Mining of Cenozoic alluvial deposits at Copeton and Bingara (Eastern Australia) has produced two million macrodiamonds (0.25 ct median size). Raman spectroscopy is used to identify included minerals within uncut Copeton diamonds, with sealed chamber remnant pressures of 31.7 to 35.6 kbar for coesite, 13.6 and 22.7 kbar for clinopyroxene, and 7.6 kbar for grossular garnet. Assuming elastic behaviour, these values generate inclusion entrapment PT loci which intersect, restricting diamond formation conditions: from 250 °C, 43 kbar to 800 °C, 52 kbar. Larger than error (± 100 °C and ± 4 kbar), this range shows a systematic variation in inclusion composition with diamond zoning and N properties. Published research shows 1) Copeton and Bingara diamonds are unique, and 2) modern alluvium in the Bingara district carries mantle-formed garnet, captured by post-tectonic alkali basalt from an extensive diamondiferous ultrahigh pressure (UHP) terrane that stalled at depth because it is dominated by mafic eclogite. The combined Raman and geological results indicate two sets of subduction UHP diamond formation conditions/protolith are required, firstly cooler oceanic slab and secondly including higher temperature continental crust. The Copeton and Bingara stones are UHP macrodiamonds, and Carboniferous 40Ar/39Ar age dates on clinopyroxene inclusions should be interpreted as ages of crystallisation, representing the termination of subduction. The characteristic features of ruptured inclusions and etched percussion marks on Copeton and Bingara diamond indicate volcanic delivery to the earth's surface. Alluvial deposits elsewhere in Eastern Australia may carry similar diamond along with diamond of different origin. 相似文献
Effects of dynamic recrystallization on lattice preferred orientation (LPO) in olivine were investigated through the combination of two SEM-based techniques, electron backscattered diffraction (EBSD) technique for crystallographic orientation measurement and backscattered electron imaging (BEI) for dislocation observation. Samples are experimentally deformed olivine aggregates in simple shear geometry. In the sample deformed at T=1473 K and high stresses (480 MPa), only incipient dynamic recrystallization is observed along grain-boundaries. Orientations of these small recrystallized grains are more random than that of relict grains, suggesting an important role of grain-boundary sliding at this stage of recrystallization. In the sample deformed at T=1573 K and low stress (160 MPa), dynamic recrystallization is nearly complete and the LPO is characterized by two [100] peaks. One peak is located at the orientation subparallel to the shear direction and is dominated by grains with high Schmid factor. The other occurs at high angles to the shear direction and is due to the contribution from grains with low Schmid factor. Grains with high Schmid factor tend to have higher dislocation densities than those with low Schmid factor. Based on these observations, we identify two mechanisms by which dynamic recrystallization affects LPO: (1) enhancement of grain-boundary sliding due to grain-size reduction, leading to the modification of LPO caused by the relaxation of constraint for deformation; (2) grain-boundary migration by which grains with lower dislocation densities grow at the expense of grains with higher dislocation densities. Based on the deformation mechanism maps and stress versus recrystallized grain-size relation, we suggest that the first mechanism always plays an important role whereas the second mechanism has an important effect only under limited conditions. 相似文献
The pipe shapes, infill and emplacement processes of the Attawapiskat kimberlites, including Victor, contrast with most of the southern African kimberlite pipes. The Attawapiskat kimberlite pipes are formed by an overall two-stage process of (1) pipe excavation without the development of a diatreme (sensu stricto) and (2) subsequent pipe infilling. The Victor kimberlite comprises two adjacent but separate pipes, Victor South and Victor North. The pipes are infilled with two contrasting textural types of kimberlite: pyroclastic and hypabyssal-like kimberlite. Victor South and much of Victor North are composed of pyroclastic spinel carbonate kimberlites, the main features of which are similar: clast-supported, discrete macrocrystal and phenocrystal olivine grains, pyroclastic juvenile lapilli, mantle-derived xenocrysts and minor country rock xenoliths are set in serpentine and carbonate matrices. These partly bedded, juvenile lapilli-bearing olivine tuffs appear to have been formed by subaerial fire-fountaining airfall processes.
The Victor South pipe has a simple bowl-like shape that flares from just below the basal sandstone of the sediments that overlie the basement. The sandstone is a known aquifer, suggesting that the crater excavation process was possibly phreatomagmatic. In contrast, the pipe shape and internal geology of Victor North are more complex. The northwestern part of the pipe is dominated by dark competent rocks, which resemble fresh hypabyssal kimberlite, but have unusual textures and are closely associated with pyroclastic juvenile lapilli tuffs and country rock breccias±volcaniclastic kimberlite. Current evidence suggests that the hypabyssal-like kimberlite is, in fact, not intrusive and that the northwestern part of Victor North represents an early-formed crater infilled with contrasting extrusive kimberlites and associated breccias. The remaining, main part of Victor North consists of two macroscopically similar, but petrographically distinct, pyroclastic kimberlites that have contrasting macrodiamond sample grades. The juvenile lapilli of each pyroclastic kimberlite can be distinguished only microscopically. The nature and relative modal proportion of primary olivine phenocrysts in the juvenile lapilli are different, indicating that they derive from different magma pulses, or phases of kimberlite, and thus represent separate eruptions. The initial excavation of a crater cross-cutting the earlier northwestern crater was followed by emplacement of phase (i), a low-grade olivine phenocryst-rich pyroclastic kimberlite, and the subsequent eruption of phase (ii), a high-grade olivine phenocryst-poor pyroclastic kimberlite, as two separate vents nested within the original phase (i) crater. The second eruption was accompanied by the formation of an intermediate mixed zone with moderate grade. Thus, the final pyroclastic pipe infill of the main part of the Victor North pipe appears to consist of at least three geological/macrodiamond grade zones.
In conclusion, the Victor kimberlite was formed by several eruptive events resulting in adjacent and cross-cutting craters that were infilled with either pyroclastic kimberlite or hypabyssal-like kimberlite, which is now interpreted to be of probable extrusive origin. Within the pyroclastic kimberlites of Victor North, there are two nested vents, a feature seldom documented in kimberlites elsewhere. This study highlights the meaningful role of kimberlite petrography in the evaluation of diamond deposits and provides further insight into kimberlite emplacement and volcanism. 相似文献
Shear deformation of hot pressed plagioclase–olivine aggregates was studied in the presence and absence of mineral reaction. Experiments were performed at 900 °C, 1500 MPa, and a constant shear strain rate of 5×10−5 s−1 in a solid medium apparatus. Whether the mineral reaction between plagioclase and olivine takes place or not is controlled by choosing the appropriate plagioclase composition; labradorite (An60) does not react, anorthite (An92) does. Labradorite–olivine aggregates deformed without reaction are very strong and show strain hardening throughout the experiment. Syndeformational reaction between olivine and anorthite causes a pronounced strain weakening. The reaction produces fine-grained opx–cpx–spinel aggregates, which accommodate a large fraction of the finite strain. Deformation and reaction are localised within a 0.5-mm-wide sample. Three representative samples were analysed for their fabric anisotropy R* and shape-preferred orientation α* (fabric angle with the shear plane) using the autocorrelation function (ACF). Fabric anisotropy can be calibrated to quantify strain variations across the sheared samples. In the deformed and reacted anorthite–olivine aggregate, there is a strong correlation between reaction progress and strain; regions of large shear strain correspond to regions of maximum reaction progress. Within the sample, the derived strain rate variations range up to almost one order of magnitude. 相似文献
At sufficiently high temperatures and/or long periods, the elastic behaviour of crystalline material gives way progressively to viscoelastic behaviour associated with the stress-induced migration of crystal defects. This transition is marked by the onset of appreciable strain energy dissipation accompanied by frequency dependence (dispersion) of the shear modulus and elastic wave speeds. Ultrasonic interferometry and torsional forced-oscillation techniques can be used to probe the low-amplitude stress-strain behaviour of fine-grained polycrystalline material in two very different frequency ranges, respectively 10-100 MHz and 1 mHz-1 Hz. Here we demonstrate and apply these two complementary methods in a study of the high-temperature mechanical behaviour of a fine-grained synthetic olivine polycrystal. At the high frequencies of ultrasonic interferometry, the shear wave speed varies linearly with temperature between room temperature and the highest experimentally accessible temperature (1300 °C) in close accord with expectations based on similarly high-frequency studies of the elastic behaviour of single-crystal olivine. However, at teleseismic frequencies (<1 Hz) and temperatures >900 °C, the shear wave speed becomes much more strongly temperature-sensitive reflecting markedly viscoelastic behaviour. Newly emerging laboratory-derived constraints on this viscoelastic enhancement of the temperature sensitivity of seismic wave speeds and its grain-size dependence will provide a more robust interpretation of seismological models for the variation of wave speeds and attenuation within the Earth's interior. 相似文献
The origin of compositional heterogeneities among the magmas parental to mid-ocean ridge basalts (MORB) was investigated using
a single rock piece of the olivine-phyric basalt from 43°N, Mid-Atlantic Ridge (AII D11-177). The exceptional feature of this
sample is presence of very primitive olivine crystals (90–91 mol% Fo) that are significantly variable in terms of CaO (0.15–0.35 wt%).
A population of low-Ca olivine (0.15–0.25 wt% CaO) is also notably distinct from high-Ca olivine population in AII D11-177,
and primitive MORB olivine in general, in having unusual assemblage of trapped mineral and glass inclusions. Mineral inclusions
are represented by high-magnesian (Mg# 90.7–91.1 mol%) orthopyroxene and Cr-spinel, distinctly enriched in TiO2 (up to 5 wt%, c.f. <1 wt% in common MORB spinel). Glass inclusions associated with orthopyroxene and high-Ti Cr-spinel have
andesitic compositions (53–58 wt% SiO2). Compared to the pillow-rim glass and “normal” MORB inclusions, the Si-rich glass inclusions in low-Ca olivine have strongly
reduced Ca and elevated concentrations of Ti, Na, K, P, Cl, and highly incompatible trace elements. Strong variability is
recorded among glass inclusions within a single olivine phenocrysts. We argue that the observed compositional anomalies are
mineralogically controlled, and thus may arise from the interaction between hot MORB magmas and crystal cumulates in the oceanic
crust or magma chamber. 相似文献