南海高钙沉积物中18种常微量元素的ICP-AES测定方法研究

在利用ICP-AES分析南海高钙沉积物中的常微量元素时,钙、镁常常干扰其它元素测试。通过采用优化仪器工作参数、扣除背景值、谱线干扰校正和基体匹配的步骤,消除了元素干扰和钙、镁基体效应,提高了方法的灵敏度和准确度。通过对南海沉积物样品的大量实验和国家一级标准样验证,建立了适宜高钙海洋沉积物元素含量的ICP-AES测试方法。该方法检出限为1.55~271μg/L,相对标准偏差RSD<4.54%(n=6)。     

ROCKS & MINERALS DETERMINATION AND ANALYSIS

正20140786Deng Zhenping(Institute of Karst Geology,Chinese Academy of Geological Sciences,Guilin 541004,China);Yang Wen-qiong Application of Stripping Voltammetry with a Solid Amalgam Electrode for Determination of Copper in a Tracer and Groundwater Tracing Experiment(Rock and Mineral Analy-     

A timescale decomposed threshold regression downscaling approach to forecasting South China early summer rainfall

A timescale decomposed threshold regression(TSDTR) downscaling approach to forecasting South China early summer rainfall(SCESR) is described by using long-term observed station rainfall data and NOAA ERSST data. It makes use of two distinct regression downscaling models corresponding to the interannual and interdecadal rainfall variability of SCESR.The two models are developed based on the partial least squares(PLS) regression technique, linking SCESR to SST modes in preceding months on both interannual and interdecadal timescales. Specifically, using the datasets in the calibration period 1915–84, the variability of SCESR and SST are decomposed into interannual and interdecadal components. On the interannual timescale, a threshold PLS regression model is fitted to interannual components of SCESR and March SST patterns by taking account of the modulation of negative and positive phases of the Pacific Decadal Oscillation(PDO). On the interdecadal timescale, a standard PLS regression model is fitted to the relationship between SCESR and preceding November SST patterns. The total rainfall prediction is obtained by the sum of the outputs from both the interannual and interdecadal models. Results show that the TSDTR downscaling approach achieves reasonable skill in predicting the observed rainfall in the validation period 1985–2006, compared to other simpler approaches. This study suggests that the TSDTR approach,considering different interannual SCESR-SST relationships under the modulation of PDO phases, as well as the interdecadal variability of SCESR associated with SST patterns, may provide a new perspective to improve climate predictions.     

广东良口黄田埔高分异Ⅰ型花岗岩地球化学特征及大地构造意义

广州从化区良口亚髻山霞石正长岩为典型岩石遗迹,在碱性岩体野外填图研究过程中,新发现东侧分布有黄田埔高分异花岗岩,形成时间约(146±13)Ma,为晚侏罗世岩浆活动产物。元素地球化学特征显示硅高、钾富、分异指数高、Rb/Sr比值高以及Rb/Ba、Nb/Ta、Zr/Hf、TFeO/MgO比值低;稀土元素ΣREE平均值为248 g/t,ΣCe/ΣYb平均值为2.34,δEu(0.16)负异常明显;Ga(×10~4)/Al比值较低(平均值为3.47),Zr+Nb+Ce+Y含量(平均值为264g/t)低于A型花岗岩(350 g/t);I(Sr)值为0.691 8~0.712 8,平均值为0.708 1;ε_(Nd)(t)值为-3.5~-10.0,平均值为-6.7。元素地球化学、同位素地球化学和同位素年代学综合研究结果表明,岩株的形成可能与上地幔岩浆分异有关,为高分异Ⅰ型花岗岩。     

湘南地区芙蓉锡矿床中硼矿化的发现及意义

硼矿是中国重要的紧缺矿产,长期依赖进口,找寻新的硼矿资源迫在眉睫.笔者在湘南地区芙蓉锡矿床新发现了矽卡岩型硼矿化,硼矿物包括硼镁铁矿、遂安石和氟硼镁石,1件典型样品的X射线粉晶衍射分析结果表明硼矿物总含量达到47.4％,换算成w(B)(以B2O3计)约为9.5％,高于5％的硼矿最低工业品位.该发现预示着湘南地区,乃至华南与高分异花岗岩有关的钨锡多金属矿集区有良好的硼成矿潜力,在今后的找矿过程中,需加强与钨锡多金属共伴生的硼矿化评价工作.     

西藏甲玛矿床南坑高分异Ⅰ型花岗斑岩及黑云母矿物学特征

高硅花岗岩对于理解浅部岩浆房的行为具有重要意义。本文对西藏甲玛矿区南坑矿段的花岗斑岩开展了岩相学、岩石地球化学及黑云母矿物学研究。结果显示,该花岗斑岩具有高SiO2(73.39%~77.99%)、高K2O(4.34%~6.45%)和低P2O5(0.03%~0.06%)特征,铝饱和指数为0.97~0.98,富集Rb、Th、U和Pb,明显亏损Ba、Nb、Ta、Sr、P、Ti和Eu等,属准铝质高分异I型花岗岩类;其中的黑云母具有高Al2O3(9.87%~10.92%)、高MgO(13.38%~14.64%)、高F(0.56%~1.11%)和高Cl(0.07%~0.12%)特征,Mg#为0.61~0.63,属镁质黑云母,黑云母源区为壳幔混合源。研究认为,该区花岗斑岩可能为甲玛矿区浅部埃达克质二长花岗斑岩的岩浆经矿物结晶分异演化出高硅残余熔体,并以岩脉形式上侵就位,而残留在岩浆房的物质结晶形成似斑状二长花岗岩,二者构成互补的关系,即主体为似斑状二长花岗岩,补体为高分异花岗斑岩。     

高表面活性矿物对Zn~(2+)的吸附机理及其环境意义

本文利用高表面活性矿物蒙脱石、蛭石、沸石在一定的介质条件下对Zn2 +进行吸附实验研究。蒙脱石和蛭石对Zn2 +的等温吸附线呈双“S”型 ,而沸石对Zn2 +的等温吸附线则呈“Langmuir”型。三种矿物对Zn2 +的吸附容量大小顺序为 :蒙脱石 >蛭石 >沸石。运用粉晶X射线衍射、红外光谱、差热及热重分析等技术对矿物及矿物吸附Zn2 +后的结构特征进行了研究。结果表明 ,蒙脱石吸附锌后其层间域中吸附锌大量水解形成新的物相 ,而蛭石与沸石吸附锌后水解很少。这为利用高表面活性矿物控制和治理环境污染及其可循环利用提供了理论依据。     

香港全风化花岗岩饱和直剪试验中的剪胀问题

通过对全风化花岗岩的慢剪试验,指出了在直剪试验中出现的两种垂直位移变化形式,其对土体的剪胀剪缩性质的 反映与三轴试验是一致的。剪胀的发生与土体的密实程度密切相关;随垂直压力的增大,剪胀发生所需剪应力也增大;剪应 力达到峰值所需要剪位移总是比剪胀发生时所需的剪位移大。     

KN系列难降解有机废水处理新药剂的研制及应用

KN系列污水处理剂对不同污水采用多孔、层状非金属矿经活化复配而成，不仅对难降解有机废水具有良好的处理效果，也可用于易生物降解废水，并且价格低，相关工艺具有占地少、投资省、运转费用低的特点。所产生的污泥脱水性能好，并可无害化最终处理，不产生二次污染。     

Evolution mechanism of the western Pacific subtropical high

Ever since Charney et al.[1] studied the multiple equilibrium states in atmosphere with highly truncated spectral method in 1979, many Chinese researchers, such as Li Maicun et al. (1983)[2], Liu Chongjian et al. (1983)[3], Miu Jinhai et al. (1985)[4] and…