钱二块铀矿床采铀注液结垢趋势的理论分析与预测

用离子系数矩阵法对钱二块铀矿床地浸采铀试验注液中存在的独立离子反应进行了确定,由溶度积规则及反应平衡原理,借助Matlab编程,估算出了钱二块铀矿床地浸采铀试验注液可能会生成的沉淀物种类及数量,为防治结垢提供了一定的理论依据.     

Chronology and cooling history of the Tianmenshan pluton in South Jiangxi Province and their geological significance

Geochronological studies on the crust-derived Tianmenshan pluton were undertaken by SHRIMP zircon U-Pb dating and Ar-Ar dating of biotite, muscovite and K-feldspar, giving a petrogenetic age of 167 Ma. Owing to the closure systems in different minerals, the cooling history of the pluton can be determined with an age-temperature diagram. The late hydrothermal event has been recognized, which is related probably with mineralization. In terms of the comparative geochronological and petrologic records, it is concluded that there are some constrains on tectonic evolution and that the formation of the Tianmenshan pluton proceeded in a transition period from Indosinian post-orogeny extension to strong compressive tectonics. And the timing of the hydrothermal event matches the compressive climax of the Yanshanian orogeny. The temporal gap between granite emplacement and wolframite mineralization could last 10-20 Ma owing to the low cooling rate of the pluton.     

Measurement of the total nitrogen in lake sediments： Comparison and its environmental significance

Nitrogen cycle is an important bio-geochemical process in the environment. Measurement of the total nitrogen （TN） is a routine experiment in agriculture, biology and environmental sciences. The Kjeldahl method （KM） and elemental analyzer method （EA） are both commonly used to determine TN. Total nitrogen by EA is the sum of nitrate （NO3）, nitrite （NO2）, organic nitrogen and ammonia. Total nitrogen by KM （TKN） is made up of both organic nitrogen and ammonia. A comparative study focused on the two methods is conducted by analysis of TN in 97 samples from the sediment sequence of Gouchi, a salt lake in North China. KM presents a higher degree of accuracy than EA with a standard deviation of 0.007 vs. 0.024. With the presence of nitrate and/or nitrite nitrogen, however, measurement by KM is considerably lower than that by EA. Therefore, for samples from lake sediment sequences or soils in North China, KM is inapplicable to determining TN because of usually high contents of nitrous salt. Despite the inconsistency, use of both methods to the same samples makes sense in reconstructions of climatic and environmental changes from lake sediments. In Lake Gouchi, the contents of nitrate and nitrite nitrogen vary from 1.40% in the lower part of the sequence to 14.77% in the uppermost part, suggesting a gradual evolution process from a fresh water lake to the present-day salt lake.     

Effects of human activities on mercury in the environment in Xi＇an area, China

Effects of mercury on ecosystems and human health are well documented. Human activities have significant impacts on transport, transformation, and fate of mercury in the natural environment. In this study, a gold mining area （Tongchuan）, an urban area （Xi＇an）, and a historical site （Qinshihuan Tomb） in Shaanxi Province, China, was chosen to study the effects of human activities on the transport, transformation, and fate of mercury in the area. Samples of atmospheric precipitate, soil, sediment, pomegranate, corn and those from wells and the rivers that flow through or flow by the city and from the mining area were collected. The EPA methods were used for sample preparation and analysis of these samples. These methods combine acid digestion, chemical reduction, purge and trap with Cold Vapor Atomic Fluorescence Spectrometry （CVAFS）. Preliminary results showed high total mercury concentrations in the water samples collected from a river in Tongguan County. The total mercury concentrations ranged from 133 to 188 ng/L in the water samples collected from the rivers flowing through Xi＇an City. The amount of total mercury in the soil/sediment samples which were collected in the vicinity of Xi＇an ranged from 31.8 to 83.2 ng/g. The total mercury concentrations in the samples of atmospheric precipitate （including rain and snow collected from Sep. 2005 to Jan. 2006） ranged from 106-298 ng/L.     

NUMERICAL STUDY ON THE MIXING OF UNSORTED SEDIMENT PARTICLES DISCHARGED INTO A CROSS-FLOW BY MULTIPHASE PARTICLE-IN-CELL （MP-PIC） METHOD

The mixing characteristics of dredged sediments of variable size discharged into cross-flow are studied by an Eulerian-Lagrangian method. A three-dimensional (3D) numerical model has been developed by using the modified k-ε parameterization for the turbulence in fluid phase/water and a Lagrangian method for the solid phase/sediments. In the model the wake turbulence induced by sediments has been included as additional source and sink terms in the k-ε model; and the trajectories of the sediments are tracked by the Lagrangian method in which the sediment drift velocities in cross-flow are computed by a multiphase particle-in-cell (MP-PIC) method and the diffusion process is approximated by a random walk model. The hydrodynamic behavior of dumped sediment cloud is governed by the total buoyancy on the cloud, the drag force on each particle and velocity of cross-flow. The cross-flow destroys more or less the double vortices occurred in stagnant ambience and dominates the longitudinal movement of sediment cloud. The computed results suggest satisfactory agreement by comparison with the experimental results of laboratory.     

STRUCTURE AND COMPOSITION OF A WATERSHED-SCALE SEDIMENT INFORMATION NETWORK

A "Watershed-Scale Sediment Information Network" (WaSSIN), designed to complement UNESCO’s International Sedimentation Initiative, was endorsed as an initial project by the World Association for Sedimentation and Erosion Research. WaSSIN is to address global fluvial-sediment information needs through a network approach based on consistent protocols for the collection, analysis, and storage of fluvial-sediment and ancillary information at smaller spatial scales than those of the International Sedimentation Initiative. As a second step of implementation, it is proposed herein that the WaSSIN have a general structure of two components, (1) monitoring and data acquisition and (2) research. Monitoring is to be conducted in small watersheds, each of which has an established database for discharge of water and suspended sediment and possibly for bed load, bed material, and bed topography. Ideally, documented protocols have been used for collecting, analyzing, storing, and sharing the derivative data. The research component is to continue the collection and interpretation of data, to compare those data among candidate watersheds, and to determine gradients of fluxes and processes among the selected watersheds. To define gradients and evaluate processes, the initial watersheds will have several common attributes. Watersheds of the first group will be: (1) six to ten in number, (2) less than 1000 km2 in area, (3) generally in mid-latitudes of continents, and (4) of semiarid climate. Potential candidate watersheds presently include the Weany Creek Basin, northeastern Australia, the Zhi Fanggou catchment, northern China, the Eshtemoa Watershed, southern Israel, the Metsemotlhaba River Basin, Botswana, the Aiuaba Experimental Basin, Brazil, and the Walnut Gulch Experimental Watershed, southwestern United States.     

Isotopic tracing of ore-forming source materials for Dexing porphyry copper deposit of Jiangxi, China

Dexing copper deposit is the biggest porphyry copper deposit in China. By researching isotopes of C, Si and Cu from the samples of Tongchang and Fujiawu ore-field, the authors found that δ^13 CpDB values of siderite were close to the δ^13 CpDB value of original magma; δ^30Si values of the samples at the ore-forming stage were close to the δ^30 Si value range of magma, δ^30Si values of partial samples were far away from it; Cu isotopic compositions of massive chalcopyrite formed at the early ore-forming stage are higher than that of veinal chalcopyrite formed at the later ore-forming stage. The results show that ore-forming materials were mainly derived from the porphyry body, and part of them were from wall rock materials.     

Grain-size related nitrogen distribution in southern Yellow Sea surface sediments

Forty-eight surface sediments of the southern Yellow Sea are separated into three grain-size fractions. Four forms of extractable nitrogen (nitrogen in ion-exchangeable form (Nie), nitrogen in weak-acid extractable form (Nwa), nitrogen in strong-alkali extractable form (Nsa) and nitrogen in strong-oxidant form (N50))are obtained by the sequential extraction. The results show that the contents and the distributions of the extractable nitrogen in the southern Yellow Sea surface sediments are closely related to sediment grain size. The distributions ofNie, Nso and total nitrogen (TN) present positive correlations with fine particles content, while Nwa and Nsa does not have such correlation. The net contents of all the forms of nitrogen increase with sediment grain size finer.     

现代热液喷口系统低温氧化物沉积体的矿物学特征及启示

Fe-Si氧化物是现代洋底热液系统最为普遍的沉积产物之一,它可以构成低温烟囱体、形成氧化物丘、充填围岩裂隙,或者以无规则沉积体出现(Hekinian et al.,1993),也可以在弥散流区形成更大规模的多金属沉积物(Hrischeva et al.,2007;