Characteristics of paleoproterozoic Subduction System in Western Margin of Yangtze Plate

INTRODUCTIONDebate centered on Proterozoic tectonic style and crustalevolution has existed for a long time.The customary viewbelieved that the Proterozoic undeveloped solid plate could notput into effect on the subduction because of the high heat flowin the earth,and the continental crustal growth was dominatedby mafic magm a vertical underplating (Wyborn,1988;Etheridge etal.,1987) .However,many observations recentlyobtained from Proterozoic mobile zones in the world suggeststhat Proter…     

Petrochemistry of Late Miocene to Quaternary Igneous Rocks and Metallogenesis in Southwest Hokkaido, Japan

Abstract: Southwest Hokkaido is largely covered by Late Miocene to Quaternary igneous rocks, and has a large number of gold veins and base-metal veins of the same age. Investigation of the silica-normalized concentration of elements has revealed regional petrochemical zoning; large ion lithophile elements (LILE) and K₂O/(Na₂O+K₂O) of the rocks increase toward Japan Sea, whereas total FeO, CaO, and ⁸⁷Sr/⁸⁶Sr decrease. Mapped concentration isoplethes of these elements are not ideally parallel to the volcanic front, but protrude to the west at Funka Bay, and to the northwest at Matsumae Peninsula. Isoplethes of ⁸⁷Sr/⁸⁶Sr show similar patterns and two more northwestward protrusions in the northeast (Jozankei block) of southwest Hokkaido. Contrary to the general petrochemical trend, both high– and low-LILE volcanic rocks occur in the Jozankei block. The ore deposits are distributed in four metallogenic zones; manganese–base–metal zone on the Japan Sea side, pyrite-limonite zone mainly along the volcanic front, gold zone in the middle, and two units of gold–base–metal zone. The northern unit of this zone is in the Jozankei block, and seems a part of the gold zone overlapped by the manganese–base–metal zone. Thus, as a rule, pyrite–limonite, gold, and base-metal deposits accompany low–, intermediate–, and high-LILE igneous rocks, respectively. Individual deposits and volcanic rocks make chains oblique to the zones and the volcanic front. The majority of the ore deposits are distributed along ridges of Bouguer anomalies overlapped by the volcanic chains, which apparently control the patterns of the petrochemical isoplethes. This is typical for two volcanic chains to the north and south of Funka Bay, where the petrochemical isoplethes protrude to the west. This indicates that both the igneous activity and the mineralization have been under the control of tectonic fractures at the roots of the volcanic chains. The geological, petrochemical and metallogenic data support the idea that the chemical characteristics of the deposits are correlated mainly with the chemistry of the associated magmas, and partly with that of the host rocks.     

Applicability of large-ion lithophile and high field strength element basalt discrimination diagrams

Basalt discriminant diagrams have been used to identify the tectonic setting of basaltic magmatism since the 1970s and have played an important role in reconstructing paleotectonic environments. However, the significant increase in the availability of geochemical data has led to a reassessment of these diagrams, suggesting that some of the tectonic settings indicated by these diagrams are not accurate. Here, we use a database of global ocean island basalt (OIB), mid-ocean ridge basalt (MORB), and island arc basalt (IAB) geochemistry to propose a series of new tectonic discriminant diagrams based on the ratios of large-ion lithophile elements (LILEs) to high field strength elements (HFSEs). These new diagrams indicate that the LILE can be used to differentiate OIB, MORB, and IAB samples, meaning that LILE/HFSE ratios can discriminate between these basalts that form in different tectonic settings. Our new diagrams can correctly assign samples to OIB, MORB, and IAB categories more than 85% of the time, with the discrimination between OIB and MORB having an accuracy of slightly less than 85%.     

Trace and rare-earth element behaviors during alteration and mineralization in the Attepe iron deposits (Feke-Adana,southern Turkey)

Hydrothermal-metasomatic iron ores consisting mainly of siderite, ankerite and hematite are located in the Lower–Middle Cambrian limestone marbles of the Eastern Taurus Belt. The siderite, ankerite, hematite and host rock samples from the deposits have been investigated for major, trace, and rare-earth elements (REE) to evaluate the element mobility and mass transfer during fluid–rock interactions.     

西藏崩纳藏布和甲岗雪山地区花岗岩的地球化学特征及成因初探

西藏申扎县崩纳藏布和甲岗雪山两个地区出露的岩浆岩体一直被认为是两个较大的花岗岩基，但实际地质调查表明，这两个岩体中的每一个都可以分解为多个不同岩性的小岩体，K—Ar同位素年龄表明，这些岩体主要形成于燕山晚期(90．55Ma-114．67Ma)和喜山早期(58．75Ma)。对其中部分岩体开展的微量元素、稀土元素以及Rb—Sr和Sm—Nd同位素的地球化学初步研究表明，两地出露的花岗岩体虽然形成于不同时代，但具有相同的以壳幔混合带为主的源区。另一方面．痕量元素的含量及同位素的组成特征也同时表明了形成于不同时期的岩体具有含量、配分、趋势变化等方面的差异，反映其具体的成因和分异演化过程并不相同。     

Sediment Melts at Sub-arc Depths: an Experimental Study

The phase and melting relations in subducted pelites have beeninvestigated experimentally at conditions relevant for slabsat sub-arc depths (T = 600–1050°C, P = 2·5–4·5GPa). The fluid-present experiments produced a dominant paragenesisconsisting of garnet–phengite–clinopyroxene–coesite–kyanitethat coexists with a fluid phase at run conditions. Garnet containsdetectable amounts of Na₂O (up to 0·5 wt%), P₂O₅ (upto 0·56 wt%), and TiO₂ (up to 0·9 wt%) in allexperiments. Phengite is stable up to 1000°C at 4·5GPa and is characterized by high TiO₂ contents of up to 2 wt%.The solidus has been determined at 700°C, 2·5 GPaand is situated between 700 and 750°C at 3·5 GPa.At 800°C, 4·5 GPa glass was present in the experiments,indicating that at such conditions a hydrous melt is stable.In contrast, at 700°C, 3·5 and 4·5 GPa, asolute-rich, non-quenchable aqueous fluid was present. Thisindicates that the solidus is steeply sloping in P–T space.Fluid-present (vapour undersaturated) partial melting of thepelites occurs according to a generalized reaction phengite+ omphacite + coesite + fluid = melt + garnet. The H₂O contentof the produced melt decreases with increasing temperature.The K₂O content of the melt is buffered by phengite and increaseswith increasing temperature from 2·5 to 10 wt%, whereasNa₂O decreases from 7 to 2·3 wt%. Hence, the melt compositionschange from trondhjemitic to granitic with increasing temperature.The K₂O/H₂O increases strongly as a function of temperatureand nature of the fluid phase. It is 0·0004–0·002in the aqueous fluid, and then increases gradually from about0·1 at 750–800°C to about 1 at 1000°C inthe hydrous melt. This provides evidence that hydrous meltsare needed for efficient extraction of K and other large ionlithophile elements from subducted sediments. Primitive subduction-relatedmagmas typically have K₂O/H₂O of 0·1–0·4,indicating that hydrous melts rather than aqueous fluids areresponsible for large ion lithophile element transfer in subductionzones and that top-slab temperatures at sub-arc depths are likelyto be 700–900°C. KEY WORDS: experimental petrology; pelite; subduction; UHP metamorphism; fluid; LILE     

Geochemistry and petrogenesis of lamprophyric dykes and the associated rocks from Eslamy peninsula, NW Iran: Implications for deep-mantle metasomatism

Eslamy peninsula in NW of Iran is formed by a strato-volcano with collapsed calderon, which is intruded by lamprophyric dykes with minette composition. Also trachytic and microsyenitic dykes have intruded the volcanic rocks. The oldest volcanic activity includes eruption of leucite basanite, leucite tephrite, basanite and tephrite, which are associated with pyroclastic rocks. Lamprophyric dykes are distinguishable with large mica phenocrysts. Mica-clinopyroxenite xenoliths can be found in the rocks. The source magma of the rocks had a ultrapotassic to shoshonitic nature, rich in LREE and LILE. Eslamy peninsula lamprophyres are between alkaline and calc-alkaline lamprophyres in terms of REE patterns and spider diagrams for trace elements, but are closer to clac-alkaline lamprophyres. The behaviour of trace elements studied by the means of spider diagrams show that the magma, producing the lamprophyres, is generated from deep-mantle probably from a garnet-bearing source (garnet lherzolite) with high CO₂/H₂O content. The resulted magma had interacted with crustal materials and had formed Eslamy peninsula lamprophyres in a post-collisional tectonic setting. Geochemistry of rare elements indicate an extensive rutile-rich metasomatism in the source magma of the lamprophyres.