Asymmetrically zoned reaction rims: assessment of grain boundary diffusivities and growth rates related to natural diffusion-controlled mineral reactions

This study explores garnet coronas around hedenbergite, which were formed by the reaction plagioclase + hedenbergite→garnet + quartz, to derive information about diffusion paths that allowed for material redistribution during reaction progress. Whereas quartz forms disconnected single grains along the garnet/hedenbergite boundaries, garnet forms ～20‐μm‐wide continuous polycrystalline rims along former plagioclase/hedenbergite phase boundaries. Individual garnet crystals are separated by low‐angle grain boundaries, which commonly form a direct link between the reaction interfaces of the plagioclase|garnet|hedenbergite succession. Compositional variations in garnet involve: (i) an overall asymmetric compositional zoning in Ca, Fe²⁺, Fe³⁺ and Al across the garnet layer; and (ii) micron‐scale compositional variations in the near‐grain boundary regions and along plagioclase/garnet phase boundaries. These compositional variations formed during garnet rim growth. Thereby, transfer of the chemical components occurred by a combination of fast‐path diffusion along grain boundaries within the garnet rim, slow diffusion through the interior of the garnet grains, and by fast diffusion along the garnet/plagioclase and the garnet/hedenbergite phase boundaries. Numerical simulation indicates that diffusion of Ca, Al and Fe²⁺ occurred about three to four, four and six to seven orders of magnitude faster along the grain boundaries than through the interior of the garnet grains. Fast‐path diffusion along grain boundaries contributed substantially to the bulk material transfer across the growing garnet rim. Despite the contribution of fast‐path diffusion, bulk diffusion through the garnet rim was too slow to allow for chemical equilibration of the phases involved in garnet rim formation even on a micrometre scale. Based on published garnet volume diffusion data the growth interval of a 20‐μm‐wide garnet rim is estimated at ～10³–10⁴ years at the inferred reaction conditions of 760 ± 50 °C at 7.6 kbar. Using the same parameterization of the growth law, 100‐μm‐ and 1‐mm‐thick garnet rims would grow within 10⁵–10⁶ and 10⁶–10⁷ years respectively.     

An experimental study of the grain-scale processes of peridotite melting: implications for major and trace element distribution during equilibrium and disequilibrium melting

The grain-scale processes of peridotite melting were examined at 1,340°C and 1.5 GPa using reaction couples formed by juxtaposing pre-synthesized clinopyroxenite against pre-synthesized orthopyroxenite or harzburgite in graphite and platinum-lined molybdenum capsules. Reaction between the clinopyroxene and orthopyroxene-rich aggregates produces a melt-enriched, orthopyroxene-free, olivine + clinopyroxene reactive boundary layer. Major and trace element abundance in clinopyroxene vary systematically across the reactive boundary layer with compositional trends similar to the published clinopyroxene core-to-rim compositional variations in the bulk lherzolite partial melting studies conducted at similar P–T conditions. The growth of the reactive boundary layer takes place at the expense of the orthopyroxenite or harzburgite and is consistent with grain-scale processes that involve dissolution, precipitation, reprecipitation, and diffusive exchange between the interstitial melt and surrounding crystals. An important consequence of dissolution–reprecipitation during crystal-melt interaction is the dramatic decrease in diffusive reequilibration time between coexisting minerals and melt. This effect is especially important for high charged, slow diffusing cations during peridotite melting and melt-rock reaction. Apparent clinopyroxene-melt partition coefficients for REE, Sr, Y, Ti, and Zr, measured from reprecipitated clinopyroxene and coexisting melt in the reactive boundary layer, approach their equilibrium values reported in the literature. Disequilibrium melting models based on volume diffusion in solid limited mechanism are likely to significantly underestimate the rates at which major and trace elements in residual minerals reequilibrate with their surrounding melt. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Si diffusion in zircon

Self-diffusion of Si under anhydrous conditions at 1 atm has been measured in natural zircon. The source of diffusant for experiments was a mixture of ZrO₂ and ³⁰Si-enriched SiO₂ in 1:1 molar proportions; experiments were run in crimped Pt capsules in 1-atm furnaces. ³⁰Si profiles were measured with both Rutherford backscattering spectrometry (RBS) and nuclear reaction analysis with the resonant nuclear reaction ³⁰Si(p,γ)³¹P. For Si diffusion normal to c over the temperature range 1,350–1,550°C, we obtain an Arrhenius relation D = 5.8 exp(−702 ± 54 kJ mol⁻¹/RT) m² s⁻¹ for the NRA measurements, which agrees within uncertainty with an Arrhenius relation determined from the RBS measurements [62 exp(−738 ± 61 kJ mol⁻¹/RT) m² s⁻¹]. Diffusion of Si parallel to c appears slightly faster, but agrees within experimental uncertainty at most temperatures with diffusivities for Si normal to c. Diffusion of Si in zircon is similar to that of Ti, but about an order of magnitude faster than diffusion of Hf and two orders of magnitude faster than diffusion of U and Th. Si diffusion is, however, many orders of magnitude slower than oxygen diffusion under both dry and hydrothermal conditions, with the difference increasing with decreasing temperature because of the larger activation energy for Si diffusion. If we consider Hf as a proxy for Zr, given its similar charge and size, we can rank the diffusivities of the major constituents in zircon as follows: D _Zr < D _Si << D _{O, dry} < D _{O, ‘wet’}.     

高桩码头桩基负摩擦力现场试验研究 ——上海洋山深水港工程现场试验

高桩码头接岸结构中的桩基础,在抛石的作用下将产生负摩擦力。通过支撑桩及自由桩上负摩擦力的现场试验研究,获得抛石过程中基桩内力随深度变化的基本规律。抛石过程中基桩上的负摩擦力主要产生在抛石段。同时,抛石作为附加荷载,将引起下方软弱土层的固结沉降,桩土之间产生相对位移,从而在抛石段下方一定范围内也产生负摩擦力作用。承台荷载对负摩擦力的大小和分布有着重要的影响。提出的负摩擦力分布规律和采用有效应力法计算层状土负摩擦力的公式,可为桩基础的设计,尤其对水下单面抛石施工的设计及采取消减负摩擦力的措施提供依据。     

钱二块铀矿床采铀注液结垢趋势的理论分析与预测

用离子系数矩阵法对钱二块铀矿床地浸采铀试验注液中存在的独立离子反应进行了确定,由溶度积规则及反应平衡原理,借助Matlab编程,估算出了钱二块铀矿床地浸采铀试验注液可能会生成的沉淀物种类及数量,为防治结垢提供了一定的理论依据.     

地磁场强度变化对暴露年代测定的影响及校正

在103-105a的尺度上,地磁场强度变化是影响陆地宇生核素生成速率的主要因素,其影响程度取决于样品的地理位置和暴露时间。根据已有的磁场古强度数据,模拟200 ka以来海拔2 km、25°N和40°N的地表10Be生成速率的变化,进而分析地表宇生核素生成速率变化对岩石暴露年代测定的影响及其模式年龄的校正。校正磁场强度变化后,海拔2 km、25°N上,50-200 ka的模式年龄可被压缩14%~19%,大于1σ的误差,相同海拔40°N上的模式年龄可减小约8%。对中低纬两组模式年龄的校正充分证明,磁场强度引起的陆地宇生核素生成速率变化是暴露年代测定中主要误差源之一,尤其在低纬高海拔地区这一影响更不容忽视。     

海藻硫酸多糖911对小鼠脾淋巴细胞增殖反应及对细胞产生IL—2作用的影响

本文以~3H—TdR掺入法观察911对小鼠脾淋巴细胞增殖反应的影响并用CTLL细胞检测了其对IL—2的作用。体外实验结果表明,911对小鼠脾淋巴细胞增殖反应有明显的增强作用,以0.5μg/ml的浓度效果最为明显,相对增殖指数RPI可达200％;体内实验则以5mg/kg体重ip,连续7d效果最好,相对增殖指数RPI可达176％;911用药组小鼠IL—2的产生量均高于对照组,以5mg/kg和10mg/kg效果最好。以上实验证明,这一多糖是一种有希望的新免疫调节药物。     

尼罗罗非鱼对不同颜色定置网片的反应特性

本文初步研究了尼罗罗非鱼对红、黄、绿、蓝、青灰色定置网片反应特性,并探讨了该鱼对青灰色网片的适应特性。结果表明:绿色网片对罗非鱼的阻拦作用最大,青灰色网片次之,红、黄色网片再次,蓝色网片最小。罗非鱼对青灰色网片具明显的适应现象,它们完成整个适应过程所需的实验重复次数约为7次。     

海底孔压对波浪响应试验研究及数值模拟

孔隙水压力在海底土尤其在砂性海床中扮演着一个非常重要的角色.波浪的周期性加载作用,在砂土及粉土中产生超静孔隙水压力,其幅值大小是海床发生液化破坏的控制因素.在海上工程的历次调查中发现孔压引起许多液化破坏现象,如粉土海床的塌陷、凹坑、坡度较大处的粉砂流及构筑物基础周围的过量冲刷造成石油管架下沉等等,因此研究海床中孔压对波浪的响应具有重要的理论意义和实践意义.     

十红滩砂岩型铀矿床地浸采铀水文地质条件分析及评价

分析了十红滩砂岩型铀矿床地浸采铀水文地质条件,对浸铀的有利和不利因素进行了评价,并运用地球化学模式证明传统的酸法和碱法浸铀试验不适合十红滩铀矿床,并对浸铀的方法提出了一些建议和设想。