Radiocarbon redating of contaminated samples from a tropical volcano: the Mansion ‘Series’ of St Kitts,West Indies

Heavy rainfall and dense vegetation on tropical volcanoes produce abundant carbonized wood in pyroclastic deposits, in addition to easy contamination of this wood by root systems and soluble humic material. Because the physical nature of the charcoal varies, some samples are more prone to contamination. Two independent studies of the same volcano, Mt Liamuiga on St Kitts in the Lesser Antilles, sometimes using samples from the same carbonized tree, yielded a systematic difference in radiocarbon ages. An exchange of samples and a re-investigation of three physically distinct types of charcoal yielded the following results. Rare, hard, dense charcoal, lacking contamination, which had yielded a spurious age of 2860 years bp, was redated at 1845±58 years bp. Common soft, friable charcoal with good cellular structure proved to be susceptible to contamination. A field decontamination technique utilized by one group seems significant as it yields older ages than when only routine laboratory pre-treatment was used, indicating that the latter technique only partly removes the dried and hard residue produced by the decomposition of modern plant rootlets. A previous date of 24870 years bp obtained from powdery charcoal in a horizon beneath the Mansion Series contradicted ages older than 41000 years bp from common friable charcoal in the lower Mansion Series. The soft powdery charcoal was re-investigated using a sample collected a few centimeters from the original, although field decontamination of this sample was not possible, more extensive laboratory treatment yielded an age of ca. 43000 years bp, again proving that routine laboratory pretreatments are inadequate. A revised geochronology for the Mansion Series is described and a cautionary discussion is presented for the benefit of investigators using radiocarbon ages to date volcanic deposits.     

古炭屑与古森林火?

森林火普遍发生在地质历史时期中，它对自然植被系统的演替起着重要作用。不同强度和频率的森林火培育出不同类型的植被：频繁的森林火导致草甸的形成，而热带雨林形成的原因之一是森林火的缺乏。古炭屑作为古森林火的遗迹，具有分布广泛、细胞结构保存完好以及原地埋藏等特点，为研究古森林火发生的强度和频率提供了宝贵的材料。古炭屑的出现与当时的气候因素、植被类型和地理状况有密切关系：干旱、少雨的气候常常伴随高频率森林火的发生，表现出古炭屑的数量增多；易燃物种组成的植被易发生森林火，古炭屑的出现也会增多，而耐火树种会降低森林火的强度，古炭屑则出现少。因此，从古炭屑的数量和种类的变化，可探讨古森林火的发生规律，进而推断长期地质历史时期的气候、植被、地理状况的演变。     

活性炭柱分离－亚硫酸钠解吸萃取比色法测定痕量金

本文叙述了用活性炭色层柱分离、亚硫酸钠解吸、TMK-异戊醇萃取比色测定痕量金的方法。采用了以硫酸钴、铬酸钾和硫酸铜等无机盐配制模拟标准系列,可以长期使用。本法操作简单,快速,成本低,工效高。一人一天可以分析30个以上试样,能测定出1×10~(-3)ppm的金含量,适用于地质普查金矿中大批试样的分析。     

Emission spectrographic estimation of gold

A procedure for estimating minute quantities (parts per billion) of gold is described, based on dissolution of the sample in aqua regia, adsorption on activated charcoal, arcing of the charcoal ash, and measurement of the intensity of the emitted spectra.     

现代植物炭屑形态的初步分析及其古环境意义*

通过对23种现代植物炭屑的观察、测量以及对草本、木本炭屑模拟破碎试验后的测量统计发现:现代植物炭屑形态根据其长宽比(L/W)和形态特征可以分为3个类型:1)草本型炭屑,L/W最大,平均为10.2±1.3, 呈长-薄条型、针型、簇纤维型,边缘及断口截然,棱角分明,有些具有气孔构造,很少有不规则的形态出现; 2)木本型炭屑(灌木+乔木),L/W较小,平均3.1±0.2,多呈方~长方型或立方体型,边缘多参差不齐,有些横向断口有粗大木纤维露出,相对致密; 3)阔叶类植物叶片炭屑,L/W最小,平均1.7±0.1,薄片状、网状,絮状,易碎。进一步通过对6个典型草原和森林表土样品的实验室分析,发现现代土壤中的炭屑颗粒大小相对现代植物炭屑颗粒大小总体有所减小,但草原土壤中炭屑长宽比相对森林土壤炭屑仍然较大,土壤中炭屑形态和部分结构鉴别特征仍能保留。表明L/W值与炭屑结构特征可以用来区分多数草本与木本植物炭屑。在此基础上,通过对黄土高原渭南剖面S₁以来不同层位12个地层样品的炭屑形态分析,初步研究了不同草本、木本植物炭屑形态变化的特点和环境意义。     

High-resolution paleoecological analysis of recent disturbance in a southern Chilean Nothofagus forest

A 1600 year paleoecological record of environmental change is developed from a small lake in the Nothofagus forest of southern Chile (45.5°S, 72°W). High resolution fossil pollen, charcoal, sedimentological, and chrysophycean stomatocyst analyses are used to investigate the impacts of natural and anthropogenic disturbances on terrestrial and lacustrine environments. Chronological control is based on a combination of ²¹⁰Pb and ¹⁴C dating. Temporal resolution during the past 150–200 yr is ca. 8 yr/sample. The macroscopic charcoal record correlates very closely with historical and dendroecological records of 20th century anthropogenic burning in this region. The chrysophyte stratigraphy indicates that this burning had immediate impacts on the lake itself, while the pollen record provides evidence for a succession of vegetation changes lagging slightly behind the disturbance. These palynological changes are very similar to the pollen signal of European disturbance in northeastern North America. Pre-European shifts in chrysophyte assemblages may be due to the influence of earthquake activity on the lake, though there is no corroborative evidence in the pollen or charcoal records. This study demonstrates that high resolution paleoecological methods can be used to help bridge the temporal gap between traditional ecological and paleoecological studies of environmental change in the temperate forests of southern South America.     

甘肃河西走廊早期冶炼活动及影响的炭屑化石记录

炭屑化石的显微结构研究是根据木材的解剖特征（组成木材的细胞与组织的形态和排列方式）确定燃烧植物的类型,重建古植被和古环境,探讨人类活动对环境的影响。火石梁和缸缸洼青铜冶炼点位于河西走廊西北部、黑河流域下游巴丹吉林南缘沙地中,散布了大量的炭屑化石遗存。通过炭屑化石3个切面（横切面、径切面和弦切面）显微结构特征研究,比对现代切片标本和木材解剖图版,识别和确定炭屑化石的木材种属,确定 2100～1860BC期间的青铜冶炼所用木材为柽柳、杨属、柳属、蓼科4种乔灌木植物,火石梁和缸缸洼地区大量乔、灌群落生长要比目前荒漠生态环境优越的多。先民的青铜冶炼活动导致乔木和灌木植物被大量砍伐,植被盖度急剧降低,对生态环境产生重大影响,是1900BC左右杨属、柳属和蓼科乔灌木植物基本消失的主要原因。     

A late Holocene paleoenvironmental reconstruction from Agua Caliente,southern Belize,linked to regional climate variability and cultural change at the Maya polity of Uxbenká

We report high-resolution macroscopic charcoal, pollen and sedimentological data for Agua Caliente, a freshwater lagoon located in southern Belize, and infer a late Holocene record of human land-use/climate interactions for the nearby prehistoric Maya center of Uxbenká. Land-use activities spanning the initial clearance of forests for agriculture through the drought-linked Maya collapse and continuing into the historic recolonization of the region are all reflected in the record. Human land alteration in association with swidden agriculture is evident early in the record during the Middle Preclassic starting ca. 2600 cal yr BP. Fire slowly tapered off during the Late and Terminal Classic, consistent with the gradual political demise and depopulation of the Uxbenká polity sometime between ca. 1150 and 950 cal yr BP, during a period of multiple droughts evident in a nearby speleothem record. Fire activity was at its lowest during the Maya Postclassic ca. 950–430 cal yr BP, but rose consistent with increasing recolonization of the region between ca. 430 cal yr BP and present. These data suggest that this environmental record provides both a proxy for 2800 years of cultural change, including colonization, growth, decline, and reorganization of regional populations, and an independent confirmation of recent paleoclimate reconstructions from the same region.     

青藏高原东北缘武山盆地中中新世炭屑记录及其古气候意义

火是生态系统中的重要因子,是反映古气候和环境变化的重要标志。因此,重建火活动历史可以帮助我们理解过去的气候变化和火活动的机制,但是目前在全球范围内十分缺少对中新世时期高分辨率的火活动记录的研究。炭屑已被证明是重建火活动历史的有效替代性指标,基于青藏高原东北缘武山盆地中中新世时期高分辨率的炭屑记录,重建了研究区天然火活动历史,结合现有资料,探讨了火-植被-气候之间的关系以及研究区火活动对全球变化的响应。结果表明：（1） 15.30~13.60 Ma时期,炭屑总浓度变化范围为59~4324粒·g^-1,平均浓度为835粒·g^-1。炭屑形状以次圆形为主,且几乎所有的炭屑粒径都小于50 μm,反映出研究区天然火活动是以乔木植物燃烧的森林火活动为主,主要是区域性火活动。根据炭屑总浓度的变化趋势,将研究区天然火活动历史分为2个主要阶段。阶段Ⅰ（15.30~14.00 Ma）：炭屑总浓度逐步增加,平均浓度为866粒·g^-1。其中,阶段Ⅰ又可以细分为3个次要阶段,Ⅰa（15.30~14.38 Ma）：炭屑总浓度最低,平均浓度为693粒·g^-1;Ⅰb（14.38~14.20 Ma）：炭屑总浓度快速减少,平均浓度为1140粒·g^-1;Ⅰc（14.20~14.00 Ma）：炭屑总浓度急剧增加,平均浓度为988粒·g^-1。阶段Ⅱ（14.00~13.60 Ma）：炭屑总浓度急剧减少,平均浓度为777粒·g^-1。（2） 孢粉数据重建的研究区的植被和气候变化结果表明,15.30~14.38 Ma时期为开阔的森林植被,湿度较低;14.38~14.00 Ma时期乔木增加,湿度增加;14.00~13.60 Ma时期乔木属种显著减少,湿度降低。（3） 经过对比分析,炭屑总浓度变化趋势与乔木类花粉百分比趋势相近,次圆形炭屑浓度趋势与阔叶类植物花粉的百分比趋势显著正相关,认为武山盆地中中新世的天然火活动与森林植被的盖度（尤其是阔叶林的盖度）有较强联系,在气候温暖湿润的时期,炭屑浓度高。此外,通过对比炭屑总浓度趋势和深海底栖有孔虫氧同位素的变化,可以推测,全球温度变化可能通过影响研究区植被变化来对天然火活动产生重要影响。     

A record of Lateglacial/Holocene environmental change from a high‐elevation site in the Intermountain West,USA

Records of past vegetation and fire history can be complicated by changes in the depositional environment of a sampling location. However, these changes can alternatively be used as a measure of climate variability. Our study site, ca. 18.0 cal. ka BP record from Little Brooklyn Lake, Wyoming, located near the crest of the Snowy Range, records three moisture states. Initially, the lake was likely a glacier‐fed pond indicated by the presence of Pediastrum algae colonies. Around 13.0 cal. ka BP this pond transitioned to a meadow environment, suggested by the loss of Pediastrum algae colonies and slow sedimentation rates. Meadow conditions were maintained until ca. 5.0 cal. ka BP when Pediastrum algae colony abundance increased,indicating the formation of a shallow lake. From 18.0 to ca. 5.0 cal. ka BP, the pollen record is suggestive of alpine vegetation conditions with relatively high spruce and herbaceous taxa. Low charcoal influx also characterizes the period between 18.0 and 5.0 cal. ka BP. After 5.0 cal. ka BP, the coincidence of the formation of shallow lake and pollen data, indicating a shift to a spruce and fir forest, suggests an increase in effective moisture. Fire remained rare in this basin over the entire record, however, once the lake established sedimentation rates and charcoal influx increased. Copyright © 2013 John Wiley & Sons, Ltd.