areas. However, the spatial extents of large cities are often overestimated because of the effect of over-glow from nighttime light if a fixed thresholding technique is used. In the work reported here, an inside buffer method was developed to solve this issue. The method is based on the fact that the area overestimated is proportional to the extent of the lit area if a fixed threshold is used to extract urban areas in a region/county. Using this method, the extents of urban areas in North China were extracted and validated by interpretations from Landsat Thematic Mapper images. The results showed that the lit areas had a significant linear relationship with the urban areas for 120 representative cities in North China in 2000, with an R² value of over 0.95. This demonstrates that the inside buffer method can be used to extract urban areas. The validation results showed that the inside buffer model developed in 2000 can be directly used to extract the extent of urban areas using more recent nighttime light imagery. This is of great value for the timely updating of urban area databases in large regions or countries.     

基于珞珈一号与DMSP/OLS数据的辽宁省城市空间扩张分析

基于珞珈一号和DMSP/OLS夜间灯光数据,提取辽宁省城市空间用地信息并监测分析了2003—2018年城市空间扩张特征。结果表明:1)利用辽宁省DMSP/OLS长时间序列夜间灯光数据提出了一种适合校正长时间序列DMSP/OLS数据的校正方法,提高了数据的连续性和可对比性;2)弥补了统计数据在空间属性的不足,消除了过去单纯依靠统计数据分析城市空间扩张的弊端,为其他省市分析城市扩张提供新的遥感监测分析方法;3)在2003—2018年间,辽宁省城市空间扩张存在城市空间扩张与南方省份相比发展比较缓慢及协调性欠佳等问题。     

基于DMSP/OLS稳定夜间灯光数据的中国1995-2008年电力消费量时空动态研究(英文)

Electric power consumption (EPC) is one of the basic indices for evaluating electric power use. Obtaining timely and accurate data on the spatiotemporal dynamics of EPC is crucial for understanding and practical deployment of electric power resources. In this study, an EPC model was developed using stable nighttime lights time-series data from the Defense Meteorological Satellite Program Operational Linescan System (DMSP/OLS). The model was used to reconstruct the spatial patterns of EPC in Chinese Mainland at the county level from 1995 to 2008. In addition, the spatiotemporal dynamics of EPC were analyzed, and the fol-lowing conclusions were drawn. (1) The EPC model reliably represented the spatiotemporal dynamics of EPC in Chinese Mainland with approximately 70% accuracy. (2) The EPC in most regions of Chinese Mainland was at low to moderate levels, with marked temporal and spatial variations; of high-level EPC, 58.26% was concentrated in eastern China. Six urban agglomerations (Beijing-Tianjin-Tangshan region, Shanghai-Nanjing-Hangzhou region, Pearl River Delta, Shandong Peninsula, middle-south of Liaoning Province, and Sichuan Basin) accounted for 10.69% of the total area of Chinese Mainland but consumed 39.23% of the electricity. (3) The EPC of most regions in Chinese Mainland increased from 1995 to 2008, and 64% of the mainland area showed a significant increase in EPC. Moderate increases in EPC were found in 61.62% of eastern China and 80.65% of central China from 1995 to 2008, whereas 75.69% of western China showed no significant increase in EPC. Meanwhile, 77.27%, 89.35%, and 66.72% of the Shanghai-Nanjing-Hangzhou region, Pearl River Delta, and Shandong Peninsula, respectively, showed high-speed increases in EPC. Moderate increases in EPC occurred in 71.12% and 72.13% of the Beijing-Tianjin-Tangshan region and middle-south of Liaoning Province, respectively, while no significant increase occurred in 56.34% of the Sichuan Basin.     

基于DMSP/OLS夜间灯光数据进行提取的实证研究——以福州为例

DMSP/OLS数据能够观测到夜间灯光,因而被广泛应用于人类活动与城市扩展研究。本文以福州市为例,分析比较现有夜光数据的城区提取方法。通过实例分析,从阈值设定方面进行讨论,比较各方法的优缺点,可为夜间灯光数据在提取城市区域方面提供借鉴。