琼西抱板群变质沉积岩地球化学研究

琼西中元古代抱板群变质沉积岩可分为白云母石英片岩组和石英二云母片岩组，其原岩为砂岩质泥质沉积岩夹火山物质。白云母石英片岩组和石英二云母片岩组在地球化学成分上的差异是原始沉积化学分异作用的结果。对主元素、微量元素（含稀土元素）及Sm-Nd同位素的综合研究表明，海南岛存在古元古代或更早的古老基底，抱板群变质沉积岩一部分来源于成熟度较低的古老地壳物质，另一部分来源于含地幔火山物质较多的初生地壳，或与研究区大规模造山运动、构造－岩浆活动所伴生的地幔物质加入有关。初步研究显示，琼西抱板群变质沉积岩可能是造山带岛弧和活动大陆边缘区（扩张弧后或弧间盆地）大地构造环境下的沉积产物。     

A comparison of the evolution of diamondiferous quartz-rich rocks from the Saxonian Erzgebirge and the Kokchetav Massif: are so-called diamondiferous gneisses magmatic rocks?

The petrography and chemical composition of minerals of quartz-rich diamondiferous rocks from the Kokchetav Massif, especially the zonation of garnet, were studied and compared with diamondiferous quartzofeldspathic rocks from the Saxonian Erzgebirge. Many compositional and textural features were found to be similar. For instance, microdiamonds are enclosed systematically in a specific intermediate growth zone of garnet in these rocks. On the basis of experimental data, a magmatic scenario was constructed to check if the quartz-rich diamondiferous rocks are of magmatic origin. By this, the P-T paths, derived here for the Kokchetav rocks, and the textural observations it is concluded that the minerals of the diamondiferous rocks have crystallized from silicate melts. These melts originated by anatexis of deeply submerged metasediments (Erzgebirge: at T as high as 1200°C, Kokchetav Massif: at 50-100°C lower T) and ascended from at least 200 km depth. Relics of the pre-anatectic evolution are still present, for instance, as garnet cores. After ascent and emplacement of the magma in deep portions of thickened continental crust (Kokchetav Massif: 45-50 km close to 800°C, Erzgebirge: 55-60 km at 30-50°C lower T) considerable quantities of (white and/or dark) micas formed by peritectic reactions from melt. For instance, garnets could be resorbed at this stage and biotite grew instead. After the magmatic stage, retrogression took place much stronger in the Kokchetav Massif. This was accompanied by deformation transforming broadly the magmatic texture of quartz-rich diamondiferous rocks from the Kokchetav Massif to a gneissic texture.     

湘西南高涧群的地球化学特征及其意义

湘西南高涧群主要是一套浅变质沉积碎屑岩系，由变质泥岩、板岩和变质粉砂岩组成，原岩颗粒小。变质作用对岩石化学成分没有大的改变,岩石具有相近的风化蚀变指数（平均CIA＝75）风化蚀变矿物主要为伊利石－白云母－蒙脱石组合。主要化学成分反映沉积物来源于中性和基性火成岩区。浅变质沉积岩中大多数微量元素亏损，元素Cu,Zn,Co,Ti,Cr等在研究区的南部和北部具有相似的共生组合。并且稀土元素的分布模式基本相同，稀土的总量与岩性有关。上述特点显示了高涧群沉积物来源相同，亲石元素共生组合相似；Au,Ag,As,Sb,Sr,Ba等存在一定的分异，Ba/Co比值，Sr/Ba比值和δCe值表明，它是主要在浅深海－深海相还原环境下的产物。     

北祁连榴辉岩相变沉积岩的特征及其构造意义

在北祁连造山带中,出露典型的高压/低温变质岩石,前人对其中的低温榴辉岩已做过较多的研究,但对其中的变沉积岩研究涉及很少.本文展示了榴辉岩相变质沉积岩的岩石学、地球化学、锆石U-Pb年代学和Hf同位素方面的一些新的研究结果.变沉积岩含有榴辉岩相的矿物组合,峰期温压条件为t= 450～520℃,p=1.9～2.3 GPa,与相邻榴辉岩的温压条件一致.地球化学显示这些岩石的原岩为不成熟的沉积岩,可能形成于大陆边缘或大陆岛弧环境.变沉积岩中的碎屑锆石U-Pb年龄主要集中在1800 Ma左右和540～600 Ma之间,结合锆石Hf同位素特征,表明其原岩的碎屑来源既有周缘陆块的前寒武纪变质基底物质,又有新元古代-早古生代新生洋壳或增生物质.同时,这些数据也表明北祁连早古生代洋壳俯冲过程中发生了活动大陆边缘的构造剥蚀作用,即形成于上盘的沉积物(弧前盆地或增生楔)被构造作用运移到俯冲带中,并俯冲到60～70km深处,遭受榴辉岩相变质作用,然后折返到地表.     

Influence of ferric iron on phase equilibria in greenschist facies assemblages: the hematite‐rich metasedimentary rocks from the Monti Pisani (Northern Apennines)

We have investigated the effects of different Fe₂O₃ bulk contents on the calculated phase equilibria of low‐T/intermediate‐P metasedimentary rocks. Thermodynamic modelling within the MnO–Na₂O–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–O (MnNKFMASHTO) chemical system of chloritoid‐bearing hematite‐rich metasedimentary rocks from the Variscan basement of the Pisani Mountains (Northern Apennines, Italy) fails to reproduce the observed mineral compositions when the bulk Fe₂O₃ is determined through titration. The mismatch between observed and computed mineral compositions and assemblage is resolved by tuning the effective ferric iron content by P–XFe₂O₃ diagrams, obtaining equilibration conditions of 475 °C and 9–10 kbar related to a post‐compressional phase of the Alpine collision. The introduction of ferric iron affects the stability of the main rock‐forming silicates that often yield important thermobaric information. In Fe₂O₃‐rich compositions, garnet‐ and carpholite‐in curves shift towards higher temperatures with respect to the Fe₂O₃‐free systems. The presence of a ferric‐iron oxide (hematite) prevents the formation of biotite in the mineral assemblage even at temperatures approaching 550 °C. The use of P–T–XFe₂O₃ phase diagrams may also provide P–T information in common greenschist facies metasedimentary rocks.     

Detrital zircon ages and Hf isotopic compositions of metasedimentary rocks in the Wuqia area of Southwest Tianshan,NW China: implications for the early Paleozoic tectonic evolution of the Tianshan orogenic belt

ABSTRACT

The Chinese Southwest Tianshan Orogenic Belt is located along the boundary between the Central Asian Orogenic Belt (CAOB) and the Tarim Block (TB), NW China. It records the convergence of the Tarim Block and the Middle Tianshan, and is, therefore, a crucial region for understanding the Eurasia continental growth and evolution. The Wulagen (geographical name) metasedimentary rocks of the Wuqia area (mainly metamorphic sandstones and mica schists) form one of the metamorphic terranes in the Southwestern Tianshan Orogenic Belt. The geochronology of these rocks is poorly known, which hampers our understanding of the tectonic evolution of the belt. We analyzed 517 zircon grains for detrital zircon U–Pb dating and 93 zircon grains for in situ Lu–Hf isotopic compositions from the Wulagen metasedimentary rocks. The analyzed zircon grains yield Neoarchean to late Paleozoic U–Pb ages with major age peaks at ~2543 Ma, 1814 Ma, 830 Ma, 460 Ma, and the youngest cluster of zircon (magmatogene) ages is 395 Ma. The zircon U–Pb data show that the late Paleozoic (Early Devonian) is the maximum depositional age of the Wulagen metasedimentary rocks, rather than the previously considered Precambrian period. The zircons with Paleozoic ages yield εHf(t) values of ?22.0 to +11.3 and two-stage model ages (TDM₂) of 3.95 to 1.30 Ga, suggesting that the parental magmas were formed from partial melting of pre-existing crustal rocks. Our zircon U–Pb geochronology and Hf isotopic data indicate the major source regions for the Wulagen metasedimentary rocks was the Kyrgyzstan North Tianshan. The zircon age population of 600–400 Ma (peak at ~460 Ma) has negative εHf(t) values (?15.0 to ?0.6) and Mesoproterozoic two-stage model ages, suggesting that the early Paleozoic magmatism resulted mainly from the melting of ancient crust, which played an important role in crustal evolution in the southern CAOB.     

阿尔泰造山带喀纳斯群变质碎屑岩地球化学特征及年代学研究

喀纳斯群为一套巨厚的中低压型浅变质碎屑岩系,主要由片岩、片麻岩、变质砂岩等组成,其形成时代未有统一的认识,致使阿尔泰构造带的构造演化过程争议较大。对喀纳斯群变质岩进行原岩恢复,认为该套变质岩为副变质岩,考虑到变质碎屑岩的成岩物质继承母岩特征和变质程度的影响,利用碎屑岩研究方法对元素地球化学特征进行探讨,显示出喀纳斯群变质碎屑岩原岩形成环境以大陆岛弧为主,兼有活动大陆边缘的特征,CIA、ICV指数反应出原岩经历了相对温暖、湿润的风化作用,成熟度较低。锆石U-Pb定年结果表明,最年轻的锆石年龄集中在(500±3.0)Ma,代表喀纳斯群的上限年龄,认为该套地层形成于晚寒武世晚期之前,为一套形成于大陆岛弧或活动大陆边缘的复理石建造。新元古代青白口纪初期基底裂解事件,暗示着阿尔泰构造带存在前寒武纪大陆地壳基底。     

华北克拉通古老物质记录——焦作地区太古宙变质岩的锆石SHRIMP U-Pb定年和LA-MC-ICPMS Hf同位素分析

本文报道了华北克拉通中部焦作地区太古宙变质岩的锆石U-Pb定年和Hf同位素分析结果。二云钾长片麻岩的碎屑锆石和变质锆石年龄分别为3.3~3.4 Ga和2.47±0.02 Ga,碎屑锆石的ε_(Hf)(3.40Ga)和t_(DM2(CC))。值分别为-2.4~+13.9和2.89~3.84 Ga,变质锆石的ε_(Hf)(2.47Ga)和t_(DM2(CC))值分别为-18.8~-6.4和3.38~4.13 Ma。黑云角闪片麻岩中只存在变质锆石,年龄为2.49±0.01 Ga,变质锆石的ε_(Hf)(2.49Ga)和t_(DM2(CC))值分别为~15.0~-3.8和3.23~3.91 Ga。结合地球化学和前人研究成果,可得出如下结论:①碎屑物质来自以3.4 Ga花岗质岩浆岩为主的物源区,物源区岩石具有相当的规模,是壳幔混合作用的产物,形成过程中有更古老(始太古代)陆壳物质参与;②岩石遭受约2.5 Ga强烈构造热事件作用,深熔作用导致花岗质脉体形成;③可把变质碎屑沉积岩形成(沉积)时代限制在2.5~3.3 Ga之间;④变质锆石的Hf同位索组成与核部锆石的十分类似,变质增生边主要形成于核部锆石的溶解—再沉淀作用。     

Geochemical diagnostics of metasedimentary dark enclaves: a case study from the Peninsular Ranges Batholith,southern California

Dark enclaves rich in amphibole and biotite are ubiquitous in granitoid rocks and typically represent fragments of mafic magmas, cumulates, restites, or country rocks. To develop criteria for identifying dark enclaves of non-magmatic origin, we investigated dark enclaves from a complete spectrum of light (carbonate- or feldspar-rich) to dark (amphibole-rich, biotite-rich, or composite) enclaves, reflecting progressive thermal and chemical equilibration with the host tonalite, the Domenigoni Valley pluton in the Peninsular Ranges Batholith, California. Metasedimentary dark enclaves have geochemical characteristics that overlap those of literature-compiled igneous dark enclaves. When compared with modelled igneous differentiation paths, metasedimentary enclaves can have anomalous CaO and K₂O contents for a given SiO₂, but other major-element systematics may not deviate noticeably from igneous differentiation trends. In addition, the fact that literature-compiled mafic enclaves trend towards high K₂O + CaO suggests that not all mafic enclaves are of igneous origin. In this work, we provide criteria for identifying enclaves of possible metasedimentary origin.     

赣中南新元古代潭头群变质沉积岩物源及构造背景

赣中南一带广泛出露前震旦纪新元古代潭头群变质沉积岩,地层中火山岩较发育,属火山-沉积碎屑岩组合。其砂质岩石具有中等含量的SiO2（64．81％～71．77％,平均为68．30％）,较低的FeOt＋MgO（4．08％～6．99％,平均为5．74％）和较高的K2O／Na2O（0．75～3．33,平均为1．64）及Al2O3／TiO2（26．02～43．47,平均为31．73）。稀土总量较高（∑REE为158．44×10^-6～293．36×10^-6。平均为237．98×10^-6）,轻稀土明显富集。所有样品的稀土分布模式相似,明显向右倾斜,具有中等程度的Eu异常（δEu为0．42～0．61,平均为0．48）。微量元素平均含量与上地壳平均组分相当。地球化学特征表明,赣中南新元古代潭头群变质沉积岩可能来源于古-中元古代地层。结合变质岩的沉积环境及其火山岩特征,研究认为潭头群的构造背景属岛弧环境,可能与新元古代华夏陆块和扬子陆块的俯冲碰撞有关。