塔中石炭系碎屑岩深埋藏优质储层成因探讨

塔中地区石炭系碎屑岩为一套次生－原生孔隙型深埋藏优质储层。储集岩为中细粒－细粒石英砂岩，储层形成于古地温梯度低、沉积物浅埋时间长、深埋时间短、孔隙水矿化度高及较早被油气占居的条件下，致使原生孔隙保存较好。同时，塔中地区石炭系目前刚进入８０℃－１２０℃的强溶成岩阶段，次生孔隙正在发育，距离碳酸盐岩沉淀带和后期石英次生加大带尚有较大深度，因而储层的孔渗性维持在最佳状态。     

黄土微结构图像处理的方法

本介绍了对黄土微结构电镜图像进行图像处理的常用方法。这些方法可以去除图像噪声，提高图像的对比度，使得图像便于进行人工解译或借助软件的图像分析。     

Shale Gas Formation and Occurrence in China: An Overview of the Current Status and Future Potential

Shale gas is one of the most promising unconventional resources both in China and abroad. It is known as a form of self-contained source-reservoir system with large and continuous dimensions. Through years of considerable exploration efforts, China has identified three large shale gas fields in the Fuling, Changning and Weiyuan areas of the Sichuan Basin, and has announced more than 540 billion m~3 of proven shale gas reserves in marine shale systems. The geological theories for shale gas development have progressed rapidly in China as well. For example, the new depositional patterns have been introduced for deciphering the paleogeography and sedimentary systems of the Wufeng shale and Longmaxi shale in the Sichuan Basin. The shale gas storage mechanism has been widely accepted as differing from conventional natural gas in that it is adsorbed on organic matter or a mineral surface or occurs as free gas trapped in pores and fractures of the shale. Significant advances in the techniques of microstructural characterization have provided new insights on how gas molecules are stored in micro- and nano-scale porous shales. Furthermore, newly-developed concepts and practices in the petroleum industry, such as hydraulic fracturing, microseismic monitoring and multiwell horizontal drilling, have made the production of this unevenly distributed but promising unconventional natural gas a reality. China has 10–36 trillion m~3 of promising shale gas among the world's whole predicted technically recoverable reserves of 206.6 trillion m~3. China is on the way to achieving its goal of an annual yield of 30–50 billion m~3 by launching more trials within shale gas projects.     

Evaluation of ostracod-based palaeoenvironmental reconstruction with instrumental data from the arid Faiyum Depression,Egypt

The utility of ostracod-based palaeoenvironmental reconstruction was evaluated using instrumental data for Lake Qarun, Egypt. The euryhaline ostracod Cyprideis torosa was the only species found in the lake’s recent sediment record. This species is known to tolerate salinity levels and water solute compositions that may prevent colonisation by other species. Oxygen and carbon isotope ratios of ostracod carbonate from lake sediments covary with changes in instrumental values for lake level and salinity for the period 1890–1974. δ¹³C-values correlate negatively with lake water salinity (r ² = 0.87) and δ¹⁸O-values correlate negatively with measured lake level changes (r ² = 0.41). Other ostracod proxy data provide qualitative information on lake level trends. Fossil assemblage data (juvenile/adult and valve/carapace ratios and valve preservation) provide information on wave energy. Ecophenotypic variation of C. torosa valves provided some useful palaeolimnological information. Sr/Ca and Mg/Ca ratios in ostracods were not found to reflect water composition, due to the uncoupling of these ratios with salinity in Lake Qarun. Overall, our results highlight the need to calibrate ostracod proxy data in modern systems prior to their use for palaeoenvironmental reconstruction.     

东营凹陷下第三系深部碎屑岩储层次生孔隙垂向分布及成因分析

东营凹陷下第三系埋深大于 30 0 0 m的深部碎屑岩储层普遍发育 2～ 4个次生孔隙带 ,Φ=10 %～ 30 % ,K=0 .1× 10 - 3μm2～ 30× 10 - 3μm2 ,为中孔低渗低孔低渗油气储层。综合有机质热演化过程、成岩作用和构造断裂等分析 ,认为东营凹陷埋深大于 30 0 0m碎屑岩地层中 ,第一、二个次生孔隙带埋深在 30 0 0 m～ 390 0 m之间 ,其形成主要与有机质成熟过程释放有机酸对长石等颗粒的溶解有密切关系 ,在深大断裂附近储层同时受到大气淡水的影响 ,而深陷带包裹于暗色泥岩中的浊积砂岩的次生孔隙发育情况还与泥质岩异常压力带有关 ;第三个次生孔隙带埋深一般为 390 0 m～ 430 0 m,主要成因于粘土矿物转化造成的还原环境 ,同时受到硫酸盐热化学氧化还原反应的影响。这三个次生孔隙发育带对储集油气有效。第四个孔隙发育带埋深在 470 0 m以下 ,主要是构造成因的微裂缝 ,较难成为有效的油气储层。     

准噶尔盆地玛湖凹陷风城组页岩自生长英质矿物的成因机理及其储层改造意义

玛湖凹陷二叠系风城组是近几年准噶尔盆地页岩油接替的主攻领域,但其页岩成岩改造强烈,原始岩性归属尚不明确。X射线粉晶衍射测得风城组页岩黏土矿物含量普遍较低（<10%）,长英质矿物含量较高（60%~80%）。薄片分析发现风城组长英质页岩存在三种类型：① 粉砂级（4~63 μm）长石和石英碎屑含量丰富,为典型的粉砂岩;② 燧石条带和团块发育,为富硅页岩;③ 长英质基质发育,呈非碎屑状,且火山尘及火山玻璃少见,其矿物组成和形态与典型的黏土岩、粉砂岩及沉凝灰岩明显不同。背散射图像和高精度扫描电镜测得该长英质基质由碎屑和自生石英、钾长石和钠长石共同组成,可见黏土矿物、碎屑钾长石和钠长石向自生石英转化,碎屑钾长石向自生钠长石转化。通过调研全球中新生代碱湖沉积中自生硅酸盐矿物组合特征和成岩演化规律,探讨了二叠系风城组“贫”黏土矿物和“富”自生长英质矿物的原因,并提出风城组发育一类“改造长英质页岩”,主要由原始黏土和长石碎屑矿物和火山物质经过多期成岩改造而成。早期高碱（pH>9）沉积和成岩环境增加了SiO2溶解度和元素铝的活性,导致黏土矿物、泥级—细粉砂级长英质碎屑、火山灰等在入湖后发生“溶解、转化”,形成次稳定的硅酸盐矿物,如沸石和含镁蒙皂石,在经历漫长埋藏成岩后进一步转化为更为稳定的石英、钾长石和钠长石。碱湖页岩的成岩改造过程消耗了黏土矿物和火山灰,极大增加了页岩脆性,同时伴生了大量基质溶孔和晶间孔,是一类优质的页岩储层。     

四川盆地东部下古生界页岩储集空间特征及其对含气性的影响

四川盆地东部下古生界海相页岩是一套有利的页岩气储层,通过野外泥页岩剖面及井下岩芯观察、电镜扫描、常规物性及微孔隙结构测试、等温吸附实验等技术方法,对页岩气储层空间特征进行了研究分析,发现下古生界页岩的孔隙可分为三大类六小类,裂缝可分为两大类五小类,具有颗粒细小、致密、大孔发育少、微孔发育多、具有一定孔隙度、渗透率小、喉道细、连通性差的特征。页岩总孔体积主体是由孔径小于200nm的微孔隙提供的,纳米级孔隙和微裂缝是页岩主要的储集空间,页岩有机质孔对于孔隙度具有一定贡献,是富有机质页岩的主要微孔隙类型。页岩的微孔隙结构决定了页岩气的赋存状态和流动方式,孔缝发育程度在一定程度上决定了页岩的含气性及其渗透性能,但大型或巨型裂缝的发育,将给页岩气的有效保存带来破坏。有机质(干酪根和沥青质)和黏土颗粒内的微孔隙表面是吸附态页岩气赋存的主要空间,但有机质孔提供了大部分具吸附性的孔比表面,是控制页岩吸附性能的主要因素,而黏土矿物的作用是次要的。     

The Role of Seal and Source Rocks in Fluid-rock Interactions and their Reservoir Effects within the Carbonate Deep Burial Realm

Discoveries of deep high-quality carbonate reservoirs challenged the general understanding on the evolution of porosity decreasing with depth. New mechanisms of pore generation and preservation in the deep realm require to be proposed. Dolostones in the Feixianguan and Dengying Formations experienced maximum depths in excess of 8000 m, but still retained high porosity. Petrographic observation and homogenization temperatures help to identify products of deep fluid-rock interactions, visual and experimental porosity were used to quantify reservoir effects, the distribution of products finally being plotted to unravel the mechanisms. Th data reveal that thermochemical sulfate reduction (TSR), burial dissolution and quartz cementation are typical deep fluid-rock interactions. The SO42? of residual porewater sourced from the evaporative dolomitizing fluid was supplied for TSR in the hydrocarbon column, the TSR-inducing calcite cements were homogeneously dispersed in the hydrocarbon column. Quartz cementation was caused by the increasing acidity and Si-rich residual porewater in the oil column. Burial dissolution is forced by organic acid and limited in oil–water contact. This study suggests that seal and source rocks not only play important roles in hydrocarbon accumulation, but also have a general control on the deep fluid-rock interactions and porosity evolution in the deep burial realm.     

超压对川东南地区五峰组-龙马溪组页岩储层影响分析

四川盆地东南部保存条件较好的五峰组-龙马溪组页岩普遍存在超压,且在其他地质条件相同的情况下,超压页岩储层相对于常压、低压储层具有更高的孔隙度.研究表明,富有机质页岩在适中的热演化过程中,由于烃类的大量生成,形成较多有机质孔隙,增加了页岩储层储集空间;另一方面,烃类大量生成造成的超压对页岩储层储集空间保存具有至关重要的作用.川东南五峰组-龙马溪组优质页岩储层孔隙以有机质孔、黏土矿物孔等塑性孔为主,且缺少刚性矿物颗粒支撑,易被上覆地层有效应力压实.但超压的存在对于页岩储层具有保护作用,抵消了上覆地层有效应力对页岩储层的机械压实,从而使已形成的页岩孔隙保存下来,使页岩储集空间得以保留.研究超压对页岩储层孔隙度影响机制以及超压页岩储层发育模式对于四川盆地五峰组-龙马溪组页岩气勘探、开发具有重要意义.     

鄂尔多斯盆地大牛地地区致密砂岩石英溶解作用及其对优质储集层的影响

储集层孔隙成因机制是致密砂岩储集层评价和预测必须解决的基本问题。本文以储集层微观分析为基础,对鄂尔多斯盆地大牛地气田石炭-二叠系致密砂岩储集层孔隙成因类型及其和优质储集层成因的关系进行了研究。结果表明,研究区致密砂岩储集层中碎屑石英颗粒存在明显的直接溶解现象,并形成了以石英溶解为主的储集空间类型,这种石英溶解是碱性成岩环境作用的结果,致密砂岩储集层的发育程度仍然和孔隙度以及组分的溶解作用有密切关系,碱不稳定矿物的溶蚀量一般为1%~23%,石英溶解型孔隙对储集层孔隙的贡献率一般可以达到60%~90%,碱溶蚀量达到5%以上时有利于优质储集层的形成;石英溶解作用较强的位置主要是颗粒边部的粒间孔隙周围,这种类型的溶解形成于储集层经历较强的压实成岩改造之后,所形成的溶解孔隙在后期的持续性压实过程中损失程度较低;石英溶解作用的强弱决定了储集层物性的最终发育程度以及优质储集层的形成。