SO4^2-改性铁铝复合层柱粘土的制备及其催化性能研究

由共聚法制得的铁铝复合交联剂交换钠基蒙脱石层间的水合钠离子,再经SO42-改性处理制备了铁铝复合层柱粘土固体超强酸催化剂.利用xRD、FT-IR和BET法对催化剂的结构进行了表征.以乙酸正丁酯的合成反应为探针反应对催化剂的活性进行了测试.通过正交实验确定了铁铝复合交联粘土SO42-改性最佳工艺条件.研究了催化剂对探针反应的选择性及重复使用情况.结果表明:在由实验确定的最佳改性工艺条件下,乙酸的转化率达92.2%,反应中无副产物产生,催化剂具有较好的重复使用性能.     

关于角平分线法建立线状缓冲区算法的改进

分析了用对角平分线法建立缓冲区的算法,提出了一种新的求角平分线和缓冲点的方法,实践证明其在算法实现方面是可行的,而且效果比较理想。     

基于Kiwi数据格式的地图显示研究

在分析Kiwi显示数据存储组织方法的基础上,研究了Kiwi显示数据在内存中的动态组织,改进了地图显示的二级缓存方法,提出了地图显示的双缓冲池策略。试验结果表明,本文研究的数据动态组织方法和地图显示策略提高了地图显示速度。     

Agricultural land use in the coastal area of the Alexander von Humboldt National Park, Cuba and its implication for conservation and sustainability

In the Alexander von Humboldt National Park in eastern Cuba many endemic animals and plants are found in various different natural habitats, which are considered to be the most important ones for in-situ conservation in the entire Insular Caribbean. In some areas of the National Park agriculture is practised. Thus, the objective of this study was to document and analyse the different land use activities and their consequences for local resource management and conservation of biodiversity in two village areas. A particular question was: what has changed since the foundation of the National Park in 1996? As time series data for land use and aerial photographs were not available for this part of Cuba, a qualitative evaluation was carried out. For this, six different land use units were mapped in 2001 and additional information gathered for areas with special interest related to sustainable land use and resource conservation. Although most parts of the study area are influenced to various degrees by human impact, the different types of land use seem presently not to have a crucial or detrimental impact on the land resources of the Alexander von Humboldt National Park. However, exploitation of the natural resources in certain areas could be improved with different management options to reach sustainability as well as to meet the conservation objectives of the National Park. This includes reduced or abandoned agricultural use of steep slopes to reduce erosion risk as well as a facilitated regeneration of natural vegetation in many parts of the study area to be able to conserve the high valuable biodiversity of the Park. Environmental education seems to have played an important and successful role since the foundation of the Park in 1996. Since then, cropping on steep slopes as well as illegal logging and poaching could be reduced.     

醋酸丁酯萃取-无火焰原子吸收法测定化探样品中痕量金

在KBr存在下,用小体积醋酸丁酯萃取金后,用无火焰原子吸收法测定化探样品中痕量金的分析方法较化学富集光谱法具灵敏度高(检出下限可达0.05×10-9)、精度好、简便快速、成本低等优点.通过批量化探样的检验,证明该方法足已满足化探样品对金的测定要求.     

插层高岭石层间醋酸钾的作用和取向

利用X粉晶衍射和激光拉曼光谱实验分析高岭石及其醋酸钾插层物的结构。通过实验表明醋酸钾对结晶指数(HI)为0．9的高岭石进行插层．插层率为73％，使高岭石的d(001)由0．72075nm增加到1．42093nm。进入高岭石层间的醋酸根利用其羧基上的两个氧同时和高岭石的面内羟基形成氢键，在高岭石层间直立取向，而对其内羟基基本无影响。当温度升高时，与面内羟基伸缩振动有关的峰(3698cm^-1,3684cm^-1，3672cm^-1等)发生红移，且强度增加；而与内羟基伸缩振动有关的峰(3621cm^-1)则发生蓝移。温度升高到100C以上，开始发生去插层过程；直到250C，插层分子还不能完全从高岭石层间脱去。     

Do southern Appalachian Mountain summer stream temperatures respond to removal of understory rhododendron thickets?

Dense understory thickets of the native evergreen shrub Rhododendron maximum expanded initially following elimination of American chestnut by the chestnut blight, and later in response to loss of the eastern hemlock due to hemlock woolly adelgid invasion. Rhododendron thickets often blanket streams and their riparian zones, creating cool, low-light microclimates. To determine the effect of such understory thickets on summer stream temperatures, we removed riparian rhododendron understory on 300 m reaches of two southern Appalachian Mountain headwater streams, while leaving two 300 m reference reaches undisturbed. Overhead canopy was left intact in all four streams, but all streams were selected to have a significant component of dead or dying eastern hemlock in the overstory, creating time-varying canopy gaps throughout the reach. We continuously monitored temperatures upstream, within and downstream of treatment and reference reaches. Temperatures were monitored in all four streams in the summer before treatments were imposed (2014), and for two summers following treatment (2015, 2016). Temperatures varied significantly across and within streams prior to treatment and across years for the reference streams. After rhododendron removal, increases in summer stream temperatures were observed at some locations within the treatment reaches, but these increases did not persist downstream and varied by watershed, sensor, and year. Significant increases in daily maxima in treatment reaches ranged from 0.9 to 2.6°C. Overhead canopy provided enough shade to prevent rhododendron removal from increasing summer temperatures to levels deleterious to native cold-water fauna (average summer temperatures remained below 16°C), and local temperature effects were not persistent.     

Investigation on performance of all optical buffer with large dynamical delay time based on cascaded double loop optical buffers

Optical buffers are critical for optical signal processing in future optical packet-switched networks. In this paper, a theoretical study as well as an experimental demonstration on a new optical buffer with large dynamical delay time is carried out based on cascaded double loop optical buffers (DLOBs). It is found that pulse distortion can be restrained by a negative optical control mode when the optical packet is in the loop. Noise analysis indicates that it is feasible to realise a large variable delay range by cascaded DLOBs. These conclusions are validated by the experiment system with 4-stage cascaded DLOBs. Both the theoretical simulations and the experimental results indicate that a large delay range of 1--9999 times the basic delay unit and a fine granularity of 25 ns can be achieved by the cascaded DLOBs. The performance of the cascaded DLOBs is suitable for the all optical networks.     

面向WebGL的矢量数据三维绘制技术

矢量数据的叠加显示能够提高三维虚拟地球的表达效果与分析能力。受限于GPU的计算精度,在三维虚拟地球中矢量数据绘制普遍存在抖动现象和深度冲突现象。对基于WebGL的矢量数据三维绘制中计算精度问题进行了分析,提出了使用CPU RTC技术和GPU RTE技术提高顶点变换的精度,使用多视锥渲染算法和深度平面技术解决深度缓存精度问题。实验证明,这几种技术和算法可以有效缓解抖动现象和深度冲突现象导致的视觉干扰,改善了各种尺度和范围的矢量数据在三维地形上的叠加显示效果。