Numerical modeling for analyzing thermal surface anomalies induced by underground coal fires

Coal seams burning underneath the surface are recognized all over the world and have drawn increasing public attention in the past years. Frequently, such fires are analyzed by detecting anomalies like increased exhaust gas concentrations and soil temperatures at the surface. A proper analysis presumes the understanding of involved processes, which determine the spatial distribution and dynamic behavior of the anomalies.In this paper, we explain the relevance of mechanical and energy transport processes with respect to the occurrence of temperature anomalies at the surface. Two approaches are presented, aiming to obtain insight into the underground coal fire situation: In-situ temperature mapping and numerical simulation. In 2000 to 2005, annual temperature mapping in the Wuda (Inner Mongolia, PR China) coal fire area showed that most thermal anomalies on the surface are closely related to fractures, where hot exhaust gases from the coal fire are released. Those fractures develop due to rock mechanical failure after volume reduction in the seams. The measured signals at the surface are therefore strongly affected by mechanical processes.More insight into causes and effects of involved energy transport processes is obtained by numerical simulation of the dynamic behavior of coal fires. Simulations show the inter-relation between release and transport of thermal energy in and around underground coal fires. Our simulation results show a time delay between the coal fire propagation and the observed appearance of the surface temperature signal. Additionally, the overall energy flux away from the burning coal seam into the surrounding bedrock is about 30-times higher than the flux through the surface. This is of particular importance for an estimation of the energy released based on surface temperature measurements. Finally, the simulation results also prove that a fire propagation rate estimated from the interpretation of surface anomalies can differ from the actual rate in the seam.     

Supercritical gas sorption on moist coals

The effect of moisture on the CO₂ and CH₄ sorption capacity of three bituminous coals from Australia and China was investigated at 55 °C and at pressures up to 20 MPa. A gravimetric apparatus was used to measure the gas adsorption isotherms of coal with moisture contents ranging from 0 to about 8%. A modified Dubinin–Radushkevich (DR) adsorption model was found to fit the experimental data under all conditions. Moisture adsorption isotherms of these coals were measured at 21 °C. The Guggenheim–Anderson–de Boer (GAB) model was capable of accurately representing the moisture isotherms over the full range of relative pressures.Moist coal had a significantly lower maximum sorption capacity for both CO₂ and CH₄ than dry coal. However, the extent to which the capacity was reduced was dependent upon the rank of the coal. Higher rank coals were less affected by the presence of moisture than low rank coals. All coals exhibited a certain moisture content beyond which further moisture did not affect the sorption capacity. This limiting moisture content was dependent on the rank of the coal and the sorbate gas and, for these coals, corresponded approximately to the equilibrium moisture content that would be attained by exposing the coal to about 40–80% relative humidity. The experimental results indicate that the loss of sorption capacity by the coal in the presence of water can be simply explained by volumetric displacement of the CO₂ and CH₄ by the water. Below the limiting moisture content, the CO₂ sorption capacity reduced by about 7.3 kg t^− 1 for each 1% increase in moisture. For CH₄, sorption capacity was reduced by about 1.8 kg t^− 1 for each 1% increase in moisture.The heat of sorption calculated from the DR model decreased slightly on addition of moisture. One explanation is that water is preferentially attracted to high energy adsorption sites (that have high energy by virtue of their electrostatic nature), expelling CO₂ and CH₄ molecules.     

Quick-look assessments to identify optimal CO2 EOR storage sites

A newly developed, multistage quick-look methodology allows for the efficient screening of an unmanageably large number of reservoirs to generate a workable set of sites that closely match the requirements for optimal CO₂ enhanced oil recovery (EOR) storage. The objective of the study is to quickly identify miscible CO₂ EOR candidates in areas that contain thousands of reservoirs and to estimate additional oil recovery and sequestration capacities of selected top options through dimensionless modeling and reservoir characterization. Quick-look assessments indicate that the CO₂ EOR resource potential along the US Gulf Coast is 4.7 billion barrels, and CO₂ sequestration capacity is 2.6 billion metric tons. In the first stage, oil reservoirs are screened and ranked in terms of technical and practical feasibility for miscible CO₂ EOR. The second stage provides quick estimates of CO₂ EOR potential and sequestration capacities. In the third stage, a dimensionless group model is applied to a selected set of sites to improve the estimates of oil recovery and storage potential using appropriate inputs for rock and fluid properties, disregarding reservoir architecture and sweep design. The fourth stage validates and refines the results by simulating flow in a model that describes the internal architecture and fluid distribution in the reservoir. The stated approach both saves time and allows more resources to be applied to the best candidate sites.     

Composition and quality of coals in the Huaibei Coalfield, Anhui, China

The Huaibei Coalfield, Anhui Province, China, is one of the largest coalfields in China. The coals of Permian age are used mainly for power generation. Coal compositions and 47 trace elements of the No. 10 Coal of the Shanxi Formation, the No. 7, 5, and 4 Coals of the Lower Shihezi Formation, and the No. 3 Coal of the Upper Shihezi Formation from the Huaibei Coalfield were studied. The results indicate that the Huaibei coals have low ash, moisture, and sulfur contents, but high volatile matter and calorific value. The ash yield increases stratigraphically upwards, but the volatile matter and total sulfur contents show a slight decrease from the lower to upper seams. Magmatic intrusion into the No. 5 Coal resulted in high ash, volatile matter, and calorific value, but low moisture value in the coal. Among the studied 47 trace elements, Ba, Co, Cr, Cu, Hg, Mo, Ni, Pb, Sb, Th, U, V, and Zn are of environmental concerns. Four elements Hg, Mo, Zn, and Sb are clearly enriched in the coals as compared with the upper continental crust.     

Possible impact of dam reservoirs and river diversions on material fluxes to the Gulf of Thailand

Thai people have always been agricultural-based, although rainwater is not enough to sustain year-round agricultural practice. The first earth-filled dam was built across a valley near Sukhothai over 700 years ago. Now, there are six major multipurposed dam reservoirs, among which the largest is the Sri Nakarind (SN) built across the Kwae Yai River, the main branch of the Mae Klong River in the western part of Thailand. The first multipurposed dam reservoir built on the Chao Phraya (largest) River System is the Bhumibhol Dam on the Ping River. In this paper, the two Mae Klong River Dam Reservoirs and their biology and chemistry are discussed. Also investigated are the historical records of material fluxes to the Gulf of Thailand in down-core sediment profiles and in 40-year bands of coral, Porites lutea, taken from the Upper Gulf of Thailand near Si Chang Island. Sediment cores studied did not show clear decreases in the biogenic silica concentration in the Upper Gulf area after the building of dams. Part of the reasons might be the higher rate of dissolution of silica in tropical waters bioturbation of surface layers or the constant disturbance of the bottom sediment by fishermen using bottom trawls. The record in the coral bands seems to be more promising in reflecting the material flux change due to dam construction. An attempt to detect changes in diatom population with time due to the expected decrease in siliceous material discharge was not possible because there was a change from the use of 70 μm mesh size to 20 μm mesh size resulting in the increase of species and biomass, although the diatom percentage remained above 80% in all estuarine samples.     

Study on the connectivity of heavy oil reservoirs by ultraviolet spectrum technique in the western part of the QHD32-6 oilfield

As a new method, the ultraviolet spectrum technique is applied to studying the connectivity of biode-gradable heavy oil reservoirs. The similarity of crude oils can be judged according to the extinction coefficient （E） because aromatic hydrocarbons and non-hydrocarbons have conjugated bonds and obvious absorption in the ultraviolet range, and different materials have different characteristics and additives. The relationship diagram is made in terms of the extinction coefficients （E） of the samples by taking E as the Y-axis and wavelength as the X-axis. The connectivity of oil reservoirs is estimated according to the curve positions and characteristic fingerprints of the sampies. The connectivity of part of the reservoirs in the western part of the QHD32-6 oilfield was studied with this method. The results showed that the connectivity of samples from wells F7 and F8 in the Nm-2 oil reservoir zone is good, that of samples from wells F17 and F20 in the Nm-1 oil reservoir zone also is good, and that of samples from wells F17, F19, and F20 is poor.     

Geologic Characteristics of Gas Reservoirs in West Sichuan Foreland Basin

The foreland basin in West Sichuan is a tectonic unit that has undergone multi-periods tectonic movements of Indosinian-Yanshanian-Himalayan. Since late Triassic, it has been in a passive subsidence environment controlled by basin margin mountain systems and by the compression with abundant sediment sources. With the complex geologic setting, the main geologic characteristics of natural gas reservoir are listed as following:(1)Source rocks are coal-bearing mud and shale series with high to over maturity, and long and progressive hydrocarbon generation-displacement period. The key accumulation period is middle-late Yanshanian epoch.(2)There are three gas-bearing systems vertically, each of which has different reservoir mechanism, main-controlled factors and distribution law, so the exploration thoughts and techniques are also different.(3)Undergoing multi-period generation-migration-accumulation, oil and gas have encountered multi-period modification or destruction, and gas accumulation overpass multiple tectonic periods. So the trap type is complicated and dominated by combination traps. Because the main accumulation period of natural gas is early and the reservoir encountered the modification of strong Himalayan movement, there is great difference in the fullness degree of gas reservoirs and complicated gas-water relation. (4) Reservoir is tight to very tight, but reservoirs of relatively high quality developed under the super tight setting. (5) The key techniques for oil and gas exploration in west Sichuan foreland basin are the prediction of relatively favorable reservoirs, fractures and gas bearing; and the key techniques for oil and gas development are how to improve the penetration rate, reservoir protection and modification.     

地下矿产开采对天然气管道工程的安全影响评价

西气东输天然气管道工程途经兖州市,穿越杨庄、杨村、兴隆庄等煤矿矿区,压覆煤层埋深变化较大。该文采用预测法对各煤矿在不同开采条件下分煤层对管道运营安全的危害程度进行了评价分析。通过计算表明,煤矿开采埋深越浅,煤层越厚,对管道危害越严重。兴隆庄煤矿3煤层、杨村煤矿煤16t、煤17开采对管道影响强烈,杨庄煤矿煤16t、煤17开采对管道影响中等,兴隆庄煤矿煤16t、煤17开采对管道运营影响小。     

碎屑岩自生粘土矿物的沉淀作用及其对储层的影响——以川西坳陷上三叠统须家河组砂岩为例

粘土矿物是影响碎屑岩储层物性的重要因素.本文以川西坳陷孝泉-新场-合兴场地区上三叠统须家河组砂岩为例,应用铸体薄片、普通薄片、X射线衍射分析和扫描电镜分析,研究了在成岩过程中自生粘土矿物的沉淀作用及其对储层的影响.结果表明自生绿泥石对储层原生孔隙的保存和次生孔隙的发育有利,自生高岭石的含量反映了次生孔隙的发育程度,而伊利石对储层的影响是负面的.     

冀中坳陷饶阳凹陷留西地区古近系沙河街组沙三上亚段沉积相与隐蔽油藏

通过岩心观察和单井相分析,结合沉积背景资料,认为留西地区古近系沙河街组沙三上亚段发育辫状河三角洲相和湖泊相,以辫状河三角洲前缘亚相和滨浅湖亚相为主,主要发育辫状分流河道、越岸沉积、水下分流河道、河口坝、席状砂等微相。根据层序地层学基本原理,结合前人研究成果,认为本区沙三上亚段为一完整的三级层序,可划分为低位、湖侵和高位3个体系域,分别对应于沙三上亚段沉积时期的早期、中期和晚期,绘制了每个沉积阶段的沉积相图,在此基础上研究了沉积体系的平面展布特征。沙三上亚段沉积时期形成的北高南低的构造背景与辫状河三角洲近东西向展布的砂体形态相互配置,加之良好的油源供给,为后期成藏创造了条件。沙三上亚段沉积早期发育的辫状河三角洲前缘水下分流河道与河口坝砂体是主要的储集体,与沉积中期发育的烃源岩形成了十分有利的生储盖组合,具有优越的隐蔽油藏发育条件。总结了该区隐蔽油藏成藏的4种模式,确定留西地区中南部沙三上亚段沉积早期发育的辫状河三角洲前缘砂体是下一步隐蔽油藏勘探的有利目标。