车排子凸起轻质油成熟度分析与烃源层再认识

通过对车排子凸起南部轻质油的甲基双金刚烷和甲基菲参数分析,发现其成熟度已达等效镜质组反射率约1.3％～1.6％的高过成熟阶段.结合周边凹陷烃源岩演化特征分析,认为该区轻质油来源于侏罗系烃源岩的可能性较小,来自二叠系高过成熟烃源岩的可能性较大.该区轻质油地球化学特征与二叠系烃源岩差异较大,而与白垩系和古近系烃源岩地球化学特征相似,推断该高过成熟油气中不含生物标志化合物或生物标志化合物含量极低,其现有特征是在运移过程中受成熟度较低而生物标志化合物含量丰富的烃源岩可溶有机质浸染所致.这一认识不但对揭示研究区的油气成藏规律具有重要的理论和实践意义,也将为准噶尔南部深凹区及山前坳陷区轻质原油及天然气来源的重新认识提供合理的参考依据.     

内蒙古西部额济纳旗苦水沟地区下石炭统白山组烃源岩分子化石的特征

采用气相色谱、气相色谱-质谱技术,对额济纳旗苦水沟地区白山组烃源岩分子化石的特征进行了研究,剖析了分子化石蕴含的生源、沉积环境、成熟度等方面的信息及石油地质意义。白山组烃源岩饱和烃气相色谱为“前峰型”的单峰分布,主峰碳以C18为主, 表明有机质来源以海相有机质为主,Pr/Ph介于0.4~0.6之间,指示强还原的沉积环境。白山组烃源岩具有“长侧链的三环萜烷丰富、伽马蜡烷含量高和C27甾烷分布占优势”的分子化石组合特征,高伽马蜡烷含量揭示烃源岩有机相为咸水沉积环境,藿烷/甾烷比值的平均值为1.06,表明细菌和藻类对有机质的贡献处于均势,C27甾烷丰度较高,说明低等水生生物藻类是生烃母质主要的生源构成。甲基菲指数是衡量高演化有机质热演化的有效分子参数指标,白山组烃源岩甲基菲指数介于0.36~0.67之间,折算的镜质体反射率Rc为1.9~2.1,与实测的镜质体反射率相当,说明白山组烃源岩热演化处于过成熟阶段。     

内蒙古额济纳旗大狐狸山地区干泉组烃源岩 生物标志化合物特征及意义

以气相色谱、气相色谱-质谱为技术手段,对额济纳旗大狐狸山地区干泉组烃源岩的生物标志化合物进行研究,剖析生物标志化合物指示的母质来源、沉积环境、成熟度等方面的信息.干泉组烃源岩饱和烃气相色谱为”前峰型”的单峰分布,主峰碳以C1s为主,说明有机质来源以海相有机质为主,Pr/Ph介于0.3～0.6之间,指示强还原的沉积环境.干泉组烃源岩具有长侧链的三环萜烷丰富、伽马蜡烷含量高和C27甾烷分布占优势的生物标志化合物组合特征,高伽马蜡烷含量揭示烃源岩有机相为咸水沉积环境,藿烷/甾烷比值的平均值为0.59,表明藻类对有机质的贡献高于细菌.C27甾烷丰度较高,说明低等水生生物藻类是生烃母质的主要生源.干泉组烃源岩甲基菲指数介于0.35～0.50,其折算的镜质体反射率R.为2.00～2.09,与实测的镜质体反射率指示意义一致,说明干泉组烃源岩热演化处于过成熟阶段.     

Polycyclic aromatic hydrocarbons in the Jurassic–Cretaceous Tetori Group,central Japan

Primary data on the organic geochemistry of the Tetori Group provide basic information about depositional environments and thermal maturation of organic matter through two geological sections in the Hokuriku region, central Japan. The thermal maturity of organic matter was evaluated by the methylphenanthrene index‐1. The maturity progressively increases stratigraphically down through the Izumi section in Fukui Prefecture. The estimated vitrinite reflectance equivalent is <1.35% near the top of the section, gradually increasing to >2.0% near the base. The thermal maturation process can account for stratigraphic changes in abundance of PAHs through this section. However, the occasional occurrence of coronene in the middle of the Izumi section is attributed to possible paleo‐wildfires that supplied more coronene to the depositional site. The stratigraphic distribution of PAHs through the Tateyama section, Toyama Prefecture, also can be explained by the same scenario as envisaged for the Izumi section, but weathering and/or other secondary factors may have partly modified primary signals for this section. Polycyclic aromatic sulfur compounds were observed in nearly all samples from both sections, even in samples for which a freshwater paleoenvironment is surmised. Most plausibly, some reduced sulfur was re‐oxidized to elemental sulfur, which persisted in the sediments and may have contributed to the formation of aromatic sulfur compounds. Hence, polycyclic aromatic sulfur compounds do not provide an index to separate marine environments from the freshwater settings for the Tetori Group.     

Influences of ore formation on biomarkers in the Kupferschiefer from the Lubin mine, Poland

Molecular biomarkers are the important maturity parameters for sedimentary organic matter.They have also been widely used for determining the maturity of organic matter in ore deposits. However,during the study of organic matter in the Kupferschiefer from the Lubin mine, it had been found that the biomarkers were influenced by sulfide formation. In order to probe into the degree of influence on biomarkers, seven samples collected from a Kupferschiefer section from the Lubin mine were analyzed by various geochemical methods. The results indicated that in the samples with higher copper contents, the values of biomarkers are lower than in the samples with lower copper contents. In highly mineralized samples, hydrogen donation for thermochemical sulfate reduction (TSR) occurred in alkylated phenanthrenes and naphthalenes, leading to the decrease of 12 biomarker parameters during the Kupferschiefer mineralization.     

定量表征原油裂解程度的模拟实验研究

原油裂解程度反映了原油在地质体中经历高演化阶段后向天然气转变的程度。定量表征原油裂解程度．可为原油裂解气资源量的评价提供重要依据。本文在模拟实验研究的基础上,综合分析讨论了原油热裂解过程中化学组分的变化特征,包括化合物组成和浓度的变化,这些变化特征是原油裂解程度量化描述的基础。因此,可建立模拟实验过程中原油裂解程度与变化特征参数之间的定量关系,将这种定量关系应用于塔里木盆地台盆区海相原油研究,从而为研究区海相原油裂解程度的研究提供一种参考方法和标准。