Mineral inclusions and geochemical characteristics of microdiamonds from the DO27, A154, A21, A418, DO18, DD17 and Ranch Lake kimberlites at Lac de Gras, Slave Craton, Canada

A mineral inclusion, carbon isotope, nitrogen content, nitrogen aggregation state and morphological study of 576 microdiamonds from the DO27, A154, A21, A418, DO18, DD17 and Ranch Lake kimberlites at Lac de Gras, Slave Craton, was conducted. Mineral inclusion data show the diamonds are largely eclogitic (64%), followed by peridotitic (25%) and ultradeep (11%). The paragenetic abundances are similar to macrodiamonds from the DO27 kimberlite (Davies, R.M., Griffin, W.L., O'Reilly, S.Y., 1999. Diamonds from the deep: pipe DO27, Slave craton, Canada. In: Gurney, J.J., Gurney, J.L., Pascoe, M.D., Richardson, S.H. (Eds.), The J. B. Dawson Vol., Proc. 7th Internat. Kimberlite Conf., Red Roof Designs, Cape Town, pp. 148–155) but differ to diamonds from nearby kimberlites at Ekati (e.g., Lithos (2004); Tappert, R., Stachel, T., Harris, J.W., Brey, G.P., 2004. Mineral Inclusions in Diamonds from the Panda Kimberlite, S. P., Canada. 8th International Kimberlite Conference, extended abstracts) and Snap Lake to the south (Dokl. Earth Sci. 380 (7) (2001) 806), that are dominated by peridotitic stones.

Eclogitic diamonds with variable inclusion compositions and temperatures of formation (1040–1300 °C) crystallised at variable lithospheric depths sometimes in changing chemical environments. A large range to very ¹³C-depleted C-isotope compositions (δ¹³C=−35.8‰ to −2.2‰) and an NMORB bulk composition, calculated from trace elements in garnet and clinopyroxene inclusions, are consistent with an origin from subducted oceanic crust and sediments. Carbon isotopes in the peridotitic diamonds have mantle compositions (δ¹³C mode −4.0‰). Mineral inclusion compositions are largely harzburgitic. Variable temperatures of formation (garnet T_Ni=800–1300 °C) suggest the peridotitic diamonds originate from the shallow ultra-depleted and deeper less depleted layers of the central Slave lithosphere. Carbon isotopes (δ¹³C av.=−5.1‰) and mineral inclusions in the ultradeep diamonds suggest they formed in peridotitic mantle (670 km). The diamonds may have been entrained in a plume and subcreted to the base of the central Slave lithosphere.

Poorly aggregated nitrogen (IaA without platelets) in a large number of eclogitic (67%) and peridotitic (32%) diamonds, with similar nitrogen contents, indicates the diamonds were stored in the mantle at low temperatures (1060–<1100 °C) following crystallisation in the Archean. Type IaA diamonds have largely cubo-octahedral growth forms, and Type II and Type IaAB diamonds, with higher nitrogen aggregation states, mostly have octahedral morphologies. However, no correlation between these groups and their mineral inclusion compositions, C-isotopes, and N-contents rules out the possibility of unique source origins and suggests eclogitic and peridotitic diamonds experienced variable mantle thermal states. Variation in mineral inclusion chemistries in single diamonds, possible overgrowths of ¹³C-depleted eclogitic diamond on diamonds with peridotitic and ultradeep inclusions, and Type I ultradeep diamond with low N-aggregation is consistent with diamond growth over time in changing chemical environments.     

Palynological and geochemical response to environmental changes in the Lower Cretaceous in the Outer Western Carpathians; a record from the Silesian unit, Czech Republic

Rich dinoflagellate cyst assemblages recorded from the Vendryne Formation, Tesin Limestone, and Hradiste Formation of the Silesian unit, Czech Republic are presented. The results of a qualitative and quantitative study of dinoflagellate cysts are presented and discussed. Age-assessment of the sediments based on 86 species suggests a Late Tithonian to Early Berriasian age for the Vendryne Formation and a Late Berriasian (Otopeta Ammonite Zone) to the basal part of the Late Valanginian (Verrucosum Ammonite Zone) age for the Tesin Limestone. Pelitic flyschoid sediments of the Hradiste Formation belong to the Late Valanginian - Early Hauterivian age. Quantitative palynological study and carbon isotope analysis were applied to understand the change from the grey clays to dark grey clays sedimentation. The dinoflagellate cyst assemblages show deposition in a shallow-sea environment. An increasing amount of sporomorphs towards the overlying layers (they are the most abundant in the Hradiste Formation) shows a growing supply of terrestrial material at the same time. The values of δ¹³C increased significantly from a level of 0.43 or 0.75-1.81‰ in the Late Valanginian. This change probably indicates an increase in organic matter storage and perturbation of the carbon cycle connected with the dark grey clays sedimentation.     

Further studies on torbanites and coorongite using transmission electron microscopy and C-isotope analysis

Transmission electron microscopy of torbanites from various localities in eastern Australia has revealed micro-organisms of possible methanogenic affinity. Botryococcus remains in the torbanites displayed close resemblance to the rubbery B. braunii accumulations deposited in recent bodies of freshwater origin. Compaction and collapse of structure seem to be the major visible alteration to the algal colonies. C-isotope compositions of the torbanites favour methanogenic activity. Comparison with recent botroyococcal accumulations support diagenetic alteration at a very early stage of deposition.     

Stratigraphy, biostratigraphy and C-isotopes of the Permian–Triassic non-marine sequence at Dalongkou and Lucaogou, Xinjiang Province, China

Measured lithostratigraphic sections of the classic Permian–Triassic non-marine transitional sequences covering the upper Quanzijie, Wutonggou, Guodikeng and lower Jiucaiyuan Formations at Dalongkou and Lucaogou, Xinjiang Province, China are presented. These measured sections form the framework and reference sections for a range of multi-disciplinary studies of the P–T transition in this large ancient lake basin, including palynostratigraphy, vertebrate biostratigraphy, chemostratigraphy and magnetostratigraphy. The 121 m thick Wutonggou Formation at Dalongkou includes 12 sandstone units ranging in thickness from 0.5 to 10.5 m that represent cyclical coarse terrigenous input to the lake basin during the Late Permian. The rhythmically-bedded, mudstone-dominated Guodikeng Formation is 197 m and 209 m thick on the north and south limbs of the Dalongkou anticline, respectively, and 129 m thick at Lucaogou. Based on limited palynological data, the Permian–Triassic boundary was previously placed approximately 50 m below the top of this formation at Dalongkou. This boundary does not coincide with any mappable lithologic unit, such as the basal sandstones of the overlying Jiucaiyuan Formation, assigned to the Early Triassic. The presence of multiple organic δ¹³C-isotope excursions, mutant pollen, and multiple algal and conchostracan blooms in this formation, together with Late Permian palynomorphs, suggests that the Guodikeng Formation records multiple climatic perturbation signals representing environmental stress during the late Permian mass extinction interval. The overlap between the vertebrates Dicynodon and Lystrosaurus in the upper part of this formation, and the occurrence of late Permian spores and the latest Permian to earliest Triassic megaspore Otynisporites eotriassicus is consistent with a latest Permian age for at least part of the Guodikeng Formation. Palynostratigrahic placement of the Permian–Triassic boundary in the Junggar Basin remains problematic because key miospore taxa, such as Aratrisporites spp. are not present. Palynomorphs from the Guodikeng are assigned to two assemblages; the youngest, from the upper 100 m of the formation (and the overlying Jiucaiyuan Formation), contains both typical Permian elements and distinctive taxa that elsewhere are known from the Early Triassic of Canada, Greenland, Norway, and Russia. The latter include spores assigned to Pechorosporites disertus, Lundbladispora foveota, Naumovaspora striata, Decussatisporites mulstrigatus and Leptolepidites jonkerii. While the presence of Devonian and Carboniferous spores and Early Permian pollen demonstrate reworking is occurring in the Guodikeng assemblages, the sometimes common occurrence of Scutasporites sp. cf. Scutasporites unicus, and other pollen, suggests that the Late Permian elements are in place, and that the upper assemblage derives from a genuine transitional flora of Early Triassic aspect. In the Junggar Basin, biostratigraphic data and magnetostratigraphic data indicate that the Permian–Triassic boundary (GSSP Level) is in the middle to upper Guodikeng Formation and perhaps as high as the formational contact with the overlying Jiucaiyuan Formation.