四川石棉独立碲矿床蚀变岩的地质地球化学研究

四川石棉大水沟独立碲矿床堪称世界首例，其矿体两侧的围岩蚀变较窄，且蚀变带与矿脉及未蚀变岩呈清楚而截然的接触关系。主要围岩蚀变为白云石化、白（绢）云母化、云英岩化及电气石化等。这些蚀变作用分别发生于１７７．７～１６５．１Ｍａ和９１．７１～８０．１９Ｍａ。蚀变作用过程中ＳｉＯ２大量析出，Ａｌ２Ｏ３、ＴｉＯ２、ＣａＯ、ＭｇＯ、Ｋ２Ｏ、Ｈ２Ｏ、ＣＯ２、Ｆｅ２Ｏ３、ＭｎＯ则有不同程度地带入。与此同时，ＲＥＥ在此过程中包集体迁出，Ｔｅ、Ｂｉ、ＡＳ等元素的含量则决定于蚀变作用及其强度，而与原岩无关。     

甘新蒙北山地区成矿带划分和基本特征对比

在对甘新蒙北山地区成矿地质背景和成矿在时空上的联系性等综合研究分析基础上,运用新理论、新认识,以板块构造单元划分为基础,将本区划分为3个Ⅲ级成矿带、11个Ⅳ级成矿带,并对Ⅲ级成矿带特征进行了阐述,以期为矿产勘查和地质大调查工作部署提供新的思路和依据。进一步就主要矿床(点)、构造单元、矿种、赋矿建造、控矿因素、成矿类型、成矿时代等方面进行了对比,认为各Ⅳ级成矿带在区域上具有相对稳定的展布范围,具有相同的构造环境和成矿条件、类似的矿种和成矿时代,存在一定的相似性、可比性,并且各成矿带具有一定的潜在找矿价值。     

Metamorphism in Archaean greenstone belts: calculated fluid compositions and implications for gold mineralization

An inescapable consequence of the metamorphism of greenstone belt sequences is the release of a large volume of metamorphic fluid of low salinity with chemical characteristics controlled by the mineral assemblages involved in the devolatilization reactions. For mafic and ultramafic sequences, the composition of fluids released at upper greenschist to lower amphibolite facies conditions for the necessary relatively hot geotherm corresponds to those inferred for greenstone gold deposits (X_CO2= 0.2–0.3). This result follows from the calculation of mineral equilibria in the model system CaO–MgO–FeO–Al₂O₃–SiO₂–H₂O–CO₂, using a new, expanded, internally consistent dataset. Greenstone metamorphism cannot have involved much crustal over-thickening, because very shallow levels of greenstone belts are preserved. Such orogeny can be accounted for if compressive deformation of the crust is accompanied by thinning of the mantle lithosphere. In this case, the observed metamorphism, which was contemporaneous with deformation, is of the low-P high-T type. For this type of metamorphism, the metamorphic peak should have occurred earlier at deeper levels in the crust; i.e. the piezothermal array should be of the ‘deeper-earlier’type. However, at shallow crustal levels, the piezothermal array is likely to have been of ‘deeper-later’type, as a consequence of erosion. Thus, while the lower crust reached maximum temperatures, and partially melted to produce the observed granites, mid-crustal levels were releasing fluids prograde into shallow crustal levels that were already retrograde. We propose that these fluids are responsible for the gold mineralization. Thus, the contemporaneity of igneous activity and gold mineralization is a natural consequence of the thermal evolution, and does not mean that the mineralization has to be a consequence of igneous processes. Upward migration of metamorphic fluid, via appropriate structurally controlled pathways, will bring the fluid into contact with mineral assemblages that have equilibrated with a fluid with significantly lower X_CO2. These assemblages are therefore grossly out of equilibrium with the fluid. In the case of infiltrated metabasic rocks, intense carbonation and sulphidation is predicted. If, as seems reasonable, gold is mobilized by the fluid generated by devolatilization, then the combination of processes proposed, most of which are an inevitable consequence of the metamorphism, leads to the formation of greenstone gold deposits predominantly from metamorphic fluids.     

山东内生金矿矿床谱系及其致矿地质异常

矿床谱系是对成矿多样性的理论概括,而成矿多样性又是由不同级别、不同性质的致矿地质异常决定的.本文论述了山东省内生金矿矿床谱系及其致矿地质异常.     

凤太矿田层控铅锌(铜)矿床的成矿物质来源探讨

秦岭凤太矿田层控铅锌(铜)矿床的金属物质、硫和成矿溶液主要来自深部基底的岩石,属海底喷流—沉积成因矿床。从这一理论认识出发可进一步分析控矿地质条件及今后在该区有效地寻找同类矿床。     

桐柏县固庙—新集1：20万金银异常评价方法及效果

随着河南区域化探扫面工作的结束，异常评价是摆在我们面前的当务之急。近年来，随着地质工作的不断深入，我们在异常评价程序及方法上作了一些探索，下面以桐柏县固庙—新集１：２０万金银异常评价方法及效果为例，重点加以讨论。     

黄金的成色

黄金的成色并不是一成不变的，它成色的高低是与成矿温度、成矿阶段、深度、时代、变质程度、水溶液及风化作用等有一定关系，我们从这些关系中可以寻找到我们找矿的捷径和依据。     

柿竹园矿床大理岩型锡矿石工艺矿物学研究

大理岩型锡矿石产于燕山早、中期千里山花岗岩与中、上泥盆统灰岩的外接触带。矿石呈细脉、网脉浸染状,锡矿物有:锡石、黄锡矿,富钛尼日利亚石、尼日利亚石和木锡矿,脉石矿物绿帘石、石榴石、电气石、萤石、方解石及磁黄铁矿等亦含锡,锡主要呈锡的浊立矿物存在,占总锡量的89.78％,其中锡石锡占总锡量的80.01％,其次有呈类质同象形式存在的锡,在绿帘石、石榴石、电气石等矿物中以Sn~(4+)取代Fe~(3+),这类锡占总量的8.33％。工艺矿物学研究表明,该类锡矿石以“贫”、“细”、“杂”为特征。锡不仅十分分散,而且品位偏低,矿石矿物组合及镶嵌关系复杂、相互包裹,紧密连生;锡矿物粒度微细,粒径一般为0.2～0.01mm,部分为<0.0l～0.002mm,是一种难选的锡矿石类型。通过锡的回收试验,采用选冶联合工艺流程,预测锡的最佳回收率可达50％以上。     

Anhydrite pseudomorphs and the origin of stratiform Cu–Co ores in the Katangan Copperbelt (Democratic Republic of Congo)

The stratiform Cu–Co ore mineralisation in the Katangan Copperbelt consists of dispersed sulphides and sulphides in nodules and lenses, which are often pseudomorphs after evaporites. Two types of pseudomorphs can be distinguished in the nodules and lenses. In type 1 examples, dolomite precipitated first and was subsequently replaced by Cu–Co sulphides and authigenic quartz, whereas in type 2 examples, authigenic quartz and Cu–Co sulphides precipitated prior to dolomite and are coarse-grained. The sulphur isotopic composition of the copper–cobalt sulphides in the type 1 pseudomorphs is between −10.3 and 3.1‰ relative to the Vienna Canyon Diablo Troilite, indicating that the sulphide component was derived from bacterial sulphate reduction (BSR). The generation of during this process caused the precipitation and replacement of anhydrite by dolomite. A second product of BSR is the generation of H₂S, resulting in the precipitation of Cu–Co sulphides from the mineralising fluids. Initial sulphide precipitation occurred along the rim of the pseudomorphs and continued towards the core. Precipitation of authigenic quartz was most likely induced by a pH decrease during sulphide precipitation. Fluid inclusion data from quartz indicate the presence of a high-salinity (8–18 eq. wt.% NaCl) fluid, possibly derived from evaporated seawater which migrated through the deep subsurface. ⁸⁷Sr/⁸⁶Sr ratios of dolomite in type 1 nodules range between 0.71012 and 0.73576, significantly more radiogenic than the strontium isotopic composition of Neoproterozoic marine carbonates (⁸⁷Sr/⁸⁶Sr = 0.7056–0.7087). This suggests intense interaction with siliciclastic sedimentary rocks and/or the granitic basement. The low carbon isotopic composition of the dolomite in the pseudomorphs (−7.02 and −9.93‰ relative to the Vienna Pee Dee Belemnite, V-PDB) compared to the host rock dolomite (−4.90 and +1.31‰ V-PDB) resulted from the oxidation of organic matter during BSR.     

能量色散X射线荧光光谱法测定钼矿石中钼铅铁铜

建立了能量色散X射线荧光光谱法测定钼矿石中钼、铅、铁、铜的方法,讨论了粒度效应、矿物效应的影响因素,确定了采取粉末样品,用系列标准样品建立工作曲线,通过元素间相互校正消除基体效应,用内控标准样品考察了方法的精密度(RSD,n=11)为0.44%～15.4%。实际样品的测定结果和化学法相符,可满足日常分析工作需要。