Possible chemical structures and biological precursors of different vitrinites in coal measure in Northwest China

Chemical structure of Jurassic vitrinites isolated from the coals in basins in NW China have been checked using solid state ¹³C NMR and flash pyrolysis-GC/MS. Study shows some Jurassic collodetrinites are rich in aliphatic products in pyrolysates, consisting with the high amount of methylene carbon in ¹³C NMR spectra. In contrast, pyrolysates of Jurassic collotelinites are rich in phenols and alkylbenzenes. Also one Pennsylvanian and one Permian vitrinite selected from the Ordos basin, NW China have been checked for comparison. The proportion of aliphatics is low in pyrolysates, and aliphatic carbon peak in ¹³C NMR spectrum of Permian vitrinite is mostly composed of gas-prone carbons compared with collodetrinites in those Jurassic basins. But both pyrolysis and ¹³C NMR data shows the Pennsylvanian vitrinite is not only gas-prone but also oil-prone. Relatively high proportion of long chain aliphatic structure of some Jurassic vitrinite in Junggar, Turpan-Hami basins may be due to the contribution of liptodetrinites, which may be included during the formation of vitrinites. And it seems that suberinite is the most possible precursor of long chain aliphatics in the structure of Jurassic collodetrinite.     

不饱和古罗糖醛酸三糖和甘露糖醛酸三糖的结构表征

以双功能褐藻胶裂解酶 (Pseudoalteromonas sp.strain No. 2 72 )分别降解均聚古罗糖醛酸(PG)和均聚甘露糖醛酸 (PM) ,经 Bio- Gel- P6和 POROS- HQ2 0分离得到 2种三糖纯品 ,经 ESI- MS,1 H- NMR,1 3 C- NMR,1 H- 1 H COSY,1 H- 1 3 C HMQC确定其结构为 Δ4,5-古罗糖醛酸 - α(1→ 4 ) - L-古罗糖醛酸 -α(1→ 4 ) - L -古罗糖醛酸 (简写为Δ GG)和Δ4,5-甘露糖醛酸 -β (1→ 4 ) - D-甘露糖醛酸 -β (1→ 4 ) - D-甘露糖醛酸 (ΔMM) ,为进一步从事构效关系研究提供结构信息。     

Study of macroaggregate composition using FT-IR and H-NMR spectroscopy

Mucous macroaggregates, recently observed in the northern Adriatic in summer of 1997 and late spring of 2000, are primarily the product of phytoplankton (diatom) exudates during favourable environmental conditions in late spring, and can be viewed as macrogels. The FT-IR and ¹H-NMR spectra of macroaggregate samples from the northern Adriatic, collected in different formation stages in July 1997, August 1997, September 1997 and June 2000, as well as of cultured diatom Skeletonema costatum, showed that they are similar and composed of aliphatic components and polysaccharides bonded through carboxylic and amide groups, and organosilicon compounds. The stability of macrogels of macroaggregates is, according to FT-IR and X-ray analyses, most probably enhanced by interactions with entrapped particles of calcite, quartz and clay minerals. These organic-mineral associations seem to be important for mucous phenomena. According to ¹H-NMR spectra, the temporal differences in macroaggregate composition show a relative increasing percentage of organosilicon compounds and aliphatic components bonded to carbohydrates through ester and amide groups, and an increasing ratio between aliphatic structures and carbohydrates. This indicates that aliphatic chains bonded to Si and carbohydrates may contribute to the persistence and stability of macroaggregates in the summer stratified waters in the northern Adriatic, while the temporal decrease of carbohydrate content is most probably due to microbial and photochemical degradation of algal reserve polysaccharides.     

测井资料在碳酸盐岩储层评价中的应用

以塔河油田碳酸盐岩储集层基本特征为依据，利用常规和能谱测井资料信息比值法和重叠法等技术．致力于储集层缝、孔、洞测井响应特征敏感性评价研究，从中提取8项储层敏感性参数，并对其进行综合评判，确定出划分储层类别的标准，经过50口井的测试资料验证，采用多参数综合评判来划分储层类别是可行的，对储层的评价效果较好，使常规测井资料得到了更深入、广泛的应用。     

滇西水成铀矿勘探综合测井成果

滇西龙川江盆地发现水成铀矿。本文借助地球物理综合测井技术，对龙川江盆地水成铀矿的成矿规律作有益分析和探讨。重点论述滇西水成铀成矿的成矿（沉积）环境及其成矿物征。     

利用核磁共振方法研究水文地质问题及应用实例

地面核磁共振找水方法是目前唯一直接找水的物探新方法。本文在介绍NMR方法原理的基础上,结合NMR方法技术特点和在中国的应用实例,论述了NMR方法在探测地下水、地下水资源评价等方面的效果,并提出了进一步开展新方法的工作建议。     

磁共振用于医学成像与地面找水方法的技术对比研究

目的 医学核磁共振与地面核磁共振找水是核磁共振技术应用的不同领域。本文通过对二者在方法原理、技术、应用等方面的对比研究，提出了地面核磁共振找水工作建议。     

一类测井方程的解析反演

本文采用解析方法，给出了感应测井中当介质可表示成ｖ（ｘ，ｙ，ｚ）＝Σ↓ｋ，ｆｖｋ，ｊ＾ｘ＾ｋｙ＾ｊ时的反演公式，并讨论了径向浸入深度γ０的反演。     

高岭石—莫来石反应系列：^27Al和^29SiMAS NMR研究

根据艰我国八个不同成因和特征的高岭土样品在４５０－１４５０℃热处理产物的ＭＡＳ ＮＭＲ谱和ＸＲＤ，ＩＲ，ＤＴＡ等研究结果，结合有关资料讨论了高岭石－莫来石反应序列的几个重要问题：１．高岭石的结构，尤其是五配位铝；２．９８０℃放热峰后的高温相是γ－Ａｌ２Ｏ３而不是Ａｌ－Ｓｉ尖晶石；３．对于莫来石化过程，认为初始莫来石８５０－９５０℃变高岭石形成，二次莫来石由分凝的ＳｉＯ２和γ－Ａｌ２Ｏ３在１２００－