THE INTERACTION OF COPPER WITH GOETHITE, HEMATITE AND AMORPHOROUS IRON OXIDE IN SEAWATER

1.This paper deals with a discovery of ours-a new type of isotherm in seawater systems, which cannot be represented by the adsorption isotherm equation available at present in marine chemistry. It has two characteristics as follows: (I) the non-linear relationship between the ion exchanged amount of particulate matter and the equilibrium concentration in the initial low concentration portion of the curve, showing instead an exponental function with slight concave upward. (2) the isotherm is made up of two “S shape” curves, which intersect each othernear the middle, with one “Knee” and two“Plateaus” at the intersection.     

Speciation of adsorbed arsenate on the surface of hydrous iron oxide

Adsorption of arsenate on hydrous iron oxide is an important process controlling geochemical cycling of arsenic in environment as well as the fate of arsenic-bearing mining wastes. The widely accepted view on the mechanism of adsorption is that arsenate is adsorbed via bidentate binuclear inner-sphere complexation. In this study, we characterized the arsenate-hydrous iron oxide sorption solids synthesized at pH=3-8 using Fourier transformed infrared spectroscopy （FTIR） and X-ray diffraction （XRD）. It has been determined that poorly crystalline ferric arsenate developed on the surface of iron oxide when arsenate was sorbed at acidic pH, while at alkaline pH the adsorption of arsenate was via bidentate complexation.     

细菌浸铜技术在紫金山铜矿的应用

介绍了生物浸矿技术在紫金山铜矿的应用及在这一过程中发现的一些问题，并提出了有待进一步解决的一些问题。     

西昆仑山南侧甜水海湖岩芯铁变化的环境记录

阐述了青藏高原西昆仑山南侧甜水海湖岩芯沉积物中氧化铁的丰度、频率分布和富集系数的变化规律。其丰度值范围FeO0．39％-3.95％，平均值为1．25％；Fe2O30．44％－8．09％，平均值为2．60％；Fe2O3／FeO0．21－3．60，平均比值1．12。说明该彻岩芯沉积物中铁平均丰度值较低，但其变化幅度较宽且清楚，在一定程度上反映了古气候环境具有较大幅度的波动。变异系数值表明，该湖岩芯沉积物中FeO的离散程度较Fe2O3大。大约距今23万年来氧化铁的沉积地球化学特征可划分出7个环境演化阶段，并基本上可与深海氧同位索阶段对比。揭示了甜水海湖演化与青藏高原强烈隆升引起的气候环境改变的密切关系。在距今23一15万年，沉积以河流相或冲积、洪积相为主，沉积环境以氧化环境为主导，气候以温干型波动；在距今15－7．4万年，沉积以湖相为主，沉积环境以还原环境为主导，气候以温湿型为主；在距今74万年以来，湖盆沉积环境多样化，沉积物以湖相和近源冲积、洪积相交替出现。气候出现冷湿、冷干、温湿和温干多种波动模式。这些资料分析初步认为甜水海古湖大约形成于距今15万年，即青藏高原第三成湖期，这也与青藏高原在距今15万年左右的再次构造隆升有关。     

论我国铝土矿床类型及其红土化风化壳形成机制问题

中国铝土矿床98%以上为古风化壳型,少量属红土型.前者分六个亚型,即铝硅酸盐岩古风化壳原地残积（Ⅰ_a）;碳酸盐岩古风化壳准原地堆积（Ⅰ_b）、异地堆积（Ⅰ_c）以及异地沉积（湖水）（Ⅰ_d）;I_ca古风化壳异地沉积（海相）;Ⅰ_f碳酸盐岩古风化壳准原地堆积（或沉积）-现代喀斯特堆积等六个亚型.ⅠⅠ_b、Ⅰ_c三亚型矿床在大气条件下就位,就位以后继续红土化,为此矿层很少层理;矿石中常有渗流管、渗流凝胶.Ⅰ_d、Ⅰ_e亚型在水体中沉积,有层理,无渗流管、渗流凝胶.所有铝土矿床的矿物组成及矿石结构、构造都是含铝岩石红土化风化作用易溶物淋失,难溶的钛、铝、铁质残留的风化壳铝土物质;无水体中结构、构造特征;δ18O‰及δD‰值证为风化物;除Ⅰ_c外均无动物化石及其碎屑.     

游离氧化铁形态转化对红粘土工程性质的影响

本文通过模拟环境中的有机质使游离氧化铁形态转化对典型红粘土工程性质的影响试验,系统地测试了游离氧化铁的形态分布与物性指标的关系。试验结果表明,在渍水条件下,游离氧化铁的形态转化对红粘土性质的影响不显著,但在渗水条件下,由于游离氧化铁的流失使得胶结作用减弱,它对红粘土工程性质的影响逐渐明显,其潜在的危害仍然是不容忽视的。     

四川紫色水稻土氧化铁的分异

以岷江冲积物、黄壤残积物发育成的水稻土为对照,研究了紫色砂岩泥岩母质发育成的紫色水稻土氧化铁的形态及其含量和转化。揭示了紫色水稻土具有无定形铁含量,铁活化度较高,氧化铁的转化作用较弱等独特的发生特性。     

太白山土壤特性及氧化铁发生学特征

随海拔的降低,秦岭北坡中山区森林土壤因温度、降水和植被类型的变化存在很大差异:高海拔地区发育的酸性湿润雏形土酸度较高,有机质含量十分丰富;与之相比,低海拔地区发育的简育湿润淋溶土有机质含量下降,但结构复杂,土壤具有粘化层。较高的有机质含量和特殊的有机质组成促进了纯针叶林土壤中硅酸盐矿物的溶解,释放出氧化铁并使之螯迁至土壤B层富集。环境因素决定了土壤酸度、有机质等特性,也影响土壤氧化铁的组成和分布。土壤粘粒含量与土体游离氧化铁含量显著相关,剖面铁的游离度与氧化铁全量无关,只与土壤发育程度有关。太白山北坡中山区土壤处于脱盐基富硅铝化的风化发育阶段     

Refinement of a lunar FeO mapping method

Clementine UVVIS and NIR data from the lunar sampling sites (totaling 46 sampling sites) were processed and used to refine the iron determination method of Le Mouéic et al. (2000, 2002). We found that about 21 sampling sites are unsuitable to Le Mouéic et al's spectral parameters ("slope" and "depth l") because their 1500 nm filter could not be used as spectral parameters' right shoulders and to evaluate the depth of the 1-μm absorption feature accurately. We used the rest 25 sampling sites to refine the method developed by Le Mouéic et al. (2000, 2002 ) and obtained our own equation of FeO content determination. We tested our own equation, and the results are satifactory. In our work we also acquired some useful experiences in scientific applications of our own dataset of the Chang'E-1 mission.