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1.
不同氮源对微小亚历山大藻生长和毒素产生的影响 总被引:12,自引:0,他引:12
通过尿素、氯化铵、酵母浸出粉和硝酸钠等氮源对微小亚历山大藻(Alexandrium minutum)生长及毒素产生的影响研究,分析了微小亚历山大藻对不同氮源利用状况的差异.结果表明,在氮饥饿条件下,加入硝酸钠和酵母浸出粉能显著促进微小亚历山大藻的生长;高浓度的氯化铵在加入后对微小亚历山大藻有一定的毒性效应,表现为生长停滞,但毒性效应在5 d后消失,并得到与添加硝酸钠及酵母浸出粉相似的增长速率0.21 d-1;添加尿素对微小亚历山大藻的生长没有显著促进作用.在四种氮源中,尿素对微小亚历山大藻毒素产生的刺激作用也最弱,在稳定期每个细胞藻细胞毒素含量维持在6.00~8.00 fmol;添加硝酸钠、氯化铵和酵母浸出粉的藻细胞在稳定期毒素含量分别达到11.85,12.86和14.64 fmol.硝酸钠和氯化铵刺激藻毒素产生的效果比酵母浸出粉更为直接.四种含氮营养盐对微小亚历山大藻毒素组成的影响都很小. 相似文献
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The chronological data obtained by a variety of dating methods have confirmed that the sodium enriched metavolcanite series
in the area of the Longbohe copper deposit at Jinping, Yunnan Province, was formed during the Proterozoic (its Pb−Pb isochron
age=1595±75 Ma), corresponding to the Dahongshan Group sodium enriched metavolcanites. The Sm−Nd isochron age of 1336±46Ma
should represent the time at which this series of volcanic rocks experienced spilitization in response to sodium metasomatism,
equivalent to the time of sedimentation of the Ailaoshan Group and Yashan Group rocks. The Rb−Sr ages of the volcanic rocks
and the Pb−Pb ages of copper ores have recorded the events of strong dynamic metamorphism and of strong reworking-metallogenesis
of copper during the Jinningian period. Similarities in forming age, rock assemblage and isotopic characteristics between
the sodium enriched metavolcanite series and the Dahongshan Group sodium enriched metavolcanite series have provided new clues
to the exploration of the Dahongshan-type copper deposits in this area.
Granted jointly by the National Natural Science Foundation of China (Nos. 49702022, 40073001) and the State 973 Program (No.
G1999043215). 相似文献
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氢氧化钠预处理对提高泡塑富集金能力的探讨 总被引:3,自引:1,他引:3
用氢氧化钠处理的泡塑对金的回收率高,富集能力强,并根据金的分布情况对影响泡塑富集能力的原因进行了探讨,为泡塑分离富集金的分析提供了一种新的泡塑予处理方法。 相似文献
7.
Improved Platinum-Group Element Extraction by NiS Fire Assay from Chromitite Ore Samples Using a Flux Containing Sodium Metaphosphate 总被引:1,自引:0,他引:1
Many chromite-rich rocks contain relatively high concentrations of the platinum-group elements (PGE). In many cases, the phases carrying PGE occur as either platinum-group minerals (PGM) or as base metal sulfides in solid solution in sulfides. In some cases, such as the UG-2 unit of the Bushveld Complex, the PGM are occluded inside chromite grains. Chromites are notably difficult to dissolve in most fluxes and if the chromite contains some PGM the possibility exists that not all the PGE will be recovered during fusion. In this work, shortcomings in published methods of analysis based on the nickel sulfide fire assay procedure were investigated and a new procedure developed based on the addition of sodium metaphosphate to the fusion mixture. Optimum composition of the fusion mixture was found to be 10 g sodium metaphosphate and 9 g silica to 10 g sample, 15 g sodium carbonate, 30 g lithium tetraborate, 7.5 g nickel and 4.5 g sulfur to achieve complete dissolution of chromite grains. The new flux mixture was evaluated by the analysis of reference material CHR-Pt+ (which is known to contain PGM inside chromite grains) and no undissolved chromite grains were found in the glassy slag. Analysis of the nickel sulfide beads from this fire assay using neutron activation analysis showed similar results for Rh and Ru when compared with published conventional true (or accepted) values, while Au, Ir, Os, Pd and Pt values determined here were 10 to 30% higher than the corresponding published conventional true values. It was concluded that the addition of sodium metaphosphate improved chromite dissolution in the flux and appears to improve PGE recovery. 相似文献
8.
高效液相色谱-电感耦合等离子体质谱联用检测土壤中的无机硒形态 总被引:3,自引:3,他引:0
土壤样品中亚硒酸盐Se(Ⅳ)和硒酸盐Se(Ⅵ)的形态分析中,提取剂的选择和检测方法是技术的关键。以往的提取剂容易导致硒形态发生转变或无法同时提取Se(Ⅳ)和Se(Ⅵ),常用的氢化物发生原子荧光光谱法无法直接测定Se(Ⅵ),而是通过差减法得出Se(Ⅵ)含量。本文对比了不同提取剂的提取能力,确定使用0. 1 mol/L氢氧化钠溶液作为提取剂,在55℃超声萃取土壤样品30 min,提取液经高效液相色谱分离,电感耦合等离子体质谱检测,建立了土壤中Se(Ⅳ)和Se(Ⅵ)的形态分析方法。采用Hamilton PRP X-100色谱柱,以6 mmol/L柠檬酸为流动相,pH=5. 5,在8 min内可完全分离Se(Ⅳ)和Se(Ⅵ),两者的检出限分别为0. 15μg/L、0. 16μg/L,线性相关系数(r~2)均大于0. 999。以土壤为基体进行加标回收试验,Se(Ⅳ)和Se(Ⅵ)的回收率在84. 2%~95. 8%之间,相对标准偏差为1. 4%~5. 3%(n=6)。该方法简单快速,具有良好的精密度和准确度,适用于土壤中无机硒的形态分析。 相似文献
9.
Application of a Bayesian model to infer the contribution of coalbed natural gas produced water to the Powder River,Wyoming and Montana 下载免费PDF全文
The Powder River Basin (PRB) of Wyoming and Montana contains significant coal and coal bed natural gas (CBNG) resources. CBNG extraction requires the production of large volumes of water, much of which is discharged into existing drainages. Compared to surface waters, the CBNG produced water is high in sodium relative to calcium and magnesium, elevating the sodium adsorption ratio (SAR). To mitigate the possible impact this produced water may have on the quality of surface water used for irrigation, the State of Montana passed water anti‐degradation legislation, which could affect CBNG production in Wyoming. In this study, we sought to determine the proportion of CBNG produced water discharged to tributaries that reaches the Powder River by implementing a four end‐member mixing model within a Bayesian statistical framework. The model accounts for the 87Sr/86Sr, δ13CDIC, [Sr] and [DIC] of CBNG produced water and surface water interacting with the three primary lithologies exposed in the PRB. The model estimates the relative contribution of the end members to the river water, while incorporating uncertainty associated with measurement and process error. Model results confirm that both of the tributaries associated with high CBNG activity are mostly composed of CBNG produced water (70–100%). The model indicates that up to 50% of the Powder River is composed of CBNG produced water downstream from the CBNG tributaries, decreasing with distance by dilution from non‐CBNG impacted tributaries from the point sources to ~10–20% at the Montana border. This amount of CBNG produced water does not significantly affect the SAR or electrical conductivity of the Powder River in Montana. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
10.
本文叙述了用活性炭色层柱分离、亚硫酸钠解吸、TMK-异戊醇萃取比色测定痕量金的方法。采用了以硫酸钴、铬酸钾和硫酸铜等无机盐配制模拟标准系列,可以长期使用。本法操作简单,快速,成本低,工效高。一人一天可以分析30个以上试样,能测定出1×10~(-3)ppm的金含量,适用于地质普查金矿中大批试样的分析。 相似文献