贵州夜郎湖表层水体地球化学昼夜变化及其影响因素

为探究岩溶水库水文地球化学行为过程,对贵州普定夜郎湖表层水体进行了为期3 d的高分辨率昼夜监测。结果表明：1）多变的天气和水文条件叠加导致水体离子指标昼夜变化不显著,规律性较差。而水温、DO、pH值、SpC、SIc、pCO₂等常规理化指标受水温变化和生物作用表现出明显的昼夜波动。2）利用亨利常数和主成分分析,得到温度变化、生物作用、人类活动、水库的蓄水与放水对夜郎湖水库水文地球化学特征变化的贡献率分别为21.66%、17.28%、14.08%和10.22%,说明作用于水库水文地球化学行为的因子具有多元性。3）δ ¹⁸O表现出与DO一致的波动趋势,即白天上升,晚上下降,反映在短时间尺度上,氢氧稳定同位素变化受控于生物过程（主要是呼吸作用过程）;而对比水库水体和大气降水的d-excess（d值）发现,水库水体的d值（8.21‰）显著偏低于当地大气降水的d值（9.64‰）,说明在长时间尺度上,主要受蒸发效应引起的不平衡分馏影响。     

红阳煤田石炭-二叠纪含煤地层的沉积特征

红阳煤田含煤地层太原组与山西组,是一套典型的“海陆交互相”沉积。依据剖面上沉积相序列变化特点,可划分为14个沉积旋回,每个沉积旋回均含有一层煤。有二种聚煤环境:一是海水退出潮坪后形成的泥炭沼泽聚积的煤层;二是扇三角洲平原形成的泥炭沼泽聚积的煤层。     

DISASTER ANALYSIS AND COUNTERMEASURES OF LAND SUBSIDENCE CAUSED BY COAL CUTTING IN CHINA

In recent years, many coal-producing countries have paid great attention to the land subsidence causedby coal cutting. In China, because of the dense population in coalfield areas, the land subsidence hazard is more seri-ous. After a brief analysis on the mechanism of land subsidence, this paper gives a comprehensive and systematical ac-count on all kinds of hazards caused by the land subsidence in China. The study shows that land subsidence has endan-gered land, buildings, traffic and communication lines, dykes and dams. It also causes damage to ecological and socialenvironment. In order to lessen the hazard of land subsidence, preventive measures should be taken to reduce the col-lapse amount, such as extraction with stowing, banded mining system, succession and coordination mining system, orhigh-pressure mudflow between rock strata. Measures of reinforcing or moving certain buildings should also be taken toreduce the destructive degree. In order to harness the subsidence land and bring them under control for fanning, mea-sures should be taken such as filling with spoil or fine breeze, excavating the deeper and covering the shallower land.     

Ab initio infra-red spectra of iron-polycyclic aromatic hydrocarbon compounds: a model case

C₁₀H₆-Fe⁺ complexes were observed by Fourier transform mass spectrometry by Marty et al. (Chem. Phys. Lett. 256 (1996) 669). In this article, we present the infra-red (IR) spectra of the two isomers calculated by ab initio methods of quantum chemistry. In the past, the same approach has predicted successfully unexpected features of the IR spectra of polycyclic aromatic hydrocarbon (PAH) cations which were confirmed by measurements in matrices (J. Phys. Chem. 98 (1994) 9187). The C₁₀H₆-Fe⁺ systems are models for larger PAHs-Fe⁺ complexes, which are believed to play a key rôle in space chemistry.     

Study on numerical simulation to water lowering in an open coal mine digging

In view of the situation of excavation of open coal mine for the underground water disaster,we should carry out simulation studies for the numerical value of the water lowering project and improve the accuracy and the level of the water lowering project.On the basis of the hydrological geological conditions of certain open mine digging,a more reasonable seepage numerical model was built according to MODFLOW.It was simulated in advance that the process of the confined water level descending with the time,and combining with the actual observations to test the correctness of the model.The calculation showed that the results coincided well with the results of actual measurement.Based on this,different water lowering numerical simulations were built for the open coal mine digging.It could be simulated and forecast that the changes of the groundwater level in drainage process within and outside the mine pit,and it was quantitatively assessed that the possible water lowering result of the opencast water drainage process,which provide an important basis for the actual water lowering project and the possible project disposal.     

Late Cretaceous-Paleogene Palynostratigraphy from the Arkhara-Boguchan Brown Coal Mine of Zeya-Bureya Depression, Russia

1IntroductionThe Arkhara-Boguchan brown coal mine is lo-cated in the western Arkhara depression,southeast-ern part of the Zea-Bureya Basin (Fig.1). Late Creta-ceous-Paleogene coal-bearing strata are well out-cropped at the Arkhara-Boguchan quarry. It contains four coal-bearing beds (in descending order): “Ve-likan”, “Promezhutochny”,“Dvoinoy”and “Nyzhny”, and composed of three sedimentary cycles (Fig.2). The lower cycle can be divided into two sub-cycles:the lowest sub-cycle is …     

Anhydrite pseudomorphs and the origin of stratiform Cu–Co ores in the Katangan Copperbelt (Democratic Republic of Congo)

The stratiform Cu–Co ore mineralisation in the Katangan Copperbelt consists of dispersed sulphides and sulphides in nodules and lenses, which are often pseudomorphs after evaporites. Two types of pseudomorphs can be distinguished in the nodules and lenses. In type 1 examples, dolomite precipitated first and was subsequently replaced by Cu–Co sulphides and authigenic quartz, whereas in type 2 examples, authigenic quartz and Cu–Co sulphides precipitated prior to dolomite and are coarse-grained. The sulphur isotopic composition of the copper–cobalt sulphides in the type 1 pseudomorphs is between −10.3 and 3.1‰ relative to the Vienna Canyon Diablo Troilite, indicating that the sulphide component was derived from bacterial sulphate reduction (BSR). The generation of during this process caused the precipitation and replacement of anhydrite by dolomite. A second product of BSR is the generation of H₂S, resulting in the precipitation of Cu–Co sulphides from the mineralising fluids. Initial sulphide precipitation occurred along the rim of the pseudomorphs and continued towards the core. Precipitation of authigenic quartz was most likely induced by a pH decrease during sulphide precipitation. Fluid inclusion data from quartz indicate the presence of a high-salinity (8–18 eq. wt.% NaCl) fluid, possibly derived from evaporated seawater which migrated through the deep subsurface. ⁸⁷Sr/⁸⁶Sr ratios of dolomite in type 1 nodules range between 0.71012 and 0.73576, significantly more radiogenic than the strontium isotopic composition of Neoproterozoic marine carbonates (⁸⁷Sr/⁸⁶Sr = 0.7056–0.7087). This suggests intense interaction with siliciclastic sedimentary rocks and/or the granitic basement. The low carbon isotopic composition of the dolomite in the pseudomorphs (−7.02 and −9.93‰ relative to the Vienna Pee Dee Belemnite, V-PDB) compared to the host rock dolomite (−4.90 and +1.31‰ V-PDB) resulted from the oxidation of organic matter during BSR.     

鱼卡煤田大煤沟组高分辨率层序地层特征及聚煤规律

利用高分辨率层序地层学理论和技术方法,综合地震、测井、岩芯和煤质资料对柴达木盆地北缘鱼卡煤田中下侏罗统大煤沟组地层河湖三角洲沉积体系进行高分辨率层序地层学分析,从中识别出短期、中期、长期3个级别的基准面旋回层序,划分出向上"变深"非对称型、向上"变浅"非对称型及对称型3种短期基准面旋回基本结构类型。依据等时地层对比法则进行不同级次基准面旋回层序的联井对比,建立了大煤沟组的等时地层格架,在等时地层格架内进行了煤层对比,并在等时地层格架内分析了聚煤规律。     

华北地台东部石炭系—二叠系优质煤储层形成分布控制因素

优质煤储层在此指厚度大、分布广、储集物性好的煤层。沉积相对优质煤储层的形成和分布有重要控制作用。通过浅海和泻湖淤积填平发育起来的潮坪环境和三角洲环境是最有利的优质煤储层形成环境,煤储层厚度大、分布广。沉积环境对煤储层中的灰分含量和镜质组含量有重要影响,而灰分含量和镜质组含量又直接影响煤储层的储集物性。灰分充填了煤储层中的孔隙,其含量越高,储集物性越差;镜质组有利于割理的形成,其含量越高,储集物性越好。由于在灰分含量、煤岩显微组分等方面的差异,潮坪环境沉积的煤储层的储集物性优于三角洲的煤储层,下三角洲平原沉积的煤储层优于上三角洲平原沉积的煤储层。海平面变化对优质煤储层的形成和分布也有重要控制作用。高位体系煤储层富集,单层厚度大,横向分布相当稳定,尤其是高位体系域晚期,是形成优质煤储层最有利的层位。而水进体系域煤储层稀少,单层厚度小,横向分布不稳定,不利于优质煤储层形成。     

鄂尔多斯盆地东缘煤储层微孔隙结构特征及其影响因素

在对鄂尔多斯盆地东缘58套采自不同层位不同地域煤样显微组分测试和低温液氮比表面测试的基础上,从比表面积、吸附曲线形态、阶段孔径结构分布、阶段孔径比表面积贡献、FHH分形特征几个方面刻画了煤储层微孔隙特征。同时,就“孔比表面积—孔隙结构—煤物质组成与化学结构”这一因果链,分析了鄂尔多斯盆地东缘煤微孔隙特征与煤变质程度、煤岩显微组分以及矿物组分与类型的关系。研究发现,Ro在0.60%~1.91%范围内,比表面积及FHH分形分维数先明显降低,Ro至1.3%后又略有回升,同时吸附回线“滞后环”及分形尺度对应的压力范围明显减小,孔径3~4 nm“墨水瓶”型孔明显减少乃至消失,并成为比表面积减少的主要贡献者。在相似煤级条件下,惰质组分较镜质组分有更多的比表面积贡献。粘土矿物组分含量>10%时,孔径3~4 nm“墨水瓶”型孔对比表面贡献明显,且随煤级增高影响作用相对加大。