Triassic Nb-enriched basalts, magnesian andesites, and adakites of the Qiangtang terrane (Central Tibet): evidence for metasomatism by slab-derived melts in the mantle wedge

New chronological, geochemical, and isotopic data are reported for Triassic (219–236 Ma) adakite-magnesian andesite-Nb-enriched basaltic rock associations from the Tuotuohe area, central Qiangtang terrane. The adakites and magnesian andesites are characterized by high Sr/Y (25–45), La/Yb (14–42) and Na₂O/K₂O (12–49) ratios, high Al₂O₃ (15.34–18.28 wt%) and moderate to high Sr concentrations (220–498 ppm) and ε_ND (t) (+0.86 to +1.21) values. Low enrichments of Th, Rb relative to Nb, and subequal normalized Nb and La contents, and enrichments of light rare earth elements combine to distinguish a group of Nb-enriched basaltic rocks (NEBs). They have positive ε_ND (t) (+2.57 to +5.16) values. Positive correlations between Th, La and Nb and an absence of negative Nb anomalies on mantle normalized plots indicate the NEBs are products of a mantle source metasomatized by a slab melt rather than by hydrous fluids. A continuous compositional variation between adakites and magnesian andesites confirms slab melt interaction with mantle peridotite. The spatial association of the NEBs with adakites and magnesian andesites define an “adakitic metasomatic volcanic series” recognized in many demonstrably subduction-related environments (e.g., Mindanao arc, Philippines; Kamchatka arc, Russia; and southern Baja California arc, Mexico). The age of the Touhuohe suite, and its correlation with Triassic NEB to the north indicates that volcanism derived from subduction-modified mantle was abundant prior to 220 Ma in the central Qiangtang terrane.     

西天山特克斯达坂库勒萨依序列埃达克岩的确立及钼找矿意义

库勒萨依序列斑岩体δ平均3.05,属于钙碱性系列岛弧浅成岩。 SiO₂含量为57.06％~70.74％,高Al₂O₃、Na₂O、Sr和相对富集LREE,低MgO、Y、Yb,强烈亏损HREE。Na₂O/K₂O＞1,Sr/Y平均57.67,正Eu异常,因而具有典型O型埃达克岩特征。库勒萨依序列斑岩体与Mo异常套合好,已发现钼矿体,找矿前景良好。该埃达克岩的确立,对深化西天山区域成矿规律和指导今后找矿具有借鉴和指导意义。     

拉萨地体东南缘的多期深熔作用及动力学

位于青藏高原班公湖-怒江蛇绿岩带与印度-雅鲁藏布江蛇绿岩带之间拉萨地体东南缘的前寒武纪结晶基底经历了角闪岩相-麻粒岩相区域变质作用和强烈的混合岩化.研究区可识别出两期深熔作用,第一期为斜长角闪岩部分熔融形成的花岗闪长岩脉体,其与围岩一起发生了变质与变形再造,转变成了黑云斜长片麻岩.第二期为含夕线石石榴石片麻岩部分熔融形成的含石榴石斜长石花岗岩脉体.岩石化学成分显示,第一期深熔脉体具有埃达克岩的典型地球化学特征,其SiO2=63.81%,Al2O3=16,92%,MgO=1.86%,Na2O=4.22%,K2O=1.81%,K2O/Na2O=0.43,并显示出LREE富集、无Eu异常的BEE配分模型,同时明显富Sr(366×10-6),贫Y(12×10-6)和Yb(0.4×10-6),Sr/Y=30.舍石榴石斜长石花岗岩主要由斜长石、石英和石榴石组成,含少量白云母和黑云母,其全岩SiO2=71.14%,Al2O3=14.26%,K2O=0.26%,Na2O=2.79%.CaO=2.94%.过铝指数A/CNK=1.40,为典型的过铝花岗岩.黑云斜长片麻岩脉体中的大多数锆石具有同心韵律状结晶环带和较高的Th//U比值(0.433～1.167),为典型的岩浆结晶锆石.锆石岩浆结晶域U-Pb原位定年给出了64.0±1.0Ma(MSWD=8.7)加权平均年龄;个别锆石变质交生边给出了27.9 Ma的谐和年龄,同时具有较低的Th/U比值(0.019),应代表后期叠加的变质热事件年龄.含石榴石斜长石花岗岩中的锆石均发育同心韵律状环带,而且具有较高的Th/U比值(0.196～1.212).所获得的谐和年龄在27.0～34.1Ma之间(加权平均年龄为29.3±0.9 Ma),应代表过铝花岗岩的结晶年龄.因此,我们认为拉萨地体东南缘变质基底在古近纪经历了两期深熔作用,第一期发生在约65Ma,在特提斯洋壳俯冲和印度板块与拉萨地体碰撞的动力学体制下,拉萨地体下地壳加厚和升温,发生了麻粒岩相变质和部分熔融,形成了埃达克岩质的花岗闪长岩浆;第二期混合岩化作用发生在约30Ma,在印度板块与拉萨地体碰撞后伸展的动力学体制下,高角闪岩相泥质变质岩中的含水矿物脱水熔融形成了过铝质花岗闪长岩浆.     

Na depletion in modern adakites via melt / rock reaction within the sub-arc mantle

Interaction between slab-derived melt and mantle peridotite and the role of slab melt as a metasomatizing agent in the sub-arc mantle is being increasingly recognized. Adakite, the slab melt erupted on the surface, usually exhibits anomalously high MgO, CaO, Cr and Ni contents that indicate interaction with mantle peridotitite. Here we note that Cenozoic adakites have Na₂O contents below 5.8 wt.% with ∼95% samples lower than 5.0 wt.%, and are generally depleted in this component relative to experimental basalt partial melts (mostly beyond 5.0 wt.% and up to 9.0 wt.% Na₂O) produced under 1.5-3.0 GPa conditions that are most relevant to adakite production. We interpret the adakite Na depletion to be also a consequence of the melt / rock reaction that takes place within the hot mantle wedge. During ascent and reaction with mantle peridotite, primary adakite melts gain mantle components MgO, CaO, Cr and Ni but lose Na₂O, SiO₂ and perhaps K₂O to the mantle, leading to Na-rich mantle metasomatism. Selective assimilation of predominately mantle clinopyroxene, some spinel and minor olivine at high T/P has been considered to be an important process in producing high-Mg adakites from primary low-Mg slab melts [Killian, R., Stern, C. R., 2002. Constraints on the interaction between slab melts and the mantle wedge from adakitic glass in peridotite xenoliths. Eur. J. Mineral. 14, 25-36]. In such a process, Na depletion in the assimilated melt is the result of dilution due to the increase in melt mass. Phase relationships in the reaction system siliceous melt + peridotite and quantitative calculation suggest that assimilation of mantle clinopyroxene, olivine and spinel and fractional crystallization of sodic amphibole and orthopyroxene, under conditions of moderate T/P and increasing melt mass, is also an important process that modifies the composition of adakites and causes the Na depletion.     

Petrogenesis of Cretaceous adakitic and shoshonitic igneous rocks in the Luzong area, Anhui Province (eastern China): Implications for geodynamics and Cu–Au mineralization

Both adakitic and shoshonitic igneous rocks in the Luzong area, Anhui Province, eastern China are associated with Cretaceous Cu–Au mineralization. The Shaxi quartz diorite porphyrites exhibit adakite-like geochemical features, such as light rare earth element (LREE) enrichment, heavy REE (HREE) depletion, high Al₂O₃, MgO, Sr, Sr / Y and La / Yb values, and low Y and Yb contents. They have low ε_Nd(t) values (− 3.46 to − 6.28) and high (⁸⁷Sr / ⁸⁶Sr)_i ratios (0.7051–0.7057). Sensitive High-Resolution Ion Microprobe (SHRIMP) zircon analyses indicate a crystallization age of 136 ± 3 Ma for the adakitic rocks. Most volcanic rocks and the majority of monzonites and syenites in the Luzong area are K-rich (or shoshonitic) and were also produced during the Cretaceous (140–125 Ma). They are enriched in LREE and large-ion lithophile elements, and depleted in Ti, and Nb and Ba and exhibit relatively lower ε_Nd(t) values ranging from − 4.65 to − 7.03 and relatively higher (⁸⁷Sr / ⁸⁶Sr)_i ratios varying between 0.7057 and 0.7062. The shoshonitic and adakitic rocks in the Luzong area have similar Pb isotopic compositions (²⁰⁶Pb / ²⁰⁴Pb = 17.90–18.83, ²⁰⁷Pb / ²⁰⁴Pb = 15.45–15.62 and ²⁰⁸Pb / ²⁰⁴Pb = 38.07–38.80). Geological data from the Luzong area suggest that the Cretaceous igneous rocks are distributed along NE fault zones (e.g., Tanlu and Yangtze River fault zones) in eastern China and were likely formed in an extensional setting within the Yangtze Block. The Shaxi adakitic rocks were probably derived by the partial melting of delaminated lower crust at pressures equivalent to crustal thickness of > 50 km (i.e., 1.5 GPa), possibly leaving rutile-bearing eclogitic residue. The shoshonitic magmas, in contrast, originated mainly from an enriched mantle metasomatized by subducted oceanic sediments. They underwent early high-pressure (> 1.5 GPa) fractional crystallization at the boundary between thickened (> 50 km) lower crust and lithospheric mantle and late low-pressure (< 1.5 GPa) fractional crystallization in the shallow (< 50 km) crust. The adakitic and shoshonitic rocks appear to be linked to an intra-continental extensional setting where partial melting of enriched mantle and delaminated lower crust was probably controlled by lithospheric thinning and upwelling of hot asthenosphere along NE fault zones (e.g., Tanlu and Yangtze River fault zones) in eastern China. Both the shoshonitic and adakitic magmas were fertile with respect to Cu–Au mineralization.     

洋脊和年轻洋壳俯冲与埃达克岩生成的热模拟

新生代以来 ,环太平洋周边分布的埃达克岩 (Adakite)主要与年轻洋壳俯冲时在 70～ 90km深处的部分熔融有关。利用数值方法 ,模拟了洋壳俯冲的热演化过程并讨论了脱水、熔融对埃达克岩浆活动的影响。结果表明 :仅在活动海岭俯冲前后约 10Ma内 ,年轻的、热的俯冲海洋板片在 75～85km深度范围内 ,温度升高至 82 5～ 10 0 0℃脱水 ,导致年轻洋壳中角闪岩部分熔融 ,形成埃达克岩(Adakite)。而一般洋壳俯冲在 10 0km以下深度才脱水 ,由于脱水区压力较高洋壳自身不能熔融 ,水进入上覆地幔楔状体导致部分熔融 ,形成安山岩 (Andesite     

加强埃达克岩研究，开创中国Cu、Au等找矿工作的新局面

埃达克岩与浅成低温热液Au-Ag及斑岩型Cu、Cu-Au矿床有密切的关系，环太平洋地区多数大型和世界级的斑岩铜矿均与埃达克岩有关。埃达克岩有利于成矿的关键因素与埃达克岩形成时角闪石转变为石榴石的脱水作用有关，而水能萃取出在地幔和基性岩中富集的金属元素。因此，埃达克岩集中分布的地区有利于铜、金等矿化的聚集。中国铜矿资源严重不足，解决这个紧迫问题的出路在寻找斑岩铜矿。全球铜矿主要分布在环太平洋地区，中国与环太平洋类似的地区不是中国东部，而是古亚洲洋造山带、东北吉黑东部和西藏冈底斯。从国家目标出发，建议实施铜、金等找矿工作的战略转移，把浅成低温热液和斑岩型Au、Cu、Ag等矿床找矿的重点放在古生代的古亚洲洋造山带、晚古生代-中生代的吉黑东部和中-新生代的冈底斯地区。古亚洲洋造山带首选阿尔泰西南缘-东准噶尔、东天山和内蒙古中部3个地区。埃达克岩可以作为找矿标志来使用，因此，在找矿思路上也应当有一个变化，即：先找埃达克岩，再找矿。     

铜陵地区中生代中酸性侵入岩的地球化学特征及其成矿-地球动力学意义

本文对铜陵地区晚侏罗世-早白垩世高钾钙碱性中酸性侵入岩进行了研究,发现该类岩体具有埃达克岩的地球化学特征,具体表现为:SiO2≥56％,Al2O3含量高(>15％),Na2O/K2O>1,亏损HREE,(La/Yb)N>12,负Eu异常不明显(Eu*/Eu=0.71-0.96),Sr含量高(>750μg/g),Sr/Y比值高(>38)。但是,由于岩石的K2O含量较高、εNd(t)较低和ISr值较高,又不同于典型的与板块俯冲有关的埃达克岩,而与中国东部中生代的C型埃达克岩比较类似,暗示铜陵地区的高钾钙碱性岩可能是加厚的下地壳底部基性岩部分熔融的产物。本文主要依据铜陵埃达克质岩的HREE特征,将其分为三类:第一类岩体为HREE平坦型,Yb含量较高(>1.8μg/g);第二类为HREE平坦型,Yb<1.8μg/g,(Ho/Yb)N≈1;第三类岩体HREE亏损,Yb<1.8μg/g,(Ho/Yb)N<1.2。上述三类岩石地球化学性质上的差异不太可能是分离结晶作用或地壳混染的 结果,而可能是由于幔源岩浆与下地壳物质混合的程度不同引起源区成分不同形成的。铜陵地区及中国东部埃达克质岩石可能代表了中国东部中生代时的地壳增生和加厚过程。铜陵埃达克岩主要是古老下地壳和底侵玄武岩不同比例混合部分熔融形成的,在岩浆演化过程中可能还不同程度地叠加了分离结晶作用和岩浆混合作用的影响。铜陵埃达克岩具岛弧特征,但并不表明其     

新疆库鲁克塔格青白口系北塞纳尔塔格组流纹岩的成因及其地质意义

运用LA-ICP-MS锆石U-Pb测年获得库鲁塔格西山口地区北塞纳尔塔格组蚀变流纹岩的形成时代为841.0±1.4Ma（MSWD=0.42）, 蚀变流纹岩的发现指示塔里木北缘新元古代中期除发育大量的侵入岩外还存在火山活动。地球化学特征分析表明, 岩石富集Rb、 Ba、 K等大离子亲石元素和轻稀土元素, 明显亏损Nb、 Ta、 P、 Ti等高场强元素。此外岩石富集Sr、 强烈亏损Y和Yb, 高的Sr/Y（>40）和（La/Yb）_N（>40）比值的特征与埃达克岩类似。蚀变流纹岩Hf同位素值ε_Hf（t）=-29～-9, Hf的二阶段模式年龄T_DM²=3.43～2.24Ga, 结合岩石较低的Mg^#、 Eu正异常以及强烈亏损重稀土元素的特征表明,其可能源于加厚古老基性下地壳的部分熔融。此外蚀变流纹岩低的锆石饱和温度T_Zr=761℃～768℃,表明源区发生部分熔融时存在外来流体的加入。结合已有区域地质资料, 初步认为蚀变流纹岩形成与塔里木北缘新元古代早、 中期洋—陆俯冲碰撞作用有关。     

昌宁-孟连结合带牛井山早古生代埃达克岩锆石U-Pb年龄、岩石成因及其地质意义

昌宁-孟连结合带是西南三江地区重要的古特提斯结合带,本文报道该带牛井山蛇绿混杂岩带内的早古生代英云闪长岩的锆石U-Pb年龄和Hf同位素、全岩地球化学特征,探讨其岩石成因,揭示早古生代(原)特提斯演化过程和恢复古地理格局。利用LA-ICP-MS对英云闪长岩进行锆石U-Pb定年,获得~(206)Pb/~(238)U加权平均年龄为468±2Ma(MSWD=1.4,n=22),代表岩浆岩结晶时代。对锆石进行原位微区Hf同位素分析获得锆石ε_(Hf)(t)=+1.6~+2.8。牛井山英云闪长岩具有高的SiO_2(61.6%~67.16%),Al_2O_3(15.4%~17.64%),Na_2O(2.93%~3.25%)含量,高的Na_2O/K_2O(3.9~5.4)比值。微量元素具有高Sr(469×10~(-6)~533×10~(-6)),低Yb(0.66×10~(-6)~1.22×10~(-6))和Y(8.5×10~(-6)~16.3×10~(-6)),Eu正异常(1.01~1.37)的特征。此外,在同等SiO 2条件下,还具有相对高的Mg~#和MgO(Mg~#=50~51,MgO=2.84%~3.58%)。这些特征表明英云闪长岩具有高镁埃达克岩的性质。岩石成因研究表明牛井山高镁埃达克岩很可能是俯冲洋壳加上部分大洋沉积物部分熔融并与上覆地幔橄榄岩反应的产物。早古生代洋壳俯冲成因的埃达克岩的发现证明昌宁-孟连特提斯洋演化历史可追溯至约468Ma。昌宁-孟连结合带早古生代岩浆作用与龙木错-双湖结合带早古生代洋壳残片的时代一致、构造属性相似,我们认为昌宁-孟连结合带与木错-双湖结合带可对比,它们代表了一个统一的古生代特提斯大洋残余。